Triply interpenetrating coordination polymers based on paddle-wheel type secondary-building units

Soon W. Lee; Hye Jin Kim; Yeon Kyoung Lee; Kyungsoo Park; Jung Ho Son; Young Uk Kwon

doi:10.1016/S0020-1693(03)00246-9

Triply interpenetrating coordination polymers based on paddle-wheel type secondary-building units

Soon W. Lee
, Hye Jin Kim
, Yeon Kyoung Lee
, Kyungsoo Park
, Jung Ho Son
, Young Uk Kwon

Department of Chemistry

Sungkyunkwan University

Research output: Contribution to journal › Article › peer-review

97 Scopus citations

Abstract

Triply interpenetrating 3-dimensional nickel and cobalt coordination polymers, [M₃(2,6-NDC)₃(bipy)_1.5], were prepared from metal nitrate {M(NO₃)₂·6H ₂O}, 2,6-naphthalenedicarboxylic acid (2,6-NDCH₂), and 4,4′-bipyridine (bipy) under hydrothermal (M=Ni) or water-benzene hydro(solvo)thermal (M=Co) conditions. Both polymers have the same secondary building units (SBUs) of paddle-wheels of the type [M₂(CO ₂R)₄], which are composed of two metals and four di(monodentate) bridging carboxylates. On the other hand, the hydrothermal reaction of Co(NO₃)₂·6H₂O with 1,3-benzenedicarboxylic acid (1,3-BDCH₂) and trans-1,2-bis(4-pyridyl)ethylene (bipyen) gave a 2-dimensional polymer [Co(1,3-BDC)(bipyen)]. The structures of all products were determined by X-ray diffraction.

Original language	English
Pages (from-to)	151-158
Number of pages	8
Journal	Inorganica Chimica Acta
Volume	353
DOIs	https://doi.org/10.1016/S0020-1693(03)00246-9
State	Published - 8 Sep 2003

Keywords

Coordination polymers
Paddle wheels
SBU
Triply interpenetrating

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10.1016/S0020-1693(03)00246-9

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@article{0025de58a6bc4fd6b7b3051d77f160fc,

title = "Triply interpenetrating coordination polymers based on paddle-wheel type secondary-building units",

abstract = "Triply interpenetrating 3-dimensional nickel and cobalt coordination polymers, [M3(2,6-NDC)3(bipy)1.5], were prepared from metal nitrate \{M(NO3)2·6H 2O\}, 2,6-naphthalenedicarboxylic acid (2,6-NDCH2), and 4,4′-bipyridine (bipy) under hydrothermal (M=Ni) or water-benzene hydro(solvo)thermal (M=Co) conditions. Both polymers have the same secondary building units (SBUs) of paddle-wheels of the type [M2(CO 2R)4], which are composed of two metals and four di(monodentate) bridging carboxylates. On the other hand, the hydrothermal reaction of Co(NO3)2·6H2O with 1,3-benzenedicarboxylic acid (1,3-BDCH2) and trans-1,2-bis(4-pyridyl)ethylene (bipyen) gave a 2-dimensional polymer [Co(1,3-BDC)(bipyen)]. The structures of all products were determined by X-ray diffraction.",

keywords = "Coordination polymers, Paddle wheels, SBU, Triply interpenetrating",

author = "Lee, \{Soon W.\} and Kim, \{Hye Jin\} and Lee, \{Yeon Kyoung\} and Kyungsoo Park and Son, \{Jung Ho\} and Kwon, \{Young Uk\}",

year = "2003",

month = sep,

day = "8",

doi = "10.1016/S0020-1693(03)00246-9",

language = "English",

volume = "353",

pages = "151--158",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - Triply interpenetrating coordination polymers based on paddle-wheel type secondary-building units

AU - Lee, Soon W.

AU - Kim, Hye Jin

AU - Lee, Yeon Kyoung

AU - Park, Kyungsoo

AU - Son, Jung Ho

AU - Kwon, Young Uk

PY - 2003/9/8

Y1 - 2003/9/8

N2 - Triply interpenetrating 3-dimensional nickel and cobalt coordination polymers, [M3(2,6-NDC)3(bipy)1.5], were prepared from metal nitrate {M(NO3)2·6H 2O}, 2,6-naphthalenedicarboxylic acid (2,6-NDCH2), and 4,4′-bipyridine (bipy) under hydrothermal (M=Ni) or water-benzene hydro(solvo)thermal (M=Co) conditions. Both polymers have the same secondary building units (SBUs) of paddle-wheels of the type [M2(CO 2R)4], which are composed of two metals and four di(monodentate) bridging carboxylates. On the other hand, the hydrothermal reaction of Co(NO3)2·6H2O with 1,3-benzenedicarboxylic acid (1,3-BDCH2) and trans-1,2-bis(4-pyridyl)ethylene (bipyen) gave a 2-dimensional polymer [Co(1,3-BDC)(bipyen)]. The structures of all products were determined by X-ray diffraction.

AB - Triply interpenetrating 3-dimensional nickel and cobalt coordination polymers, [M3(2,6-NDC)3(bipy)1.5], were prepared from metal nitrate {M(NO3)2·6H 2O}, 2,6-naphthalenedicarboxylic acid (2,6-NDCH2), and 4,4′-bipyridine (bipy) under hydrothermal (M=Ni) or water-benzene hydro(solvo)thermal (M=Co) conditions. Both polymers have the same secondary building units (SBUs) of paddle-wheels of the type [M2(CO 2R)4], which are composed of two metals and four di(monodentate) bridging carboxylates. On the other hand, the hydrothermal reaction of Co(NO3)2·6H2O with 1,3-benzenedicarboxylic acid (1,3-BDCH2) and trans-1,2-bis(4-pyridyl)ethylene (bipyen) gave a 2-dimensional polymer [Co(1,3-BDC)(bipyen)]. The structures of all products were determined by X-ray diffraction.

KW - Coordination polymers

KW - Paddle wheels

KW - SBU

KW - Triply interpenetrating

UR - https://www.scopus.com/pages/publications/0141483729

U2 - 10.1016/S0020-1693(03)00246-9

DO - 10.1016/S0020-1693(03)00246-9

M3 - Article

AN - SCOPUS:0141483729

SN - 0020-1693

VL - 353

SP - 151

EP - 158

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

ER -

Triply interpenetrating coordination polymers based on paddle-wheel type secondary-building units

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