The porous CuO electrode fabricated by hydrogen bubble evolution and its application to highly sensitive non-enzymatic glucose detection

Serhiy Cherevko; Chan Hwa Chung

doi:10.1016/j.talanta.2009.09.038

The porous CuO electrode fabricated by hydrogen bubble evolution and its application to highly sensitive non-enzymatic glucose detection

Serhiy Cherevko
, Chan Hwa Chung

Department of Chemical Engineering

Sungkyunkwan University

Research output: Contribution to journal › Article › peer-review

141 Scopus citations

Abstract

The porous Cu film was deposited on a Pt/Ti/Si substrate by electrochemical deposition accompanied by hydrogen evolution at very high current densities. CuO films with similar morphologies were obtained by subsequent annealing of the porous copper films. The morphology, composition and structure of the porous Cu and porous CuO were investigated by FE-SEM, EDS and XRD methods. The complete transformation of Cu to CuO after annealing was indicated. The sensing performances of the porous CuO film were evaluated in alkaline solution with the porous CuO film showing a wide linearity range from 1 μM to 2.5 mM with sensitivity of 2.9 mA cm^-2 mM^-1, and detection limit of 0.14 μM. The sensor showed good selectivity to conventional intermediates such as AA and UA and long term stability.

Original language	English
Pages (from-to)	1371-1377
Number of pages	7
Journal	Talanta
Volume	80
Issue number	3
DOIs	https://doi.org/10.1016/j.talanta.2009.09.038
State	Published - Jan 2010

Keywords

Amperometry
Copper oxide
Glucose
Non-enzymatic sensor
Porous film

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1016/j.talanta.2009.09.038

Cite this

@article{44055cf6f83d4a129de0abd1308238d1,

title = "The porous CuO electrode fabricated by hydrogen bubble evolution and its application to highly sensitive non-enzymatic glucose detection",

abstract = "The porous Cu film was deposited on a Pt/Ti/Si substrate by electrochemical deposition accompanied by hydrogen evolution at very high current densities. CuO films with similar morphologies were obtained by subsequent annealing of the porous copper films. The morphology, composition and structure of the porous Cu and porous CuO were investigated by FE-SEM, EDS and XRD methods. The complete transformation of Cu to CuO after annealing was indicated. The sensing performances of the porous CuO film were evaluated in alkaline solution with the porous CuO film showing a wide linearity range from 1 μM to 2.5 mM with sensitivity of 2.9 mA cm-2 mM-1, and detection limit of 0.14 μM. The sensor showed good selectivity to conventional intermediates such as AA and UA and long term stability.",

keywords = "Amperometry, Copper oxide, Glucose, Non-enzymatic sensor, Porous film",

author = "Serhiy Cherevko and Chung, \{Chan Hwa\}",

year = "2010",

month = jan,

doi = "10.1016/j.talanta.2009.09.038",

language = "English",

volume = "80",

pages = "1371--1377",

journal = "Talanta",

issn = "0039-9140",

publisher = "Elsevier B.V.",

number = "3",

}

TY - JOUR

T1 - The porous CuO electrode fabricated by hydrogen bubble evolution and its application to highly sensitive non-enzymatic glucose detection

AU - Cherevko, Serhiy

AU - Chung, Chan Hwa

PY - 2010/1

Y1 - 2010/1

N2 - The porous Cu film was deposited on a Pt/Ti/Si substrate by electrochemical deposition accompanied by hydrogen evolution at very high current densities. CuO films with similar morphologies were obtained by subsequent annealing of the porous copper films. The morphology, composition and structure of the porous Cu and porous CuO were investigated by FE-SEM, EDS and XRD methods. The complete transformation of Cu to CuO after annealing was indicated. The sensing performances of the porous CuO film were evaluated in alkaline solution with the porous CuO film showing a wide linearity range from 1 μM to 2.5 mM with sensitivity of 2.9 mA cm-2 mM-1, and detection limit of 0.14 μM. The sensor showed good selectivity to conventional intermediates such as AA and UA and long term stability.

AB - The porous Cu film was deposited on a Pt/Ti/Si substrate by electrochemical deposition accompanied by hydrogen evolution at very high current densities. CuO films with similar morphologies were obtained by subsequent annealing of the porous copper films. The morphology, composition and structure of the porous Cu and porous CuO were investigated by FE-SEM, EDS and XRD methods. The complete transformation of Cu to CuO after annealing was indicated. The sensing performances of the porous CuO film were evaluated in alkaline solution with the porous CuO film showing a wide linearity range from 1 μM to 2.5 mM with sensitivity of 2.9 mA cm-2 mM-1, and detection limit of 0.14 μM. The sensor showed good selectivity to conventional intermediates such as AA and UA and long term stability.

KW - Amperometry

KW - Copper oxide

KW - Glucose

KW - Non-enzymatic sensor

KW - Porous film

UR - https://www.scopus.com/pages/publications/71649114307

U2 - 10.1016/j.talanta.2009.09.038

DO - 10.1016/j.talanta.2009.09.038

M3 - Article

C2 - 20006101

AN - SCOPUS:71649114307

SN - 0039-9140

VL - 80

SP - 1371

EP - 1377

JO - Talanta

JF - Talanta

IS - 3

ER -

The porous CuO electrode fabricated by hydrogen bubble evolution and its application to highly sensitive non-enzymatic glucose detection

Abstract

Keywords

UN SDGs

Access to Document

Other files and links

Fingerprint

Cite this