Synthesis and spectroscopic, thermal, and XRD studies on trivalent lighter rare-earth complexes of 2,3-pyrazinedicorboxylate with hydrazinium cation

T. Premkumar; S. Govindarajan

doi:10.1016/j.inoche.2003.08.025

Synthesis and spectroscopic, thermal, and XRD studies on trivalent lighter rare-earth complexes of 2,3-pyrazinedicorboxylate with hydrazinium cation

T. Premkumar
, S. Govindarajan

Bharathiar University

Research output: Contribution to journal › Article › peer-review

18 Scopus citations

Abstract

Hydrazinium lanthanide 2,3-pyrazinedicarboxylate hydrates of composition (N₂H₅)[Ln(pyz(COO)₂)₂ (H ₂O) · nH₂O, (pyz(COO)₂ = 2,3-pyrazinedicarboxylate), where Ln = La, Pr and Nd if n = 4 and Ln = Sm, Dy and Ce if n = 0, have been prepared and characterized by physico-chemical methods.

Original language	English
Pages (from-to)	1385-1389
Number of pages	5
Journal	Inorganic Chemistry Communications
Volume	6
Issue number	11
DOIs	https://doi.org/10.1016/j.inoche.2003.08.025
State	Published - 1 Nov 2003
Externally published	Yes

Keywords

2,3-Pyrazinedicarboxylic acid
Hydrazinium cation
Infrared spectra
Rare-earth metals
Thermal studies

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10.1016/j.inoche.2003.08.025

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title = "Synthesis and spectroscopic, thermal, and XRD studies on trivalent lighter rare-earth complexes of 2,3-pyrazinedicorboxylate with hydrazinium cation",

abstract = "Hydrazinium lanthanide 2,3-pyrazinedicarboxylate hydrates of composition (N2H5)[Ln(pyz(COO)2)2 (H 2O) · nH2O, (pyz(COO)2 = 2,3-pyrazinedicarboxylate), where Ln = La, Pr and Nd if n = 4 and Ln = Sm, Dy and Ce if n = 0, have been prepared and characterized by physico-chemical methods.",

keywords = "2,3-Pyrazinedicarboxylic acid, Hydrazinium cation, Infrared spectra, Rare-earth metals, Thermal studies",

author = "T. Premkumar and S. Govindarajan",

year = "2003",

month = nov,

day = "1",

doi = "10.1016/j.inoche.2003.08.025",

language = "English",

volume = "6",

pages = "1385--1389",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

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TY - JOUR

T1 - Synthesis and spectroscopic, thermal, and XRD studies on trivalent lighter rare-earth complexes of 2,3-pyrazinedicorboxylate with hydrazinium cation

AU - Premkumar, T.

AU - Govindarajan, S.

PY - 2003/11/1

Y1 - 2003/11/1

N2 - Hydrazinium lanthanide 2,3-pyrazinedicarboxylate hydrates of composition (N2H5)[Ln(pyz(COO)2)2 (H 2O) · nH2O, (pyz(COO)2 = 2,3-pyrazinedicarboxylate), where Ln = La, Pr and Nd if n = 4 and Ln = Sm, Dy and Ce if n = 0, have been prepared and characterized by physico-chemical methods.

AB - Hydrazinium lanthanide 2,3-pyrazinedicarboxylate hydrates of composition (N2H5)[Ln(pyz(COO)2)2 (H 2O) · nH2O, (pyz(COO)2 = 2,3-pyrazinedicarboxylate), where Ln = La, Pr and Nd if n = 4 and Ln = Sm, Dy and Ce if n = 0, have been prepared and characterized by physico-chemical methods.

KW - 2,3-Pyrazinedicarboxylic acid

KW - Hydrazinium cation

KW - Infrared spectra

KW - Rare-earth metals

KW - Thermal studies

UR - https://www.scopus.com/pages/publications/0141955110

U2 - 10.1016/j.inoche.2003.08.025

DO - 10.1016/j.inoche.2003.08.025

M3 - Article

AN - SCOPUS:0141955110

SN - 1387-7003

VL - 6

SP - 1385

EP - 1389

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 11

ER -

Synthesis and spectroscopic, thermal, and XRD studies on trivalent lighter rare-earth complexes of 2,3-pyrazinedicorboxylate with hydrazinium cation

Abstract

Keywords

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