Triflimide activation of a chiral oxazaborolidine leads to a more general catalytic system for enantioselective Diels-Alder addition

Do Hyun Ryu; E. J. Corey

doi:10.1021/ja035393r

Triflimide activation of a chiral oxazaborolidine leads to a more general catalytic system for enantioselective Diels-Alder addition

Do Hyun Ryu
, E. J. Corey

Harvard University

Research output: Contribution to journal › Article › peer-review

233 Scopus citations

Abstract

The strong acid triflimide ((CF₃SO₂)₂NH) protonates chiral oxazaborolidines to form superactive, stable, chiral Lewis acids which are highly effective catalysts for a wide variety of enantioselective Diels-Alder reactions, documented herein by more than 20 examples.

Original language	English
Pages (from-to)	6388-6390
Number of pages	3
Journal	Journal of the American Chemical Society
Volume	125
Issue number	21
DOIs	https://doi.org/10.1021/ja035393r
State	Published - 28 May 2003
Externally published	Yes

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title = "Triflimide activation of a chiral oxazaborolidine leads to a more general catalytic system for enantioselective Diels-Alder addition",

abstract = "The strong acid triflimide ((CF3SO2)2NH) protonates chiral oxazaborolidines to form superactive, stable, chiral Lewis acids which are highly effective catalysts for a wide variety of enantioselective Diels-Alder reactions, documented herein by more than 20 examples.",

author = "Ryu, \{Do Hyun\} and Corey, \{E. J.\}",

year = "2003",

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doi = "10.1021/ja035393r",

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T1 - Triflimide activation of a chiral oxazaborolidine leads to a more general catalytic system for enantioselective Diels-Alder addition

AU - Ryu, Do Hyun

AU - Corey, E. J.

PY - 2003/5/28

Y1 - 2003/5/28

N2 - The strong acid triflimide ((CF3SO2)2NH) protonates chiral oxazaborolidines to form superactive, stable, chiral Lewis acids which are highly effective catalysts for a wide variety of enantioselective Diels-Alder reactions, documented herein by more than 20 examples.

AB - The strong acid triflimide ((CF3SO2)2NH) protonates chiral oxazaborolidines to form superactive, stable, chiral Lewis acids which are highly effective catalysts for a wide variety of enantioselective Diels-Alder reactions, documented herein by more than 20 examples.

UR - https://www.scopus.com/pages/publications/0038514123

U2 - 10.1021/ja035393r

DO - 10.1021/ja035393r

M3 - Article

C2 - 12785777

AN - SCOPUS:0038514123

SN - 0002-7863

VL - 125

SP - 6388

EP - 6390

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 21

ER -

Triflimide activation of a chiral oxazaborolidine leads to a more general catalytic system for enantioselective Diels-Alder addition

Abstract

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