Synthesis and Structure of Novel Tin Complexes Containing Aminoalkoxide Ligands

Seong Ho Han; Eun Ae Jung; Ji Hun Lee; Da Hye Kim; Ga Yeon Lee; Bo Keun Park; Chang Gyoun Kim; Seung Uk Son; Taek Mo Chung

doi:10.1002/slct.201801375

Synthesis and Structure of Novel Tin Complexes Containing Aminoalkoxide Ligands

Seong Ho Han
, Eun Ae Jung
, Ji Hun Lee
, Da Hye Kim
, Ga Yeon Lee
, Bo Keun Park
, Chang Gyoun Kim
, Seung Uk Son
, Taek Mo Chung

Department of Chemistry

Korea Research Institute of Chemical Technology
Sungkyunkwan University
University of Science and Technology UST

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

In this work, novel aminoalkoxide tin(II) compounds, [3-(dimethylamino)propoxy]tin [Sn(dmap)₂] (1), [4-(dimethylamino)-2-methylbutoxy]tin [Sn(damb)₂] (2), [4-(dimethylamino)-2-methylpentoxy]tin [Sn(damp)₂] (3), and [4-(dimethylamino)-2, 3-dimethylbutoxy]tin [Sn(dadb)₂] (4), were prepared by reacting Sn[N(SiMe₃)₂]₂ with two molar equivalents of the respective aminoalcohols. The newly synthesized complexes were fully characterized by spectroscopic methods (IR, MS) and elemental analysis. The molecular structures of compounds 1 and 3 were further examined by single crystal X-ray diffraction analysis. The X-ray structures of 1 and 3 revealed that the former complex was triclinic with tin as the central metal ion in trigonal bipyramidal geometry with uncoordinated nitrogen atoms while the latter complex was monomeric with the tin center in trigonal bipyramidal geometry. Thermal properties of the precursors were analyzed by thermogravimetric analysis.

Original language	English
Pages (from-to)	7836-7839
Number of pages	4
Journal	ChemistrySelect
Volume	3
Issue number	27
DOIs	https://doi.org/10.1002/slct.201801375
State	Published - 23 Jul 2018

Keywords

Aminoalkoxide Ligand
Precursor
Thin Film
Tin
Tin Complex

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10.1002/slct.201801375

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@article{a030367c0f9e472fa977b4ea9b7b4877,

title = "Synthesis and Structure of Novel Tin Complexes Containing Aminoalkoxide Ligands",

abstract = "In this work, novel aminoalkoxide tin(II) compounds, [3-(dimethylamino)propoxy]tin [Sn(dmap)2] (1), [4-(dimethylamino)-2-methylbutoxy]tin [Sn(damb)2] (2), [4-(dimethylamino)-2-methylpentoxy]tin [Sn(damp)2] (3), and [4-(dimethylamino)-2, 3-dimethylbutoxy]tin [Sn(dadb)2] (4), were prepared by reacting Sn[N(SiMe3)2]2 with two molar equivalents of the respective aminoalcohols. The newly synthesized complexes were fully characterized by spectroscopic methods (IR, MS) and elemental analysis. The molecular structures of compounds 1 and 3 were further examined by single crystal X-ray diffraction analysis. The X-ray structures of 1 and 3 revealed that the former complex was triclinic with tin as the central metal ion in trigonal bipyramidal geometry with uncoordinated nitrogen atoms while the latter complex was monomeric with the tin center in trigonal bipyramidal geometry. Thermal properties of the precursors were analyzed by thermogravimetric analysis.",

keywords = "Aminoalkoxide Ligand, Precursor, Thin Film, Tin, Tin Complex",

author = "Han, \{Seong Ho\} and Jung, \{Eun Ae\} and Lee, \{Ji Hun\} and Kim, \{Da Hye\} and Lee, \{Ga Yeon\} and Park, \{Bo Keun\} and Kim, \{Chang Gyoun\} and Son, \{Seung Uk\} and Chung, \{Taek Mo\}",

note = "Publisher Copyright: {\textcopyright} 2018 Wiley-VCH Verlag GmbH \& Co. KGaA, Weinheim",

year = "2018",

month = jul,

day = "23",

doi = "10.1002/slct.201801375",

language = "English",

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pages = "7836--7839",

journal = "ChemistrySelect",

issn = "2365-6549",

publisher = "Wiley-Blackwell Publishing Ltd",

number = "27",

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TY - JOUR

T1 - Synthesis and Structure of Novel Tin Complexes Containing Aminoalkoxide Ligands

AU - Han, Seong Ho

AU - Jung, Eun Ae

AU - Lee, Ji Hun

AU - Kim, Da Hye

AU - Lee, Ga Yeon

AU - Park, Bo Keun

AU - Kim, Chang Gyoun

AU - Son, Seung Uk

AU - Chung, Taek Mo

PY - 2018/7/23

Y1 - 2018/7/23

N2 - In this work, novel aminoalkoxide tin(II) compounds, [3-(dimethylamino)propoxy]tin [Sn(dmap)2] (1), [4-(dimethylamino)-2-methylbutoxy]tin [Sn(damb)2] (2), [4-(dimethylamino)-2-methylpentoxy]tin [Sn(damp)2] (3), and [4-(dimethylamino)-2, 3-dimethylbutoxy]tin [Sn(dadb)2] (4), were prepared by reacting Sn[N(SiMe3)2]2 with two molar equivalents of the respective aminoalcohols. The newly synthesized complexes were fully characterized by spectroscopic methods (IR, MS) and elemental analysis. The molecular structures of compounds 1 and 3 were further examined by single crystal X-ray diffraction analysis. The X-ray structures of 1 and 3 revealed that the former complex was triclinic with tin as the central metal ion in trigonal bipyramidal geometry with uncoordinated nitrogen atoms while the latter complex was monomeric with the tin center in trigonal bipyramidal geometry. Thermal properties of the precursors were analyzed by thermogravimetric analysis.

AB - In this work, novel aminoalkoxide tin(II) compounds, [3-(dimethylamino)propoxy]tin [Sn(dmap)2] (1), [4-(dimethylamino)-2-methylbutoxy]tin [Sn(damb)2] (2), [4-(dimethylamino)-2-methylpentoxy]tin [Sn(damp)2] (3), and [4-(dimethylamino)-2, 3-dimethylbutoxy]tin [Sn(dadb)2] (4), were prepared by reacting Sn[N(SiMe3)2]2 with two molar equivalents of the respective aminoalcohols. The newly synthesized complexes were fully characterized by spectroscopic methods (IR, MS) and elemental analysis. The molecular structures of compounds 1 and 3 were further examined by single crystal X-ray diffraction analysis. The X-ray structures of 1 and 3 revealed that the former complex was triclinic with tin as the central metal ion in trigonal bipyramidal geometry with uncoordinated nitrogen atoms while the latter complex was monomeric with the tin center in trigonal bipyramidal geometry. Thermal properties of the precursors were analyzed by thermogravimetric analysis.

KW - Aminoalkoxide Ligand

KW - Precursor

KW - Thin Film

KW - Tin

KW - Tin Complex

UR - https://www.scopus.com/pages/publications/85050397875

U2 - 10.1002/slct.201801375

DO - 10.1002/slct.201801375

M3 - Article

AN - SCOPUS:85050397875

SN - 2365-6549

VL - 3

SP - 7836

EP - 7839

JO - ChemistrySelect

JF - ChemistrySelect

IS - 27

ER -

Synthesis and Structure of Novel Tin Complexes Containing Aminoalkoxide Ligands

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Keywords

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