Synthesis and characterization of Sn complexes containing aminoalkoxide ligands for solution process

Sangmi Gu; Chan Mi Cho; Hae Sun Kim; Seung Uk Son; Taek Mo Chung; Bo Keun Park

doi:10.1080/15421406.2023.2165340

Synthesis and characterization of Sn complexes containing aminoalkoxide ligands for solution process

Sangmi Gu, Chan Mi Cho, Hae Sun Kim, Seung Uk Son, Taek Mo Chung, Bo Keun Park

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

The reaction of Sn(btsa)₂ and 2-(dimethylamino)-2-methylpropan-1-ol (dmamp’H) gave a mixture of Sn(dmamp’)₂ (1) and Sn₆(O)₄(dmamp’)₄ (2), in which the latter one could be purely isolated by recrystallization. The complex 2 was characterized by NMR, and elemental analysis (EA). Further structural determination was performed by single-crystal X-ray diffraction (XRD) analysis to reveal a cage-shaped cluster.

Original language	English
Pages (from-to)	44-50
Number of pages	7
Journal	Molecular Crystals and Liquid Crystals
Volume	760
Issue number	1
DOIs	https://doi.org/10.1080/15421406.2023.2165340
State	Published - 2023

Keywords

Single-crystal X-ray crystallography
solution process
tin
tin cluster
tin oxide

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title = "Synthesis and characterization of Sn complexes containing aminoalkoxide ligands for solution process",

abstract = "The reaction of Sn(btsa)2 and 2-(dimethylamino)-2-methylpropan-1-ol (dmamp{\textquoteright}H) gave a mixture of Sn(dmamp{\textquoteright})2 (1) and Sn6(O)4(dmamp{\textquoteright})4 (2), in which the latter one could be purely isolated by recrystallization. The complex 2 was characterized by NMR, and elemental analysis (EA). Further structural determination was performed by single-crystal X-ray diffraction (XRD) analysis to reveal a cage-shaped cluster.",

keywords = "Single-crystal X-ray crystallography, solution process, tin, tin cluster, tin oxide",

author = "Sangmi Gu and Cho, \{Chan Mi\} and Kim, \{Hae Sun\} and Son, \{Seung Uk\} and Chung, \{Taek Mo\} and Park, \{Bo Keun\}",

note = "Publisher Copyright: {\textcopyright} 2023 Taylor \& Francis Group, LLC.",

year = "2023",

doi = "10.1080/15421406.2023.2165340",

language = "English",

volume = "760",

pages = "44--50",

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TY - JOUR

T1 - Synthesis and characterization of Sn complexes containing aminoalkoxide ligands for solution process

AU - Gu, Sangmi

AU - Cho, Chan Mi

AU - Kim, Hae Sun

AU - Son, Seung Uk

AU - Chung, Taek Mo

AU - Park, Bo Keun

PY - 2023

Y1 - 2023

N2 - The reaction of Sn(btsa)2 and 2-(dimethylamino)-2-methylpropan-1-ol (dmamp’H) gave a mixture of Sn(dmamp’)2 (1) and Sn6(O)4(dmamp’)4 (2), in which the latter one could be purely isolated by recrystallization. The complex 2 was characterized by NMR, and elemental analysis (EA). Further structural determination was performed by single-crystal X-ray diffraction (XRD) analysis to reveal a cage-shaped cluster.

AB - The reaction of Sn(btsa)2 and 2-(dimethylamino)-2-methylpropan-1-ol (dmamp’H) gave a mixture of Sn(dmamp’)2 (1) and Sn6(O)4(dmamp’)4 (2), in which the latter one could be purely isolated by recrystallization. The complex 2 was characterized by NMR, and elemental analysis (EA). Further structural determination was performed by single-crystal X-ray diffraction (XRD) analysis to reveal a cage-shaped cluster.

KW - Single-crystal X-ray crystallography

KW - solution process

KW - tin

KW - tin cluster

KW - tin oxide

UR - https://www.scopus.com/pages/publications/85146236626

U2 - 10.1080/15421406.2023.2165340

DO - 10.1080/15421406.2023.2165340

M3 - Article

AN - SCOPUS:85146236626

SN - 1542-1406

VL - 760

SP - 44

EP - 50

JO - Molecular Crystals and Liquid Crystals

JF - Molecular Crystals and Liquid Crystals

IS - 1

ER -

Synthesis and characterization of Sn complexes containing aminoalkoxide ligands for solution process

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