Two new [Cd(CN)2]n frameworks with linear channels of large, elongated hexagonal cross-section: Structures of cadmium cyanide-guest (guest = dmf and Me2SO) clathrates

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Abstract

Two new [Cd(CN)2]n frameworks with linear channels of large, elongated hexagonal cross-section have been discovered in cadmium cyanide-guest (guest = dmf or Me2SO) clathrates; the framework in the latter clathrate is the first example of a 3-D net comprising octahedral and tetrahedral cadmium centres in a 2: 1 ratio.

Original languageEnglish
Pages (from-to)637-638
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number5
DOIs
StatePublished - 1994

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