Synthesis and characterization of Sn complexes containing aminoalkoxide ligands for solution process

Sangmi Gu; Chan Mi Cho; Hae Sun Kim; Seung Uk Son; Taek Mo Chung; Bo Keun Park

doi:10.1080/15421406.2023.2165340

Synthesis and characterization of Sn complexes containing aminoalkoxide ligands for solution process

Sangmi Gu
, Chan Mi Cho
, Hae Sun Kim
, Seung Uk Son
, Taek Mo Chung
, Bo Keun Park

Department of Chemistry

Korea Research Institute of Chemical Technology
Sungkyunkwan University
Ruhr University Bochum
University of Science and Technology UST

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

The reaction of Sn(btsa)₂ and 2-(dimethylamino)-2-methylpropan-1-ol (dmamp’H) gave a mixture of Sn(dmamp’)₂ (1) and Sn₆(O)₄(dmamp’)₄ (2), in which the latter one could be purely isolated by recrystallization. The complex 2 was characterized by NMR, and elemental analysis (EA). Further structural determination was performed by single-crystal X-ray diffraction (XRD) analysis to reveal a cage-shaped cluster.

Original language	English
Pages (from-to)	44-50
Number of pages	7
Journal	Molecular Crystals and Liquid Crystals
Volume	760
Issue number	1
DOIs	https://doi.org/10.1080/15421406.2023.2165340
State	Published - 2023

Keywords

Single-crystal X-ray crystallography
solution process
tin
tin cluster
tin oxide

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10.1080/15421406.2023.2165340

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title = "Synthesis and characterization of Sn complexes containing aminoalkoxide ligands for solution process",

abstract = "The reaction of Sn(btsa)2 and 2-(dimethylamino)-2-methylpropan-1-ol (dmamp{\textquoteright}H) gave a mixture of Sn(dmamp{\textquoteright})2 (1) and Sn6(O)4(dmamp{\textquoteright})4 (2), in which the latter one could be purely isolated by recrystallization. The complex 2 was characterized by NMR, and elemental analysis (EA). Further structural determination was performed by single-crystal X-ray diffraction (XRD) analysis to reveal a cage-shaped cluster.",

keywords = "Single-crystal X-ray crystallography, solution process, tin, tin cluster, tin oxide",

author = "Sangmi Gu and Cho, \{Chan Mi\} and Kim, \{Hae Sun\} and Son, \{Seung Uk\} and Chung, \{Taek Mo\} and Park, \{Bo Keun\}",

note = "Publisher Copyright: {\textcopyright} 2023 Taylor \& Francis Group, LLC.",

year = "2023",

doi = "10.1080/15421406.2023.2165340",

language = "English",

volume = "760",

pages = "44--50",

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TY - JOUR

T1 - Synthesis and characterization of Sn complexes containing aminoalkoxide ligands for solution process

AU - Gu, Sangmi

AU - Cho, Chan Mi

AU - Kim, Hae Sun

AU - Son, Seung Uk

AU - Chung, Taek Mo

AU - Park, Bo Keun

PY - 2023

Y1 - 2023

N2 - The reaction of Sn(btsa)2 and 2-(dimethylamino)-2-methylpropan-1-ol (dmamp’H) gave a mixture of Sn(dmamp’)2 (1) and Sn6(O)4(dmamp’)4 (2), in which the latter one could be purely isolated by recrystallization. The complex 2 was characterized by NMR, and elemental analysis (EA). Further structural determination was performed by single-crystal X-ray diffraction (XRD) analysis to reveal a cage-shaped cluster.

AB - The reaction of Sn(btsa)2 and 2-(dimethylamino)-2-methylpropan-1-ol (dmamp’H) gave a mixture of Sn(dmamp’)2 (1) and Sn6(O)4(dmamp’)4 (2), in which the latter one could be purely isolated by recrystallization. The complex 2 was characterized by NMR, and elemental analysis (EA). Further structural determination was performed by single-crystal X-ray diffraction (XRD) analysis to reveal a cage-shaped cluster.

KW - Single-crystal X-ray crystallography

KW - solution process

KW - tin

KW - tin cluster

KW - tin oxide

UR - https://www.scopus.com/pages/publications/85146236626

U2 - 10.1080/15421406.2023.2165340

DO - 10.1080/15421406.2023.2165340

M3 - Article

AN - SCOPUS:85146236626

SN - 1542-1406

VL - 760

SP - 44

EP - 50

JO - Molecular Crystals and Liquid Crystals

JF - Molecular Crystals and Liquid Crystals

IS - 1

ER -

Synthesis and characterization of Sn complexes containing aminoalkoxide ligands for solution process

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