Switching regioselectivity in crossed acyloin condensations between aromatic aldehydes and acetaldehyde by altering n -heterocyclic carbene catalysts

Ming Yu Jin; Sun Min Kim; Hogyu Han; Do Hyun Ryu; Jung Woon Yang

doi:10.1021/ol102937w

Switching regioselectivity in crossed acyloin condensations between aromatic aldehydes and acetaldehyde by altering n -heterocyclic carbene catalysts

Ming Yu Jin
, Sun Min Kim
, Hogyu Han
, Do Hyun Ryu
, Jung Woon Yang

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

85 Scopus citations

Abstract

An unprecedented high level of regioselectivities (up to 96%) in the intermolecular crossed acyloin condensations of various aromatic aldehydes with acetaldehyde was realized by an appropriate choice of N-heterocyclic carbene catalysts.(Figure Presented)

Original language	English
Pages (from-to)	880-883
Number of pages	4
Journal	Organic Letters
Volume	13
Issue number	5
DOIs	https://doi.org/10.1021/ol102937w
State	Published - 4 Mar 2011

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@article{913f6defba2f45fca7d8589f46d18833,

title = "Switching regioselectivity in crossed acyloin condensations between aromatic aldehydes and acetaldehyde by altering n -heterocyclic carbene catalysts",

abstract = "An unprecedented high level of regioselectivities (up to 96\%) in the intermolecular crossed acyloin condensations of various aromatic aldehydes with acetaldehyde was realized by an appropriate choice of N-heterocyclic carbene catalysts.(Figure Presented)",

author = "Jin, \{Ming Yu\} and Kim, \{Sun Min\} and Hogyu Han and Ryu, \{Do Hyun\} and Yang, \{Jung Woon\}",

year = "2011",

month = mar,

day = "4",

doi = "10.1021/ol102937w",

language = "English",

volume = "13",

pages = "880--883",

journal = "Organic Letters",

issn = "1523-7060",

publisher = "American Chemical Society",

number = "5",

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TY - JOUR

T1 - Switching regioselectivity in crossed acyloin condensations between aromatic aldehydes and acetaldehyde by altering n -heterocyclic carbene catalysts

AU - Jin, Ming Yu

AU - Kim, Sun Min

AU - Han, Hogyu

AU - Ryu, Do Hyun

AU - Yang, Jung Woon

PY - 2011/3/4

Y1 - 2011/3/4

N2 - An unprecedented high level of regioselectivities (up to 96%) in the intermolecular crossed acyloin condensations of various aromatic aldehydes with acetaldehyde was realized by an appropriate choice of N-heterocyclic carbene catalysts.(Figure Presented)

AB - An unprecedented high level of regioselectivities (up to 96%) in the intermolecular crossed acyloin condensations of various aromatic aldehydes with acetaldehyde was realized by an appropriate choice of N-heterocyclic carbene catalysts.(Figure Presented)

UR - https://www.scopus.com/pages/publications/79952158809

U2 - 10.1021/ol102937w

DO - 10.1021/ol102937w

M3 - Article

AN - SCOPUS:79952158809

SN - 1523-7060

VL - 13

SP - 880

EP - 883

JO - Organic Letters

JF - Organic Letters

IS - 5

ER -

Switching regioselectivity in crossed acyloin condensations between aromatic aldehydes and acetaldehyde by altering n -heterocyclic carbene catalysts

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