Thermal decomposition kinetics of hydrazinium cerium 2,3- pyrazinedicarboxylate hydrate: A new precursor for CeO 2

Thathan Premkumar; Subbiah Govindarajan; Andrew E. Coles; Charles A. Wight

doi:10.1021/jp0445223

Thermal decomposition kinetics of hydrazinium cerium 2,3- pyrazinedicarboxylate hydrate: A new precursor for CeO ₂

Thathan Premkumar, Subbiah Govindarajan, Andrew E. Coles, Charles A. Wight

Research output: Contribution to journal › Article › peer-review

28 Scopus citations

Abstract

The thermal decomposition kinetics of N ₂H ₅[Ce(pyrazine-2,3-dicarboxylate) ₂(H ₂O)] (Ce-P) have been studied by thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC), for the first time; TGA analysis reveals an oxidative decomposition process yielding CeO ₂ as the final product with an activation energy of ∼160 kJ mol ^-1. This complex may be used as a precursor to fine particle cerium oxides due to its low temperature of decomposition.

Original language	English
Pages (from-to)	6126-6129
Number of pages	4
Journal	Journal of Physical Chemistry B
Volume	109
Issue number	13
DOIs	https://doi.org/10.1021/jp0445223
State	Published - 7 Apr 2005
Externally published	Yes

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title = "Thermal decomposition kinetics of hydrazinium cerium 2,3- pyrazinedicarboxylate hydrate: A new precursor for CeO 2",

abstract = "The thermal decomposition kinetics of N 2H 5[Ce(pyrazine-2,3-dicarboxylate) 2(H 2O)] (Ce-P) have been studied by thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC), for the first time; TGA analysis reveals an oxidative decomposition process yielding CeO 2 as the final product with an activation energy of ∼160 kJ mol -1. This complex may be used as a precursor to fine particle cerium oxides due to its low temperature of decomposition.",

author = "Thathan Premkumar and Subbiah Govindarajan and Coles, \{Andrew E.\} and Wight, \{Charles A.\}",

year = "2005",

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doi = "10.1021/jp0445223",

language = "English",

volume = "109",

pages = "6126--6129",

journal = "Journal of Physical Chemistry B",

issn = "1520-6106",

publisher = "American Chemical Society",

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TY - JOUR

T1 - Thermal decomposition kinetics of hydrazinium cerium 2,3- pyrazinedicarboxylate hydrate

T2 - A new precursor for CeO 2

AU - Premkumar, Thathan

AU - Govindarajan, Subbiah

AU - Coles, Andrew E.

AU - Wight, Charles A.

PY - 2005/4/7

Y1 - 2005/4/7

N2 - The thermal decomposition kinetics of N 2H 5[Ce(pyrazine-2,3-dicarboxylate) 2(H 2O)] (Ce-P) have been studied by thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC), for the first time; TGA analysis reveals an oxidative decomposition process yielding CeO 2 as the final product with an activation energy of ∼160 kJ mol -1. This complex may be used as a precursor to fine particle cerium oxides due to its low temperature of decomposition.

AB - The thermal decomposition kinetics of N 2H 5[Ce(pyrazine-2,3-dicarboxylate) 2(H 2O)] (Ce-P) have been studied by thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC), for the first time; TGA analysis reveals an oxidative decomposition process yielding CeO 2 as the final product with an activation energy of ∼160 kJ mol -1. This complex may be used as a precursor to fine particle cerium oxides due to its low temperature of decomposition.

UR - https://www.scopus.com/pages/publications/17044371982

U2 - 10.1021/jp0445223

DO - 10.1021/jp0445223

M3 - Article

AN - SCOPUS:17044371982

SN - 1520-6106

VL - 109

SP - 6126

EP - 6129

JO - Journal of Physical Chemistry B

JF - Journal of Physical Chemistry B

IS - 13

ER -

Thermal decomposition kinetics of hydrazinium cerium 2,3- pyrazinedicarboxylate hydrate: A new precursor for CeO ₂

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