TY - JOUR
T1 - Triply interpenetrating coordination polymers based on paddle-wheel type secondary-building units
AU - Lee, Soon W.
AU - Kim, Hye Jin
AU - Lee, Yeon Kyoung
AU - Park, Kyungsoo
AU - Son, Jung Ho
AU - Kwon, Young Uk
PY - 2003/9/8
Y1 - 2003/9/8
N2 - Triply interpenetrating 3-dimensional nickel and cobalt coordination polymers, [M3(2,6-NDC)3(bipy)1.5], were prepared from metal nitrate {M(NO3)2·6H 2O}, 2,6-naphthalenedicarboxylic acid (2,6-NDCH2), and 4,4′-bipyridine (bipy) under hydrothermal (M=Ni) or water-benzene hydro(solvo)thermal (M=Co) conditions. Both polymers have the same secondary building units (SBUs) of paddle-wheels of the type [M2(CO 2R)4], which are composed of two metals and four di(monodentate) bridging carboxylates. On the other hand, the hydrothermal reaction of Co(NO3)2·6H2O with 1,3-benzenedicarboxylic acid (1,3-BDCH2) and trans-1,2-bis(4-pyridyl)ethylene (bipyen) gave a 2-dimensional polymer [Co(1,3-BDC)(bipyen)]. The structures of all products were determined by X-ray diffraction.
AB - Triply interpenetrating 3-dimensional nickel and cobalt coordination polymers, [M3(2,6-NDC)3(bipy)1.5], were prepared from metal nitrate {M(NO3)2·6H 2O}, 2,6-naphthalenedicarboxylic acid (2,6-NDCH2), and 4,4′-bipyridine (bipy) under hydrothermal (M=Ni) or water-benzene hydro(solvo)thermal (M=Co) conditions. Both polymers have the same secondary building units (SBUs) of paddle-wheels of the type [M2(CO 2R)4], which are composed of two metals and four di(monodentate) bridging carboxylates. On the other hand, the hydrothermal reaction of Co(NO3)2·6H2O with 1,3-benzenedicarboxylic acid (1,3-BDCH2) and trans-1,2-bis(4-pyridyl)ethylene (bipyen) gave a 2-dimensional polymer [Co(1,3-BDC)(bipyen)]. The structures of all products were determined by X-ray diffraction.
KW - Coordination polymers
KW - Paddle wheels
KW - SBU
KW - Triply interpenetrating
UR - https://www.scopus.com/pages/publications/0141483729
U2 - 10.1016/S0020-1693(03)00246-9
DO - 10.1016/S0020-1693(03)00246-9
M3 - Article
AN - SCOPUS:0141483729
SN - 0020-1693
VL - 353
SP - 151
EP - 158
JO - Inorganica Chimica Acta
JF - Inorganica Chimica Acta
ER -