Selective Synthesis of Ruthenium(II) Metalla[2]Catenane via Solvent and Guest-Dependent Self-Assembly

Hye Woo Lee; Palani Elumalai; Nem Singh; Hyunuk Kim; Sang Uck Lee; Ki Whan Chi

doi:10.1021/jacs.5b02573

Selective Synthesis of Ruthenium(II) Metalla[2]Catenane via Solvent and Guest-Dependent Self-Assembly

Hye Woo Lee
, Palani Elumalai
, Nem Singh
, Hyunuk Kim
, Sang Uck Lee
, Ki Whan Chi

University of Ulsan
Korea Institute of Energy Research
Hanyang University

Research output: Contribution to journal › Article › peer-review

101 Scopus citations

Abstract

The coordination-driven self-assembly of an anthracene-functionalized ditopic pyridyl donor and a tetracene-based dinuclear Ru(II) acceptor resulted in an interlocked metalla[2]catenane, [M₂L₂]₂, in methanol and a corresponding monorectangle, [M₂L₂], in nitromethane. Subsequently, guest template, solvent, and concentration effects allowed the self-assembly to be reversibly fine-tuned among monorectangle and catenane structures.

Original language	English
Pages (from-to)	4674-4677
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	137
Issue number	14
DOIs	https://doi.org/10.1021/jacs.5b02573
State	Published - 15 Apr 2015
Externally published	Yes

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title = "Selective Synthesis of Ruthenium(II) Metalla[2]Catenane via Solvent and Guest-Dependent Self-Assembly",

abstract = "The coordination-driven self-assembly of an anthracene-functionalized ditopic pyridyl donor and a tetracene-based dinuclear Ru(II) acceptor resulted in an interlocked metalla[2]catenane, [M2L2]2, in methanol and a corresponding monorectangle, [M2L2], in nitromethane. Subsequently, guest template, solvent, and concentration effects allowed the self-assembly to be reversibly fine-tuned among monorectangle and catenane structures.",

author = "Lee, \{Hye Woo\} and Palani Elumalai and Nem Singh and Hyunuk Kim and Lee, \{Sang Uck\} and Chi, \{Ki Whan\}",

note = "Publisher Copyright: {\textcopyright} 2015 American Chemical Society.",

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doi = "10.1021/jacs.5b02573",

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T1 - Selective Synthesis of Ruthenium(II) Metalla[2]Catenane via Solvent and Guest-Dependent Self-Assembly

AU - Lee, Hye Woo

AU - Elumalai, Palani

AU - Singh, Nem

AU - Kim, Hyunuk

AU - Lee, Sang Uck

AU - Chi, Ki Whan

PY - 2015/4/15

Y1 - 2015/4/15

N2 - The coordination-driven self-assembly of an anthracene-functionalized ditopic pyridyl donor and a tetracene-based dinuclear Ru(II) acceptor resulted in an interlocked metalla[2]catenane, [M2L2]2, in methanol and a corresponding monorectangle, [M2L2], in nitromethane. Subsequently, guest template, solvent, and concentration effects allowed the self-assembly to be reversibly fine-tuned among monorectangle and catenane structures.

AB - The coordination-driven self-assembly of an anthracene-functionalized ditopic pyridyl donor and a tetracene-based dinuclear Ru(II) acceptor resulted in an interlocked metalla[2]catenane, [M2L2]2, in methanol and a corresponding monorectangle, [M2L2], in nitromethane. Subsequently, guest template, solvent, and concentration effects allowed the self-assembly to be reversibly fine-tuned among monorectangle and catenane structures.

UR - https://www.scopus.com/pages/publications/84927935051

U2 - 10.1021/jacs.5b02573

DO - 10.1021/jacs.5b02573

M3 - Article

AN - SCOPUS:84927935051

SN - 0002-7863

VL - 137

SP - 4674

EP - 4677

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 14

ER -

Selective Synthesis of Ruthenium(II) Metalla[2]Catenane via Solvent and Guest-Dependent Self-Assembly

Abstract

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