Relationship between two-photon absorption and the π-conjugation pathway in porphyrin arrays through dihedral angle control

Tae Kyu Ahn; Kil Suk Kim; Deok Yun Kim; Su Bum Noh; Naoki Aratani; Chusaku Ikeda; Atsuhiro Osuka; Dongho Kim

doi:10.1021/ja056773a

Relationship between two-photon absorption and the π-conjugation pathway in porphyrin arrays through dihedral angle control

Tae Kyu Ahn
, Kil Suk Kim
, Deok Yun Kim
, Su Bum Noh
, Naoki Aratani
, Chusaku Ikeda
, Atsuhiro Osuka
, Dongho Kim

Yonsei University
Kyoto University

Research output: Contribution to journal › Article › peer-review

223 Scopus citations

Abstract

Recently, covalently linked or self-assembled porphyrin array systems have attracted much attention for their enhanced two-photon absorption (TPA) behaviors. In this study, we have investigated the TPA properties of various dihedral angle controlled, directly linked porphyrin dimers and arrays to elucidate the relationship between the π-conjugation pathway and TPA properties. We have demonstrated a strong correlation between π-conjugation (aromaticity) and TPA properties in porphyrin assemblies.

Original language	English
Pages (from-to)	1700-1704
Number of pages	5
Journal	Journal of the American Chemical Society
Volume	128
Issue number	5
DOIs	https://doi.org/10.1021/ja056773a
State	Published - 8 Feb 2006
Externally published	Yes

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10.1021/ja056773a

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title = "Relationship between two-photon absorption and the π-conjugation pathway in porphyrin arrays through dihedral angle control",

abstract = "Recently, covalently linked or self-assembled porphyrin array systems have attracted much attention for their enhanced two-photon absorption (TPA) behaviors. In this study, we have investigated the TPA properties of various dihedral angle controlled, directly linked porphyrin dimers and arrays to elucidate the relationship between the π-conjugation pathway and TPA properties. We have demonstrated a strong correlation between π-conjugation (aromaticity) and TPA properties in porphyrin assemblies.",

author = "Ahn, \{Tae Kyu\} and Kim, \{Kil Suk\} and Kim, \{Deok Yun\} and Noh, \{Su Bum\} and Naoki Aratani and Chusaku Ikeda and Atsuhiro Osuka and Dongho Kim",

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T1 - Relationship between two-photon absorption and the π-conjugation pathway in porphyrin arrays through dihedral angle control

AU - Ahn, Tae Kyu

AU - Kim, Kil Suk

AU - Kim, Deok Yun

AU - Noh, Su Bum

AU - Aratani, Naoki

AU - Ikeda, Chusaku

AU - Osuka, Atsuhiro

AU - Kim, Dongho

PY - 2006/2/8

Y1 - 2006/2/8

N2 - Recently, covalently linked or self-assembled porphyrin array systems have attracted much attention for their enhanced two-photon absorption (TPA) behaviors. In this study, we have investigated the TPA properties of various dihedral angle controlled, directly linked porphyrin dimers and arrays to elucidate the relationship between the π-conjugation pathway and TPA properties. We have demonstrated a strong correlation between π-conjugation (aromaticity) and TPA properties in porphyrin assemblies.

AB - Recently, covalently linked or self-assembled porphyrin array systems have attracted much attention for their enhanced two-photon absorption (TPA) behaviors. In this study, we have investigated the TPA properties of various dihedral angle controlled, directly linked porphyrin dimers and arrays to elucidate the relationship between the π-conjugation pathway and TPA properties. We have demonstrated a strong correlation between π-conjugation (aromaticity) and TPA properties in porphyrin assemblies.

UR - https://www.scopus.com/pages/publications/32344451954

U2 - 10.1021/ja056773a

DO - 10.1021/ja056773a

M3 - Article

AN - SCOPUS:32344451954

SN - 0002-7863

VL - 128

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JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 5

ER -

Relationship between two-photon absorption and the π-conjugation pathway in porphyrin arrays through dihedral angle control

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