Template-free anion-controlled synthesis of Pd (II) nano-aggregates for the antifouling polymerization of CO and ethylene

Yu Na Lim; Soo Kyung Chae; Woongbin Yim; Ji Yong Park; Woojin Yoon; Hoseop Yun; Eunha Kim; Seung Uk Son; Hye Young Jang

doi:10.1002/aoc.4761

Template-free anion-controlled synthesis of Pd (II) nano-aggregates for the antifouling polymerization of CO and ethylene

Yu Na Lim
, Soo Kyung Chae
, Woongbin Yim
, Ji Yong Park
, Woojin Yoon
, Hoseop Yun
, Eunha Kim
, Seung Uk Son
, Hye Young Jang

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

The reaction of [(domppp) Pd (OAc) ₂ ] [domppp = 1,3-bis (di-o-methoxyphenylphosphino)propane] and imidazolium-functionalized carboxylic acids containing various anions (Br ⁻ , PF ₆ ⁻ , SbF ₆ ⁻ and BF ₄ ⁻ ) resulted in the formation of nano-sized Pd (II) aggregates under template-free conditions. The rate of formation of aggregates can be modulated by changing the anion, affecting the rate of polymerization of CO and olefins without fouling. Herein, we describe the analysis of Pd (II) catalysts by dynamic light scattering, atomic force microscopy, X-ray photoelectron spectroscopy and X-ray crystallography, and co- and terpolymerization results including the catalytic activity, and bulk density and molecular weight of polymers.

Original language	English
Article number	e4761
Journal	Applied Organometallic Chemistry
Volume	33
Issue number	3
DOIs	https://doi.org/10.1002/aoc.4761
State	Published - Mar 2019

Keywords

anion effect
antifouling
Pd (II) nano-aggregates
polyketone
template-free

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10.1002/aoc.4761

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@article{086001675b344f9f8b031673454e8822,

title = "Template-free anion-controlled synthesis of Pd (II) nano-aggregates for the antifouling polymerization of CO and ethylene",

abstract = " The reaction of [(domppp) Pd (OAc) 2 ] [domppp = 1,3-bis (di-o-methoxyphenylphosphino)propane] and imidazolium-functionalized carboxylic acids containing various anions (Br − , PF 6 − , SbF 6 − and BF 4 − ) resulted in the formation of nano-sized Pd (II) aggregates under template-free conditions. The rate of formation of aggregates can be modulated by changing the anion, affecting the rate of polymerization of CO and olefins without fouling. Herein, we describe the analysis of Pd (II) catalysts by dynamic light scattering, atomic force microscopy, X-ray photoelectron spectroscopy and X-ray crystallography, and co- and terpolymerization results including the catalytic activity, and bulk density and molecular weight of polymers.",

keywords = "anion effect, antifouling, Pd (II) nano-aggregates, polyketone, template-free",

author = "Lim, \{Yu Na\} and Chae, \{Soo Kyung\} and Woongbin Yim and Park, \{Ji Yong\} and Woojin Yoon and Hoseop Yun and Eunha Kim and Son, \{Seung Uk\} and Jang, \{Hye Young\}",

note = "Publisher Copyright: {\textcopyright} 2019 John Wiley \& Sons, Ltd.",

year = "2019",

month = mar,

doi = "10.1002/aoc.4761",

language = "English",

volume = "33",

journal = "Applied Organometallic Chemistry",

issn = "0268-2605",

publisher = "John Wiley and Sons Ltd",

number = "3",

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TY - JOUR

T1 - Template-free anion-controlled synthesis of Pd (II) nano-aggregates for the antifouling polymerization of CO and ethylene

AU - Lim, Yu Na

AU - Chae, Soo Kyung

AU - Yim, Woongbin

AU - Park, Ji Yong

AU - Yoon, Woojin

AU - Yun, Hoseop

AU - Kim, Eunha

AU - Son, Seung Uk

AU - Jang, Hye Young

PY - 2019/3

Y1 - 2019/3

N2 - The reaction of [(domppp) Pd (OAc) 2 ] [domppp = 1,3-bis (di-o-methoxyphenylphosphino)propane] and imidazolium-functionalized carboxylic acids containing various anions (Br − , PF 6 − , SbF 6 − and BF 4 − ) resulted in the formation of nano-sized Pd (II) aggregates under template-free conditions. The rate of formation of aggregates can be modulated by changing the anion, affecting the rate of polymerization of CO and olefins without fouling. Herein, we describe the analysis of Pd (II) catalysts by dynamic light scattering, atomic force microscopy, X-ray photoelectron spectroscopy and X-ray crystallography, and co- and terpolymerization results including the catalytic activity, and bulk density and molecular weight of polymers.

AB - The reaction of [(domppp) Pd (OAc) 2 ] [domppp = 1,3-bis (di-o-methoxyphenylphosphino)propane] and imidazolium-functionalized carboxylic acids containing various anions (Br − , PF 6 − , SbF 6 − and BF 4 − ) resulted in the formation of nano-sized Pd (II) aggregates under template-free conditions. The rate of formation of aggregates can be modulated by changing the anion, affecting the rate of polymerization of CO and olefins without fouling. Herein, we describe the analysis of Pd (II) catalysts by dynamic light scattering, atomic force microscopy, X-ray photoelectron spectroscopy and X-ray crystallography, and co- and terpolymerization results including the catalytic activity, and bulk density and molecular weight of polymers.

KW - anion effect

KW - antifouling

KW - Pd (II) nano-aggregates

KW - polyketone

KW - template-free

UR - https://www.scopus.com/pages/publications/85059550842

U2 - 10.1002/aoc.4761

DO - 10.1002/aoc.4761

M3 - Article

AN - SCOPUS:85059550842

SN - 0268-2605

VL - 33

JO - Applied Organometallic Chemistry

JF - Applied Organometallic Chemistry

IS - 3

M1 - e4761

ER -

Template-free anion-controlled synthesis of Pd (II) nano-aggregates for the antifouling polymerization of CO and ethylene

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Keywords

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