Synthesis, structure and thermal properties of a new 1D magnesium sulfoacetate coordination polymer: A precursor for MgO

Rajendran Selvakumar; Steven J. Geib; Thathan Premkumar; Subbiah Govindarajan

doi:10.1007/s10973-015-4572-6

Synthesis, structure and thermal properties of a new 1D magnesium sulfoacetate coordination polymer: A precursor for MgO

Rajendran Selvakumar
, Steven J. Geib
, Thathan Premkumar
, Subbiah Govindarajan

University College

Bharathiar University
University of Pittsburgh

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

Abstract A new one-dimensional polymeric complex [Mg(SA)(H₂O)₃], where SA = sulfoacetate, has been synthesised by reaction of Mg(NO₃)₂·6H₂O with sulfoacetic acid in the presence of hydrazine hydrate. The compound was characterized by elemental analysis and FT-IR spectroscopy as well as single-crystal X-ray crystallography. The compound crystallizes in the monoclinic P2₁/C space group with a = 6.5051(5) å, b = 8.9012(7) å, c = 13.5724(11) å, β = 90.530(2)°, and V = 785.85(11) å³. The crystal structure shows a one-dimensional chain propagated through bridging and chelating a tridentate sulfoacetate anion. Furthermore, the thermal stability of the compound was investigated by thermogravimetry and differential thermal analysis.

Original language	English
Article number	4572
Pages (from-to)	943-949
Number of pages	7
Journal	Journal of Thermal Analysis and Calorimetry
Volume	121
Issue number	2
DOIs	https://doi.org/10.1007/s10973-015-4572-6
State	Published - 22 Aug 2015

Keywords

Chemical synthesis
Crystal structure
Inorganic compounds
Oxides
X-ray diffraction

Access to Document

10.1007/s10973-015-4572-6

Cite this

@article{d09a2780a8d145a6af6dbaa8c426c038,

title = "Synthesis, structure and thermal properties of a new 1D magnesium sulfoacetate coordination polymer: A precursor for MgO",

abstract = "Abstract A new one-dimensional polymeric complex [Mg(SA)(H2O)3], where SA = sulfoacetate, has been synthesised by reaction of Mg(NO3)2·6H2O with sulfoacetic acid in the presence of hydrazine hydrate. The compound was characterized by elemental analysis and FT-IR spectroscopy as well as single-crystal X-ray crystallography. The compound crystallizes in the monoclinic P21/C space group with a = 6.5051(5) {\aa}, b = 8.9012(7) {\aa}, c = 13.5724(11) {\aa}, β = 90.530(2)°, and V = 785.85(11) {\aa}3. The crystal structure shows a one-dimensional chain propagated through bridging and chelating a tridentate sulfoacetate anion. Furthermore, the thermal stability of the compound was investigated by thermogravimetry and differential thermal analysis.",

keywords = "Chemical synthesis, Crystal structure, Inorganic compounds, Oxides, X-ray diffraction",

author = "Rajendran Selvakumar and Geib, \{Steven J.\} and Thathan Premkumar and Subbiah Govindarajan",

note = "Publisher Copyright: {\textcopyright} 2015 Akad{\'e}miai Kiad{\'o}, Budapest, Hungary.",

year = "2015",

month = aug,

day = "22",

doi = "10.1007/s10973-015-4572-6",

language = "English",

volume = "121",

pages = "943--949",

journal = "Journal of Thermal Analysis and Calorimetry",

issn = "1388-6150",

publisher = "Springer Science and Business Media B.V.",

number = "2",

}

TY - JOUR

T1 - Synthesis, structure and thermal properties of a new 1D magnesium sulfoacetate coordination polymer

T2 - A precursor for MgO

AU - Selvakumar, Rajendran

AU - Geib, Steven J.

AU - Premkumar, Thathan

AU - Govindarajan, Subbiah

PY - 2015/8/22

Y1 - 2015/8/22

N2 - Abstract A new one-dimensional polymeric complex [Mg(SA)(H2O)3], where SA = sulfoacetate, has been synthesised by reaction of Mg(NO3)2·6H2O with sulfoacetic acid in the presence of hydrazine hydrate. The compound was characterized by elemental analysis and FT-IR spectroscopy as well as single-crystal X-ray crystallography. The compound crystallizes in the monoclinic P21/C space group with a = 6.5051(5) å, b = 8.9012(7) å, c = 13.5724(11) å, β = 90.530(2)°, and V = 785.85(11) å3. The crystal structure shows a one-dimensional chain propagated through bridging and chelating a tridentate sulfoacetate anion. Furthermore, the thermal stability of the compound was investigated by thermogravimetry and differential thermal analysis.

AB - Abstract A new one-dimensional polymeric complex [Mg(SA)(H2O)3], where SA = sulfoacetate, has been synthesised by reaction of Mg(NO3)2·6H2O with sulfoacetic acid in the presence of hydrazine hydrate. The compound was characterized by elemental analysis and FT-IR spectroscopy as well as single-crystal X-ray crystallography. The compound crystallizes in the monoclinic P21/C space group with a = 6.5051(5) å, b = 8.9012(7) å, c = 13.5724(11) å, β = 90.530(2)°, and V = 785.85(11) å3. The crystal structure shows a one-dimensional chain propagated through bridging and chelating a tridentate sulfoacetate anion. Furthermore, the thermal stability of the compound was investigated by thermogravimetry and differential thermal analysis.

KW - Chemical synthesis

KW - Crystal structure

KW - Inorganic compounds

KW - Oxides

KW - X-ray diffraction

UR - https://www.scopus.com/pages/publications/84937526790

U2 - 10.1007/s10973-015-4572-6

DO - 10.1007/s10973-015-4572-6

M3 - Article

AN - SCOPUS:84937526790

SN - 1388-6150

VL - 121

SP - 943

EP - 949

JO - Journal of Thermal Analysis and Calorimetry

JF - Journal of Thermal Analysis and Calorimetry

IS - 2

M1 - 4572

ER -

Synthesis, structure and thermal properties of a new 1D magnesium sulfoacetate coordination polymer: A precursor for MgO

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this