Synthesis and properties of poly(dipropargyl-16-crown-5)

H. N. Cho; J. Y. Lee; S. H. Kim; S. K. Choi; C. Y. Kim

doi:10.1007/BF00315054

Synthesis and properties of poly(dipropargyl-16-crown-5)

H. N. Cho
, J. Y. Lee
, S. H. Kim
, S. K. Choi
, C. Y. Kim

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

We have synthesized a polyacetylene derivative, poly(dipropargyl-16-crown-5), through the cyclopolymerization of the corresponding monomer by metathesis catalysts. The polymer containing crown-ether units was characterized by spectroscopic and thermal techniques. The polymer structure is believed to be a cyclized form with both five- and six-membered rings. The polymer exhibits high cation-binding properties and ionochromic effects. The order of the selectivity of alkali- metal cations for both the monomer and the polymer was found to be Na⁺ > K⁺ > Li⁺ and the polymer shows the largest red shift by approximately 40 nm in λ_maxfor Na⁺.

Original language	English
Pages (from-to)	391-398
Number of pages	8
Journal	Polymer Bulletin
Volume	36
Issue number	4
DOIs	https://doi.org/10.1007/BF00315054
State	Published - 1996
Externally published	Yes

Access to Document

10.1007/BF00315054

Cite this

@article{b3e5da8377f14c5990df4b57613de794,

title = "Synthesis and properties of poly(dipropargyl-16-crown-5)",

abstract = "We have synthesized a polyacetylene derivative, poly(dipropargyl-16-crown-5), through the cyclopolymerization of the corresponding monomer by metathesis catalysts. The polymer containing crown-ether units was characterized by spectroscopic and thermal techniques. The polymer structure is believed to be a cyclized form with both five- and six-membered rings. The polymer exhibits high cation-binding properties and ionochromic effects. The order of the selectivity of alkali- metal cations for both the monomer and the polymer was found to be Na+ > K+ > Li+ and the polymer shows the largest red shift by approximately 40 nm in λmaxfor Na+.",

author = "Cho, \{H. N.\} and Lee, \{J. Y.\} and Kim, \{S. H.\} and Choi, \{S. K.\} and Kim, \{C. Y.\}",

year = "1996",

doi = "10.1007/BF00315054",

language = "English",

volume = "36",

pages = "391--398",

journal = "Polymer Bulletin",

issn = "0170-0839",

publisher = "Springer Verlag",

number = "4",

}

TY - JOUR

T1 - Synthesis and properties of poly(dipropargyl-16-crown-5)

AU - Cho, H. N.

AU - Lee, J. Y.

AU - Kim, S. H.

AU - Choi, S. K.

AU - Kim, C. Y.

PY - 1996

Y1 - 1996

N2 - We have synthesized a polyacetylene derivative, poly(dipropargyl-16-crown-5), through the cyclopolymerization of the corresponding monomer by metathesis catalysts. The polymer containing crown-ether units was characterized by spectroscopic and thermal techniques. The polymer structure is believed to be a cyclized form with both five- and six-membered rings. The polymer exhibits high cation-binding properties and ionochromic effects. The order of the selectivity of alkali- metal cations for both the monomer and the polymer was found to be Na+ > K+ > Li+ and the polymer shows the largest red shift by approximately 40 nm in λmaxfor Na+.

AB - We have synthesized a polyacetylene derivative, poly(dipropargyl-16-crown-5), through the cyclopolymerization of the corresponding monomer by metathesis catalysts. The polymer containing crown-ether units was characterized by spectroscopic and thermal techniques. The polymer structure is believed to be a cyclized form with both five- and six-membered rings. The polymer exhibits high cation-binding properties and ionochromic effects. The order of the selectivity of alkali- metal cations for both the monomer and the polymer was found to be Na+ > K+ > Li+ and the polymer shows the largest red shift by approximately 40 nm in λmaxfor Na+.

UR - https://www.scopus.com/pages/publications/0343052261

U2 - 10.1007/BF00315054

DO - 10.1007/BF00315054

M3 - Article

AN - SCOPUS:0343052261

SN - 0170-0839

VL - 36

SP - 391

EP - 398

JO - Polymer Bulletin

JF - Polymer Bulletin

IS - 4

ER -

Synthesis and properties of poly(dipropargyl-16-crown-5)

Abstract

Access to Document

Other files and links

Fingerprint

Cite this