TY - JOUR
T1 - Synthesis, characterization and X-ray crystal structure of the benzenedithiolatohafnium(IV) porphyrin complex
AU - Ryu, Sanghoon
AU - Whang, Dongmok
AU - Yeo, Hwanjin
AU - Kim, Kimoon
PY - 1994/6/15
Y1 - 1994/6/15
N2 - A novel hafnium porphyrin complex Hf(TPP)(bdt) (TPP=5,10,15,20-tetraphenylporphyrinate; bdt=benzenedithiolate) was synthesized and characterized. The X-ray crystal structure of the complex revealed a six-coordinate Hf atom surrounded by 4 N atoms of the porphyrin and 2 S atoms of the bdt ligand. The two sulfur atoms of the bdt are in an eclipsed position with respect to the two opposite pyrrole nitrogen atoms of the porphyrin. Crystal data for Hf(TPP)(bdt): tetragonal, P41212, a= 12.471(2), c= 26.966(3) Å, V= 4038.2(7) Å3, Z=4; R= 0.054 and Rw= 0.060 for 2673 independent reflections with I>3σ(I).
AB - A novel hafnium porphyrin complex Hf(TPP)(bdt) (TPP=5,10,15,20-tetraphenylporphyrinate; bdt=benzenedithiolate) was synthesized and characterized. The X-ray crystal structure of the complex revealed a six-coordinate Hf atom surrounded by 4 N atoms of the porphyrin and 2 S atoms of the bdt ligand. The two sulfur atoms of the bdt are in an eclipsed position with respect to the two opposite pyrrole nitrogen atoms of the porphyrin. Crystal data for Hf(TPP)(bdt): tetragonal, P41212, a= 12.471(2), c= 26.966(3) Å, V= 4038.2(7) Å3, Z=4; R= 0.054 and Rw= 0.060 for 2673 independent reflections with I>3σ(I).
KW - Crystal structures
KW - Dithiolato complexes
KW - Hafnium complexes
KW - Porphyrin complexes
UR - https://www.scopus.com/pages/publications/0003156006
U2 - 10.1016/0020-1693(94)03848-1
DO - 10.1016/0020-1693(94)03848-1
M3 - Article
AN - SCOPUS:0003156006
SN - 0020-1693
VL - 221
SP - 51
EP - 54
JO - Inorganica Chimica Acta
JF - Inorganica Chimica Acta
IS - 1-2
ER -