Reversible interpenetration in a metal-organic framework triggered by ligand removal and addition

Sang Beom Choi; Hiroyasu Furukawa; Hye Jin Nam; Duk Young Jung; Young Ho Jhon; Allan Walton; David Book; Michael O'Keeffe; Omar M. Yaghi; Jaheon Kim

doi:10.1002/anie.201202925

Reversible interpenetration in a metal-organic framework triggered by ligand removal and addition

Sang Beom Choi, Hiroyasu Furukawa, Hye Jin Nam, Duk Young Jung, Young Ho Jhon, Allan Walton, David Book, Michael O'Keeffe, Omar M. Yaghi, Jaheon Kim

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

135 Scopus citations

Abstract

Caging cages: Crystals of a metal-organic framework, MOF-123 [Zn ₇O ₂(NBD) ₅(DMF) ₂] have a three-dimensional porous structure in which DMF ligands (see picture, pink) protrude into small channels. Removal of these ligands triggers the transformation of this MOF to the doubly interpenetrating form, MOF-246 [Zn ₇O ₂(NBD) ₅]. Moreover, addition of DMF into MOF-246 triggers reverse transformation to give MOF-123. NBD=2-nitrobenzene-1,4- dicarboxylate.

Original language	English
Pages (from-to)	8791-8795
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	51
Issue number	35
DOIs	https://doi.org/10.1002/anie.201202925
State	Published - 27 Aug 2012

Keywords

interpenetration
metal-organic frameworks
porosity
structural transformation
zinc

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title = "Reversible interpenetration in a metal-organic framework triggered by ligand removal and addition",

abstract = "Caging cages: Crystals of a metal-organic framework, MOF-123 [Zn 7O 2(NBD) 5(DMF) 2] have a three-dimensional porous structure in which DMF ligands (see picture, pink) protrude into small channels. Removal of these ligands triggers the transformation of this MOF to the doubly interpenetrating form, MOF-246 [Zn 7O 2(NBD) 5]. Moreover, addition of DMF into MOF-246 triggers reverse transformation to give MOF-123. NBD=2-nitrobenzene-1,4- dicarboxylate.",

keywords = "interpenetration, metal-organic frameworks, porosity, structural transformation, zinc",

author = "Choi, \{Sang Beom\} and Hiroyasu Furukawa and Nam, \{Hye Jin\} and Jung, \{Duk Young\} and Jhon, \{Young Ho\} and Allan Walton and David Book and Michael O'Keeffe and Yaghi, \{Omar M.\} and Jaheon Kim",

year = "2012",

month = aug,

day = "27",

doi = "10.1002/anie.201202925",

language = "English",

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journal = "Angewandte Chemie - International Edition",

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publisher = "John Wiley and Sons Ltd",

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T1 - Reversible interpenetration in a metal-organic framework triggered by ligand removal and addition

AU - Choi, Sang Beom

AU - Furukawa, Hiroyasu

AU - Nam, Hye Jin

AU - Jung, Duk Young

AU - Jhon, Young Ho

AU - Walton, Allan

AU - Book, David

AU - O'Keeffe, Michael

AU - Yaghi, Omar M.

AU - Kim, Jaheon

PY - 2012/8/27

Y1 - 2012/8/27

N2 - Caging cages: Crystals of a metal-organic framework, MOF-123 [Zn 7O 2(NBD) 5(DMF) 2] have a three-dimensional porous structure in which DMF ligands (see picture, pink) protrude into small channels. Removal of these ligands triggers the transformation of this MOF to the doubly interpenetrating form, MOF-246 [Zn 7O 2(NBD) 5]. Moreover, addition of DMF into MOF-246 triggers reverse transformation to give MOF-123. NBD=2-nitrobenzene-1,4- dicarboxylate.

AB - Caging cages: Crystals of a metal-organic framework, MOF-123 [Zn 7O 2(NBD) 5(DMF) 2] have a three-dimensional porous structure in which DMF ligands (see picture, pink) protrude into small channels. Removal of these ligands triggers the transformation of this MOF to the doubly interpenetrating form, MOF-246 [Zn 7O 2(NBD) 5]. Moreover, addition of DMF into MOF-246 triggers reverse transformation to give MOF-123. NBD=2-nitrobenzene-1,4- dicarboxylate.

KW - interpenetration

KW - metal-organic frameworks

KW - porosity

KW - structural transformation

KW - zinc

UR - https://www.scopus.com/pages/publications/84865435846

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DO - 10.1002/anie.201202925

M3 - Article

AN - SCOPUS:84865435846

SN - 1433-7851

VL - 51

SP - 8791

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 35

ER -

Reversible interpenetration in a metal-organic framework triggered by ligand removal and addition

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Keywords

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