Selective carbonylation of dimethyl ether to methyl acetate on Ferrierite

So Young Park; Chae Ho Shin; Jong Wook Bae

doi:10.1016/j.catcom.2015.12.006

Selective carbonylation of dimethyl ether to methyl acetate on Ferrierite

So Young Park, Chae Ho Shin, Jong Wook Bae

Department of Chemical Engineering

Research output: Contribution to journal › Article › peer-review

52 Scopus citations

Abstract

Synthesis of methyl acetate (MA) by carbonylation of dimethyl ether (DME) was investigated using laboratory-made H-form Ferrierite (FER) zeolite with different Si/Al molar ratios. The synthesized H-FER with a Si/Al ratio of 12 (FER(12)) revealed a higher DME conversion as well as MA selectivity. The observed higher catalytic performance on the FER(12) was mainly attributed to a higher ratio of Bronsted to Lewis acid sites as well as the higher crystallinity with the less coke formation. The superior properties of the FER(12) having a higher ratio of Bronsted to Lewis acid sites and crystallinity efficiently suppressed the formation of inactive coke precursors.

Original language	English
Pages (from-to)	28-31
Number of pages	4
Journal	Catalysis Communications
Volume	75
DOIs	https://doi.org/10.1016/j.catcom.2015.12.006
State	Published - 5 Feb 2016

Keywords

Carbonylation
Coke formation
Dimethyl ether
Ferrierite
Methyl acetate

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10.1016/j.catcom.2015.12.006

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title = "Selective carbonylation of dimethyl ether to methyl acetate on Ferrierite",

abstract = "Synthesis of methyl acetate (MA) by carbonylation of dimethyl ether (DME) was investigated using laboratory-made H-form Ferrierite (FER) zeolite with different Si/Al molar ratios. The synthesized H-FER with a Si/Al ratio of 12 (FER(12)) revealed a higher DME conversion as well as MA selectivity. The observed higher catalytic performance on the FER(12) was mainly attributed to a higher ratio of Bronsted to Lewis acid sites as well as the higher crystallinity with the less coke formation. The superior properties of the FER(12) having a higher ratio of Bronsted to Lewis acid sites and crystallinity efficiently suppressed the formation of inactive coke precursors.",

keywords = "Carbonylation, Coke formation, Dimethyl ether, Ferrierite, Methyl acetate",

author = "Park, \{So Young\} and Shin, \{Chae Ho\} and Bae, \{Jong Wook\}",

note = "Publisher Copyright: {\textcopyright} 2015 Elsevier B.V.",

year = "2016",

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day = "5",

doi = "10.1016/j.catcom.2015.12.006",

language = "English",

volume = "75",

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journal = "Catalysis Communications",

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TY - JOUR

T1 - Selective carbonylation of dimethyl ether to methyl acetate on Ferrierite

AU - Park, So Young

AU - Shin, Chae Ho

AU - Bae, Jong Wook

PY - 2016/2/5

Y1 - 2016/2/5

N2 - Synthesis of methyl acetate (MA) by carbonylation of dimethyl ether (DME) was investigated using laboratory-made H-form Ferrierite (FER) zeolite with different Si/Al molar ratios. The synthesized H-FER with a Si/Al ratio of 12 (FER(12)) revealed a higher DME conversion as well as MA selectivity. The observed higher catalytic performance on the FER(12) was mainly attributed to a higher ratio of Bronsted to Lewis acid sites as well as the higher crystallinity with the less coke formation. The superior properties of the FER(12) having a higher ratio of Bronsted to Lewis acid sites and crystallinity efficiently suppressed the formation of inactive coke precursors.

AB - Synthesis of methyl acetate (MA) by carbonylation of dimethyl ether (DME) was investigated using laboratory-made H-form Ferrierite (FER) zeolite with different Si/Al molar ratios. The synthesized H-FER with a Si/Al ratio of 12 (FER(12)) revealed a higher DME conversion as well as MA selectivity. The observed higher catalytic performance on the FER(12) was mainly attributed to a higher ratio of Bronsted to Lewis acid sites as well as the higher crystallinity with the less coke formation. The superior properties of the FER(12) having a higher ratio of Bronsted to Lewis acid sites and crystallinity efficiently suppressed the formation of inactive coke precursors.

KW - Carbonylation

KW - Coke formation

KW - Dimethyl ether

KW - Ferrierite

KW - Methyl acetate

UR - https://www.scopus.com/pages/publications/84979603870

U2 - 10.1016/j.catcom.2015.12.006

DO - 10.1016/j.catcom.2015.12.006

M3 - Article

AN - SCOPUS:84979603870

SN - 1566-7367

VL - 75

SP - 28

EP - 31

JO - Catalysis Communications

JF - Catalysis Communications

ER -

Selective carbonylation of dimethyl ether to methyl acetate on Ferrierite

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Keywords

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