Self-Organized Nanosalts of Pd(II)-Ammonium-Tethered Carboxylic Acid for the Synthesis of Antifouling Polyketones

Yu Na Lim; Hyeong Wan Noh; Yeon Joo Cheong; Shin Young Kang; Bun Yeoul Lee; Seung Uk Son; Hye Young Jang

doi:10.1021/acssuschemeng.7b02855

Self-Organized Nanosalts of Pd(II)-Ammonium-Tethered Carboxylic Acid for the Synthesis of Antifouling Polyketones

Yu Na Lim
, Hyeong Wan Noh
, Yeon Joo Cheong
, Shin Young Kang
, Bun Yeoul Lee
, Seung Uk Son
, Hye Young Jang

Department of Chemistry

Ajou University
Sungkyunkwan University

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

Pd(II) nanosalts formed from [LnPd(OAc)₂] (Ln = 1,3-bis(di-o-methoxyphenylphosphino)propane) and ammonium tethered carboxylic acids in MeOH were utilized for the synthesis of antifouling polyketones from CO and olefin; this is the first instance of the synthesis of antifouling polyketones in the absence of additional heterogeneous seeds. The polymerization of CO and olefin achieved with the in situ-generated Pd(II) nanosalts was studied, and the nanosalts were analyzed by dynamic light scattering (DLS) experiments.

Original language	English
Pages (from-to)	9657-9661
Number of pages	5
Journal	ACS Sustainable Chemistry and Engineering
Volume	5
Issue number	11
DOIs	https://doi.org/10.1021/acssuschemeng.7b02855
State	Published - 6 Nov 2017

Keywords

C1 resource
CO
Pd nanosalts
Polyketones
Seed-free polymerization

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10.1021/acssuschemeng.7b02855

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title = "Self-Organized Nanosalts of Pd(II)-Ammonium-Tethered Carboxylic Acid for the Synthesis of Antifouling Polyketones",

abstract = "Pd(II) nanosalts formed from [LnPd(OAc)2] (Ln = 1,3-bis(di-o-methoxyphenylphosphino)propane) and ammonium tethered carboxylic acids in MeOH were utilized for the synthesis of antifouling polyketones from CO and olefin; this is the first instance of the synthesis of antifouling polyketones in the absence of additional heterogeneous seeds. The polymerization of CO and olefin achieved with the in situ-generated Pd(II) nanosalts was studied, and the nanosalts were analyzed by dynamic light scattering (DLS) experiments.",

keywords = "C1 resource, CO, Pd nanosalts, Polyketones, Seed-free polymerization",

author = "Lim, \{Yu Na\} and Noh, \{Hyeong Wan\} and Cheong, \{Yeon Joo\} and Kang, \{Shin Young\} and Lee, \{Bun Yeoul\} and Son, \{Seung Uk\} and Jang, \{Hye Young\}",

note = "Publisher Copyright: {\textcopyright} 2017 American Chemical Society.",

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day = "6",

doi = "10.1021/acssuschemeng.7b02855",

language = "English",

volume = "5",

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journal = "ACS Sustainable Chemistry and Engineering",

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publisher = "American Chemical Society",

number = "11",

}

TY - JOUR

T1 - Self-Organized Nanosalts of Pd(II)-Ammonium-Tethered Carboxylic Acid for the Synthesis of Antifouling Polyketones

AU - Lim, Yu Na

AU - Noh, Hyeong Wan

AU - Cheong, Yeon Joo

AU - Kang, Shin Young

AU - Lee, Bun Yeoul

AU - Son, Seung Uk

AU - Jang, Hye Young

PY - 2017/11/6

Y1 - 2017/11/6

N2 - Pd(II) nanosalts formed from [LnPd(OAc)2] (Ln = 1,3-bis(di-o-methoxyphenylphosphino)propane) and ammonium tethered carboxylic acids in MeOH were utilized for the synthesis of antifouling polyketones from CO and olefin; this is the first instance of the synthesis of antifouling polyketones in the absence of additional heterogeneous seeds. The polymerization of CO and olefin achieved with the in situ-generated Pd(II) nanosalts was studied, and the nanosalts were analyzed by dynamic light scattering (DLS) experiments.

AB - Pd(II) nanosalts formed from [LnPd(OAc)2] (Ln = 1,3-bis(di-o-methoxyphenylphosphino)propane) and ammonium tethered carboxylic acids in MeOH were utilized for the synthesis of antifouling polyketones from CO and olefin; this is the first instance of the synthesis of antifouling polyketones in the absence of additional heterogeneous seeds. The polymerization of CO and olefin achieved with the in situ-generated Pd(II) nanosalts was studied, and the nanosalts were analyzed by dynamic light scattering (DLS) experiments.

KW - C1 resource

KW - CO

KW - Pd nanosalts

KW - Polyketones

KW - Seed-free polymerization

UR - https://www.scopus.com/pages/publications/85033495862

U2 - 10.1021/acssuschemeng.7b02855

DO - 10.1021/acssuschemeng.7b02855

M3 - Article

AN - SCOPUS:85033495862

SN - 2168-0485

VL - 5

SP - 9657

EP - 9661

JO - ACS Sustainable Chemistry and Engineering

JF - ACS Sustainable Chemistry and Engineering

IS - 11

ER -

Self-Organized Nanosalts of Pd(II)-Ammonium-Tethered Carboxylic Acid for the Synthesis of Antifouling Polyketones

Abstract

Keywords

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