Synthesis and C2-functionalization of indoles with allylic acetates under rhodium catalysis

Mirim Kim; Jihye Park; Satyasheel Sharma; Sangil Han; Sang Hoon Han; Jong Hwan Kwak; Young Hoon Jung; In Su Kim

doi:10.1039/c3ob41828f

Synthesis and C2-functionalization of indoles with allylic acetates under rhodium catalysis

Mirim Kim
, Jihye Park
, Satyasheel Sharma
, Sangil Han
, Sang Hoon Han
, Jong Hwan Kwak
, Young Hoon Jung
, In Su Kim

Department of Pharmacy

Sungkyunkwan University

Research output: Contribution to journal › Article › peer-review

45 Scopus citations

Abstract

Tandem rhodium-catalyzed oxidative allylation and annulation of acetanilides with allyl acetate to afford the corresponding indoles are described. In addition, the site-selective C2 allylation, crotylation and prenylation of indoles using allylic acetates under rhodium catalysis are reported.

Original language	English
Pages (from-to)	7427-7434
Number of pages	8
Journal	Organic and Biomolecular Chemistry
Volume	11
Issue number	42
DOIs	https://doi.org/10.1039/c3ob41828f
State	Published - 14 Nov 2013

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title = "Synthesis and C2-functionalization of indoles with allylic acetates under rhodium catalysis",

abstract = "Tandem rhodium-catalyzed oxidative allylation and annulation of acetanilides with allyl acetate to afford the corresponding indoles are described. In addition, the site-selective C2 allylation, crotylation and prenylation of indoles using allylic acetates under rhodium catalysis are reported.",

author = "Mirim Kim and Jihye Park and Satyasheel Sharma and Sangil Han and Han, \{Sang Hoon\} and Kwak, \{Jong Hwan\} and Jung, \{Young Hoon\} and Kim, \{In Su\}",

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journal = "Organic and Biomolecular Chemistry",

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T1 - Synthesis and C2-functionalization of indoles with allylic acetates under rhodium catalysis

AU - Kim, Mirim

AU - Park, Jihye

AU - Sharma, Satyasheel

AU - Han, Sangil

AU - Han, Sang Hoon

AU - Kwak, Jong Hwan

AU - Jung, Young Hoon

AU - Kim, In Su

PY - 2013/11/14

Y1 - 2013/11/14

N2 - Tandem rhodium-catalyzed oxidative allylation and annulation of acetanilides with allyl acetate to afford the corresponding indoles are described. In addition, the site-selective C2 allylation, crotylation and prenylation of indoles using allylic acetates under rhodium catalysis are reported.

AB - Tandem rhodium-catalyzed oxidative allylation and annulation of acetanilides with allyl acetate to afford the corresponding indoles are described. In addition, the site-selective C2 allylation, crotylation and prenylation of indoles using allylic acetates under rhodium catalysis are reported.

UR - https://www.scopus.com/pages/publications/84885440617

U2 - 10.1039/c3ob41828f

DO - 10.1039/c3ob41828f

M3 - Article

C2 - 24081311

AN - SCOPUS:84885440617

SN - 1477-0520

VL - 11

SP - 7427

EP - 7434

JO - Organic and Biomolecular Chemistry

JF - Organic and Biomolecular Chemistry

IS - 42

ER -

Synthesis and C2-functionalization of indoles with allylic acetates under rhodium catalysis

Abstract

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