Role of lithium borosilicate glass in the decomposition of MgTiO3-based dielectric ceramic during sintering

Hee Kyun Shin; Hyunho Shin; Hyun Suk Jung; Seo Yong Cho; Jeong Ryeol Kim; Kug Sun Hong

doi:10.1016/j.materresbull.2005.10.020

Role of lithium borosilicate glass in the decomposition of MgTiO₃-based dielectric ceramic during sintering

Hee Kyun Shin
, Hyunho Shin
, Hyun Suk Jung
, Seo Yong Cho
, Jeong Ryeol Kim
, Kug Sun Hong

Research output: Contribution to journal › Article › peer-review

15 Scopus citations

Abstract

The decomposition behaviour of 0.9MgTiO₃-0.1CaTiO₃ dielectric ceramic during a liquid phase sintering by lithium borosilicate (LBS) glass was studied. The decompositions of MgTiO₃ into MgTi₂O₅ and Mg₂TiO₄ were apparent during the sintering although the reactions are thermodynamically unfavourable in glass-free compositions. The role of the LBS glass in favouring the decomposition reaction was investigated in terms of the thermodynamic activity of the reaction product in the glass. The decomposition reactions were not necessarily harmful because of the high dielectric performance of the decomposition products, MgTi₂O₅ (17.4 permittivity; 47,000 GHz quality factor) and Mg₂TiO₄ (14.4 and 55,000 GHz, respectively).

Original language	English
Pages (from-to)	1206-1214
Number of pages	9
Journal	Materials Research Bulletin
Volume	41
Issue number	6
DOIs	https://doi.org/10.1016/j.materresbull.2005.10.020
State	Published - 15 Jun 2006
Externally published	Yes

Keywords

A. Ceramics
D. Dielectric properties

Access to Document

10.1016/j.materresbull.2005.10.020

Cite this

@article{838a77e2dd9c4a9eb72219eba7955aa5,

title = "Role of lithium borosilicate glass in the decomposition of MgTiO3-based dielectric ceramic during sintering",

abstract = "The decomposition behaviour of 0.9MgTiO3-0.1CaTiO3 dielectric ceramic during a liquid phase sintering by lithium borosilicate (LBS) glass was studied. The decompositions of MgTiO3 into MgTi2O5 and Mg2TiO4 were apparent during the sintering although the reactions are thermodynamically unfavourable in glass-free compositions. The role of the LBS glass in favouring the decomposition reaction was investigated in terms of the thermodynamic activity of the reaction product in the glass. The decomposition reactions were not necessarily harmful because of the high dielectric performance of the decomposition products, MgTi2O5 (17.4 permittivity; 47,000 GHz quality factor) and Mg2TiO4 (14.4 and 55,000 GHz, respectively).",

keywords = "A. Ceramics, D. Dielectric properties",

author = "Shin, \{Hee Kyun\} and Hyunho Shin and Jung, \{Hyun Suk\} and Cho, \{Seo Yong\} and Kim, \{Jeong Ryeol\} and Hong, \{Kug Sun\}",

year = "2006",

month = jun,

day = "15",

doi = "10.1016/j.materresbull.2005.10.020",

language = "English",

volume = "41",

pages = "1206--1214",

journal = "Materials Research Bulletin",

issn = "0025-5408",

publisher = "Elsevier Ltd",

number = "6",

}

TY - JOUR

T1 - Role of lithium borosilicate glass in the decomposition of MgTiO3-based dielectric ceramic during sintering

AU - Shin, Hee Kyun

AU - Shin, Hyunho

AU - Jung, Hyun Suk

AU - Cho, Seo Yong

AU - Kim, Jeong Ryeol

AU - Hong, Kug Sun

PY - 2006/6/15

Y1 - 2006/6/15

N2 - The decomposition behaviour of 0.9MgTiO3-0.1CaTiO3 dielectric ceramic during a liquid phase sintering by lithium borosilicate (LBS) glass was studied. The decompositions of MgTiO3 into MgTi2O5 and Mg2TiO4 were apparent during the sintering although the reactions are thermodynamically unfavourable in glass-free compositions. The role of the LBS glass in favouring the decomposition reaction was investigated in terms of the thermodynamic activity of the reaction product in the glass. The decomposition reactions were not necessarily harmful because of the high dielectric performance of the decomposition products, MgTi2O5 (17.4 permittivity; 47,000 GHz quality factor) and Mg2TiO4 (14.4 and 55,000 GHz, respectively).

AB - The decomposition behaviour of 0.9MgTiO3-0.1CaTiO3 dielectric ceramic during a liquid phase sintering by lithium borosilicate (LBS) glass was studied. The decompositions of MgTiO3 into MgTi2O5 and Mg2TiO4 were apparent during the sintering although the reactions are thermodynamically unfavourable in glass-free compositions. The role of the LBS glass in favouring the decomposition reaction was investigated in terms of the thermodynamic activity of the reaction product in the glass. The decomposition reactions were not necessarily harmful because of the high dielectric performance of the decomposition products, MgTi2O5 (17.4 permittivity; 47,000 GHz quality factor) and Mg2TiO4 (14.4 and 55,000 GHz, respectively).

KW - A. Ceramics

KW - D. Dielectric properties

UR - https://www.scopus.com/pages/publications/33646756531

U2 - 10.1016/j.materresbull.2005.10.020

DO - 10.1016/j.materresbull.2005.10.020

M3 - Article

AN - SCOPUS:33646756531

SN - 0025-5408

VL - 41

SP - 1206

EP - 1214

JO - Materials Research Bulletin

JF - Materials Research Bulletin

IS - 6

ER -

Role of lithium borosilicate glass in the decomposition of MgTiO₃-based dielectric ceramic during sintering

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this