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Transparent ITO/Ag-Pd-Cu/ITO multilayer cathode use in inverted organic solar cells

  • Hyo Joong Kim
  • , Hyun Hwi Lee
  • , Jinha Kal
  • , Jungseok Hahn
  • , Han Ki Kim
  • Kyung Hee University
  • Pohang Accelerator Laboratory
  • Kolon Industries, Inc.

Research output: Contribution to journalArticlepeer-review

Abstract

The characteristics of transparent ITO/Ag-Pd-Cu (APC)/ITO multilayer cathodes were investigated for use in inverted organic solar cells (IOSCs). The insertion of an APC interlayer into the ITO film effectively led to crystallization of the top ITO layer, unlike that in the Ag interlayer, and resulted in a low sheet resistance of 6.55 Ohm/square and a high optical transmittance of 84.14% without post annealing. In addition, the alloying of the Pd and Cu elements into Ag prevented agglomeration and oxidization of the metal interlayer and led to more stable ITO/APC/ITO films under ambient conditions. The microstructure and interfacial structure of the transparent ITO/APC/ITO cathode in the IOSCs were examined in detail by synchrotron X-ray scattering and high resolution transmission electron microscopy. Furthermore, we suggested a possible mechanism to explain the lower PCE of the IOSCs with an ITO/APC/ITO cathode than that of a reference IOSC with a crystalline ITO cathode using the external quantum efficiency of the IOSCs.

Original languageEnglish
Article number107236
JournalAIP Advances
Volume5
Issue number10
DOIs
StatePublished - 1 Oct 2015
Externally publishedYes

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

  1. SDG 7 - Affordable and Clean Energy
    SDG 7 Affordable and Clean Energy

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