Rh-catalyzed oxidative C-C bond formation and C-N bond cleavage: Direct access to C2-olefinated free (NH)-indoles and pyrroles

Satyasheel Sharma; Sangil Han; Mirim Kim; Neeraj Kumar Mishra; Jihye Park; Youngmi Shin; Jimin Ha; Jong Hwan Kwak; Young Hoon Jung; In Su Kim

doi:10.1039/c3ob42605j

Rh-catalyzed oxidative C-C bond formation and C-N bond cleavage: Direct access to C2-olefinated free (NH)-indoles and pyrroles

Satyasheel Sharma
, Sangil Han
, Mirim Kim
, Neeraj Kumar Mishra
, Jihye Park
, Youngmi Shin
, Jimin Ha
, Jong Hwan Kwak
, Young Hoon Jung
, In Su Kim

Department of Pharmacy

Sungkyunkwan University

Research output: Contribution to journal › Article › peer-review

56 Scopus citations

Abstract

The rhodium-catalyzed oxidative C2-olefination of indoles and pyrroles containing N-arylcarboxamide directing groups with a range of alkenes and subsequent cleavage of directing groups is described. This method provides direct and efficient access to C2-functionalized free (NH)-heterocycles.

Original language	English
Pages (from-to)	1703-1706
Number of pages	4
Journal	Organic and Biomolecular Chemistry
Volume	12
Issue number	11
DOIs	https://doi.org/10.1039/c3ob42605j
State	Published - 21 Mar 2014

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10.1039/c3ob42605j

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title = "Rh-catalyzed oxidative C-C bond formation and C-N bond cleavage: Direct access to C2-olefinated free (NH)-indoles and pyrroles",

abstract = "The rhodium-catalyzed oxidative C2-olefination of indoles and pyrroles containing N-arylcarboxamide directing groups with a range of alkenes and subsequent cleavage of directing groups is described. This method provides direct and efficient access to C2-functionalized free (NH)-heterocycles.",

author = "Satyasheel Sharma and Sangil Han and Mirim Kim and Mishra, \{Neeraj Kumar\} and Jihye Park and Youngmi Shin and Jimin Ha and Kwak, \{Jong Hwan\} and Jung, \{Young Hoon\} and Kim, \{In Su\}",

year = "2014",

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doi = "10.1039/c3ob42605j",

language = "English",

volume = "12",

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journal = "Organic and Biomolecular Chemistry",

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publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - Rh-catalyzed oxidative C-C bond formation and C-N bond cleavage

T2 - Direct access to C2-olefinated free (NH)-indoles and pyrroles

AU - Sharma, Satyasheel

AU - Han, Sangil

AU - Kim, Mirim

AU - Mishra, Neeraj Kumar

AU - Park, Jihye

AU - Shin, Youngmi

AU - Ha, Jimin

AU - Kwak, Jong Hwan

AU - Jung, Young Hoon

AU - Kim, In Su

PY - 2014/3/21

Y1 - 2014/3/21

N2 - The rhodium-catalyzed oxidative C2-olefination of indoles and pyrroles containing N-arylcarboxamide directing groups with a range of alkenes and subsequent cleavage of directing groups is described. This method provides direct and efficient access to C2-functionalized free (NH)-heterocycles.

AB - The rhodium-catalyzed oxidative C2-olefination of indoles and pyrroles containing N-arylcarboxamide directing groups with a range of alkenes and subsequent cleavage of directing groups is described. This method provides direct and efficient access to C2-functionalized free (NH)-heterocycles.

UR - https://www.scopus.com/pages/publications/84894492186

U2 - 10.1039/c3ob42605j

DO - 10.1039/c3ob42605j

M3 - Article

C2 - 24480981

AN - SCOPUS:84894492186

SN - 1477-0520

VL - 12

SP - 1703

EP - 1706

JO - Organic and Biomolecular Chemistry

JF - Organic and Biomolecular Chemistry

IS - 11

ER -

Rh-catalyzed oxidative C-C bond formation and C-N bond cleavage: Direct access to C2-olefinated free (NH)-indoles and pyrroles

Abstract

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