Single crystal structure of pure inorganic nanocomposite [GaO4Al12(OH)24(H2 O)12][Al(OH)6Mo6 O18]2(OH)·30H2O

Jung Ho Son; Young Uk Kwon

Single crystal structure of pure inorganic nanocomposite [GaO₄Al₁₂(OH)₂₄(H₂ O)₁₂][Al(OH)₆Mo₆ O₁₈]₂(OH)·30H₂O

Jung Ho Son, Young Uk Kwon

Department of Chemistry

Sungkyunkwan University

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

Single crystals of nanocomposite [GaO₄Al₁₂(OH)₂₄ (H₂O)₁₂][Al(OH)₆Mo₆ O₁₈]₂(OH)·30H₂O, 2, were obtained by the reaction between [GaO₄Al₁₂(OH)₂₄(H₂ O)₁₂]⁷⁺ and [Mo₇O₂₄]^6- clusters in an aqueous solution, analogously to the [AlO₄Al₁₂(OH)₂₄(H₂O)12] [Al(OH)₆Mo₆O₁₈]₂(OH) ·29.5H₂O nanocomposite, 1. The crystal structure of 2 was determined by single crystal x-ray diffraction; space group C2/c (No. 15), a = 27.418(2) Å, b = 15.647(2) Å, c = 23.960(4) Å, β = 102.850(9)°, V = 10,021.5(20) Å³, Z = 4. Detailed analysis of the structural data show that the clusters are held by intimate hydrogen bondings of the surface O^2- and OH^- groups of the clusters as well as the ionic interactions between the oppositely charged cluster ions.

Original language	English
Pages (from-to)	1224-1230
Number of pages	7
Journal	Bulletin of the Korean Chemical Society
Volume	22
Issue number	11
State	Published - 20 Nov 2001

Keywords

Cluster
Crystal structure
Nanocomposite
Polyoxometalate

Cite this

@article{4f4063aeab144208b7668c00ccb41aab,

title = "Single crystal structure of pure inorganic nanocomposite [GaO4Al12(OH)24(H2 O)12][Al(OH)6Mo6 O18]2(OH)·30H2O",

abstract = "Single crystals of nanocomposite [GaO4Al12(OH)24 (H2O)12][Al(OH)6Mo6 O18]2(OH)·30H2O, 2, were obtained by the reaction between [GaO4Al12(OH)24(H2 O)12]7+ and [Mo7O24]6- clusters in an aqueous solution, analogously to the [AlO4Al12(OH)24(H2O)12] [Al(OH)6Mo6O18]2(OH) ·29.5H2O nanocomposite, 1. The crystal structure of 2 was determined by single crystal x-ray diffraction; space group C2/c (No. 15), a = 27.418(2) {\AA}, b = 15.647(2) {\AA}, c = 23.960(4) {\AA}, β = 102.850(9)°, V = 10,021.5(20) {\AA}3, Z = 4. Detailed analysis of the structural data show that the clusters are held by intimate hydrogen bondings of the surface O2- and OH- groups of the clusters as well as the ionic interactions between the oppositely charged cluster ions.",

keywords = "Cluster, Crystal structure, Nanocomposite, Polyoxometalate",

author = "Son, \{Jung Ho\} and Kwon, \{Young Uk\}",

year = "2001",

month = nov,

day = "20",

language = "English",

volume = "22",

pages = "1224--1230",

journal = "Bulletin of the Korean Chemical Society",

issn = "0253-2964",

publisher = "Wiley-Blackwell",

number = "11",

}

TY - JOUR

T1 - Single crystal structure of pure inorganic nanocomposite [GaO4Al12(OH)24(H2 O)12][Al(OH)6Mo6 O18]2(OH)·30H2O

AU - Son, Jung Ho

AU - Kwon, Young Uk

PY - 2001/11/20

Y1 - 2001/11/20

N2 - Single crystals of nanocomposite [GaO4Al12(OH)24 (H2O)12][Al(OH)6Mo6 O18]2(OH)·30H2O, 2, were obtained by the reaction between [GaO4Al12(OH)24(H2 O)12]7+ and [Mo7O24]6- clusters in an aqueous solution, analogously to the [AlO4Al12(OH)24(H2O)12] [Al(OH)6Mo6O18]2(OH) ·29.5H2O nanocomposite, 1. The crystal structure of 2 was determined by single crystal x-ray diffraction; space group C2/c (No. 15), a = 27.418(2) Å, b = 15.647(2) Å, c = 23.960(4) Å, β = 102.850(9)°, V = 10,021.5(20) Å3, Z = 4. Detailed analysis of the structural data show that the clusters are held by intimate hydrogen bondings of the surface O2- and OH- groups of the clusters as well as the ionic interactions between the oppositely charged cluster ions.

AB - Single crystals of nanocomposite [GaO4Al12(OH)24 (H2O)12][Al(OH)6Mo6 O18]2(OH)·30H2O, 2, were obtained by the reaction between [GaO4Al12(OH)24(H2 O)12]7+ and [Mo7O24]6- clusters in an aqueous solution, analogously to the [AlO4Al12(OH)24(H2O)12] [Al(OH)6Mo6O18]2(OH) ·29.5H2O nanocomposite, 1. The crystal structure of 2 was determined by single crystal x-ray diffraction; space group C2/c (No. 15), a = 27.418(2) Å, b = 15.647(2) Å, c = 23.960(4) Å, β = 102.850(9)°, V = 10,021.5(20) Å3, Z = 4. Detailed analysis of the structural data show that the clusters are held by intimate hydrogen bondings of the surface O2- and OH- groups of the clusters as well as the ionic interactions between the oppositely charged cluster ions.

KW - Cluster

KW - Crystal structure

KW - Nanocomposite

KW - Polyoxometalate

UR - https://www.scopus.com/pages/publications/0035540605

M3 - Article

AN - SCOPUS:0035540605

SN - 0253-2964

VL - 22

SP - 1224

EP - 1230

JO - Bulletin of the Korean Chemical Society

JF - Bulletin of the Korean Chemical Society

IS - 11

ER -

Single crystal structure of pure inorganic nanocomposite [GaO₄Al₁₂(OH)₂₄(H₂ O)₁₂][Al(OH)₆Mo₆ O₁₈]₂(OH)·30H₂O

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