Suppression of the tetragonal distortion in thin Pb(Zr, Ti)O3 films grown on MgO(001)

H. C. Kang; D. Y. Noh; J. H. Je; H. K. Kim

Suppression of the tetragonal distortion in thin Pb(Zr, Ti)O₃ films grown on MgO(001)

H. C. Kang
, D. Y. Noh
, J. H. Je
, H. K. Kim

Gwangju Institute of Science and Technology

Research output: Contribution to journal › Conference article › peer-review

1 Scopus citations

Abstract

The paraelectric cubic to ferroelectric tetragonal phase transformation of thin Pb(Zr, Ti)O₃/MgO(001) films was studied in synchrotron x-ray scattering experiments. As the thickness of the film decreases, the transition temperature and the amount of the tetragonal distortion were decreased continuously. The thinnest 250 A thick film was purely composed of the c-type domains in the ferroelectric tetragonal phase. Based on this, we propose a model for the domain structure of the tetragonal PZT/MgO(001) film that is different from the ones suggested in literature. We attribute the suppression of the transition to the substrate effect that prefers the c-type domains near the interface, and reduces the tetragonal distortion to minimize the film-substrate lattice mismatch.

Original language	English
Pages (from-to)	317-322
Number of pages	6
Journal	Materials Research Society Symposium - Proceedings
Volume	493
State	Published - 1998
Externally published	Yes
Event	Proceedings of the 1997 MRS Fall Symposium - Boston, MA, USA Duration: 30 Nov 1997 → 4 Dec 1997

Cite this

@article{79b85b79962546b289dadb8f709d2ffe,

title = "Suppression of the tetragonal distortion in thin Pb(Zr, Ti)O3 films grown on MgO(001)",

abstract = "The paraelectric cubic to ferroelectric tetragonal phase transformation of thin Pb(Zr, Ti)O3/MgO(001) films was studied in synchrotron x-ray scattering experiments. As the thickness of the film decreases, the transition temperature and the amount of the tetragonal distortion were decreased continuously. The thinnest 250 A thick film was purely composed of the c-type domains in the ferroelectric tetragonal phase. Based on this, we propose a model for the domain structure of the tetragonal PZT/MgO(001) film that is different from the ones suggested in literature. We attribute the suppression of the transition to the substrate effect that prefers the c-type domains near the interface, and reduces the tetragonal distortion to minimize the film-substrate lattice mismatch.",

author = "Kang, \{H. C.\} and Noh, \{D. Y.\} and Je, \{J. H.\} and Kim, \{H. K.\}",

year = "1998",

language = "English",

volume = "493",

pages = "317--322",

journal = "Materials Research Society Symposium - Proceedings",

issn = "0272-9172",

publisher = "Materials Research Society",

note = "Proceedings of the 1997 MRS Fall Symposium ; Conference date: 30-11-1997 Through 04-12-1997",

}

TY - JOUR

T1 - Suppression of the tetragonal distortion in thin Pb(Zr, Ti)O3 films grown on MgO(001)

AU - Kang, H. C.

AU - Noh, D. Y.

AU - Je, J. H.

AU - Kim, H. K.

PY - 1998

Y1 - 1998

N2 - The paraelectric cubic to ferroelectric tetragonal phase transformation of thin Pb(Zr, Ti)O3/MgO(001) films was studied in synchrotron x-ray scattering experiments. As the thickness of the film decreases, the transition temperature and the amount of the tetragonal distortion were decreased continuously. The thinnest 250 A thick film was purely composed of the c-type domains in the ferroelectric tetragonal phase. Based on this, we propose a model for the domain structure of the tetragonal PZT/MgO(001) film that is different from the ones suggested in literature. We attribute the suppression of the transition to the substrate effect that prefers the c-type domains near the interface, and reduces the tetragonal distortion to minimize the film-substrate lattice mismatch.

AB - The paraelectric cubic to ferroelectric tetragonal phase transformation of thin Pb(Zr, Ti)O3/MgO(001) films was studied in synchrotron x-ray scattering experiments. As the thickness of the film decreases, the transition temperature and the amount of the tetragonal distortion were decreased continuously. The thinnest 250 A thick film was purely composed of the c-type domains in the ferroelectric tetragonal phase. Based on this, we propose a model for the domain structure of the tetragonal PZT/MgO(001) film that is different from the ones suggested in literature. We attribute the suppression of the transition to the substrate effect that prefers the c-type domains near the interface, and reduces the tetragonal distortion to minimize the film-substrate lattice mismatch.

UR - https://www.scopus.com/pages/publications/0031674998

M3 - Conference article

AN - SCOPUS:0031674998

SN - 0272-9172

VL - 493

SP - 317

EP - 322

JO - Materials Research Society Symposium - Proceedings

JF - Materials Research Society Symposium - Proceedings

T2 - Proceedings of the 1997 MRS Fall Symposium

Y2 - 30 November 1997 through 4 December 1997

ER -

Suppression of the tetragonal distortion in thin Pb(Zr, Ti)O₃ films grown on MgO(001)

Abstract

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