Zn-doped nickel iron (oxy)hydroxide nanocubes passivated by polyanions with high catalytic activity and corrosion resistance for seawater oxidation

So Jung Kim; Heechae Choi; Jeong Ho Ryu; Kang Min Kim; Sungwook Mhin; Arpan Kumar Nayak; Junghwan Bang; Minyeong Je; Ghulam Ali; Kyung Yoon Chung; Kyeong Han Na; Won Youl Choi; Sunghwan Yeo; Jin Uk Jang; Hyuk Su Han

doi:10.1016/j.jechem.2023.02.033

Zn-doped nickel iron (oxy)hydroxide nanocubes passivated by polyanions with high catalytic activity and corrosion resistance for seawater oxidation

So Jung Kim
, Heechae Choi
, Jeong Ho Ryu
, Kang Min Kim
, Sungwook Mhin
, Arpan Kumar Nayak
, Junghwan Bang
, Minyeong Je
, Ghulam Ali
, Kyung Yoon Chung
, Kyeong Han Na
, Won Youl Choi
, Sunghwan Yeo
, Jin Uk Jang
, Hyuk Su Han

Research output: Contribution to journal › Article › peer-review

21 Scopus citations

Abstract

Electrochemical water splitting to produce hydrogen fuel is a promising renewable energy-conversion technique. Large-scale electrolysis of freshwater may deplete water resources and cause water scarcity worldwide. Thus, seawater electrolysis is a potential solution to the future energy and water crisis. In seawater electrolysis, it is critical to develop cost-effective electrocatalysts to split seawater without chloride corrosion. Herein, we present zinc-doped nickel iron (oxy)hydroxide nanocubes passivated by negatively charged polyanions (NFZ-PBA-S) that exhibits outstanding catalytic activity, stability, and selectivity for seawater oxidation. Zn dopants and polyanion-rich passivated surface layers in NFZ-PBA-S could effectively repel chlorine ions and enhance corrosion resistance, enabling its excellent catalytic activity and stability for seawater oxidation.

Original language	English
Pages (from-to)	82-92
Number of pages	11
Journal	Journal of Energy Chemistry
Volume	81
DOIs	https://doi.org/10.1016/j.jechem.2023.02.033
State	Published - Jun 2023
Externally published	Yes

Keywords

Electrocatalyst
Layered double hydroxide
Oxygen evolution reaction
Seawater splitting
Sulfidation

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1016/j.jechem.2023.02.033

Cite this

Jung Kim, S., Choi, H., Ho Ryu, J., Min Kim, K., Mhin, S., Kumar Nayak, A., Bang, J., Je, M., Ali, G., Yoon Chung, K., Na, K. H., Choi, W. Y., Yeo, S., Uk Jang, J., & Han, H. S. (2023). Zn-doped nickel iron (oxy)hydroxide nanocubes passivated by polyanions with high catalytic activity and corrosion resistance for seawater oxidation. Journal of Energy Chemistry, 81, 82-92. https://doi.org/10.1016/j.jechem.2023.02.033

@article{9f7231599ec44c11a26a57ecfb391ca6,

title = "Zn-doped nickel iron (oxy)hydroxide nanocubes passivated by polyanions with high catalytic activity and corrosion resistance for seawater oxidation",

abstract = "Electrochemical water splitting to produce hydrogen fuel is a promising renewable energy-conversion technique. Large-scale electrolysis of freshwater may deplete water resources and cause water scarcity worldwide. Thus, seawater electrolysis is a potential solution to the future energy and water crisis. In seawater electrolysis, it is critical to develop cost-effective electrocatalysts to split seawater without chloride corrosion. Herein, we present zinc-doped nickel iron (oxy)hydroxide nanocubes passivated by negatively charged polyanions (NFZ-PBA-S) that exhibits outstanding catalytic activity, stability, and selectivity for seawater oxidation. Zn dopants and polyanion-rich passivated surface layers in NFZ-PBA-S could effectively repel chlorine ions and enhance corrosion resistance, enabling its excellent catalytic activity and stability for seawater oxidation.",

keywords = "Electrocatalyst, Layered double hydroxide, Oxygen evolution reaction, Seawater splitting, Sulfidation",

author = "\{Jung Kim\}, So and Heechae Choi and \{Ho Ryu\}, Jeong and \{Min Kim\}, Kang and Sungwook Mhin and \{Kumar Nayak\}, Arpan and Junghwan Bang and Minyeong Je and Ghulam Ali and \{Yoon Chung\}, Kyung and Na, \{Kyeong Han\} and Choi, \{Won Youl\} and Sunghwan Yeo and \{Uk Jang\}, Jin and Han, \{Hyuk Su\}",

note = "Publisher Copyright: {\textcopyright} 2023 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences",

year = "2023",

month = jun,

doi = "10.1016/j.jechem.2023.02.033",

language = "English",

volume = "81",

pages = "82--92",

journal = "Journal of Energy Chemistry",

issn = "2095-4956",

publisher = "Elsevier B.V.",

}

Jung Kim, S, Choi, H, Ho Ryu, J, Min Kim, K, Mhin, S, Kumar Nayak, A, Bang, J, Je, M, Ali, G, Yoon Chung, K, Na, KH, Choi, WY, Yeo, S, Uk Jang, J & Han, HS 2023, 'Zn-doped nickel iron (oxy)hydroxide nanocubes passivated by polyanions with high catalytic activity and corrosion resistance for seawater oxidation', Journal of Energy Chemistry, vol. 81, pp. 82-92. https://doi.org/10.1016/j.jechem.2023.02.033

TY - JOUR

T1 - Zn-doped nickel iron (oxy)hydroxide nanocubes passivated by polyanions with high catalytic activity and corrosion resistance for seawater oxidation

AU - Jung Kim, So

AU - Choi, Heechae

AU - Ho Ryu, Jeong

AU - Min Kim, Kang

AU - Mhin, Sungwook

AU - Kumar Nayak, Arpan

AU - Bang, Junghwan

AU - Je, Minyeong

AU - Ali, Ghulam

AU - Yoon Chung, Kyung

AU - Na, Kyeong Han

AU - Choi, Won Youl

AU - Yeo, Sunghwan

AU - Uk Jang, Jin

AU - Han, Hyuk Su

PY - 2023/6

Y1 - 2023/6

N2 - Electrochemical water splitting to produce hydrogen fuel is a promising renewable energy-conversion technique. Large-scale electrolysis of freshwater may deplete water resources and cause water scarcity worldwide. Thus, seawater electrolysis is a potential solution to the future energy and water crisis. In seawater electrolysis, it is critical to develop cost-effective electrocatalysts to split seawater without chloride corrosion. Herein, we present zinc-doped nickel iron (oxy)hydroxide nanocubes passivated by negatively charged polyanions (NFZ-PBA-S) that exhibits outstanding catalytic activity, stability, and selectivity for seawater oxidation. Zn dopants and polyanion-rich passivated surface layers in NFZ-PBA-S could effectively repel chlorine ions and enhance corrosion resistance, enabling its excellent catalytic activity and stability for seawater oxidation.

AB - Electrochemical water splitting to produce hydrogen fuel is a promising renewable energy-conversion technique. Large-scale electrolysis of freshwater may deplete water resources and cause water scarcity worldwide. Thus, seawater electrolysis is a potential solution to the future energy and water crisis. In seawater electrolysis, it is critical to develop cost-effective electrocatalysts to split seawater without chloride corrosion. Herein, we present zinc-doped nickel iron (oxy)hydroxide nanocubes passivated by negatively charged polyanions (NFZ-PBA-S) that exhibits outstanding catalytic activity, stability, and selectivity for seawater oxidation. Zn dopants and polyanion-rich passivated surface layers in NFZ-PBA-S could effectively repel chlorine ions and enhance corrosion resistance, enabling its excellent catalytic activity and stability for seawater oxidation.

KW - Electrocatalyst

KW - Layered double hydroxide

KW - Oxygen evolution reaction

KW - Seawater splitting

KW - Sulfidation

UR - https://www.scopus.com/pages/publications/85150031438

U2 - 10.1016/j.jechem.2023.02.033

DO - 10.1016/j.jechem.2023.02.033

M3 - Article

AN - SCOPUS:85150031438

SN - 2095-4956

VL - 81

SP - 82

EP - 92

JO - Journal of Energy Chemistry

JF - Journal of Energy Chemistry

ER -

Zn-doped nickel iron (oxy)hydroxide nanocubes passivated by polyanions with high catalytic activity and corrosion resistance for seawater oxidation

Abstract

Keywords

UN SDGs

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