Proton-transfer-induced 3D/2D hybrid perovskites suppress ion migration and reduce luminance overshoot

Hobeom Kim; Joo Sung Kim; Jung Min Heo; Mingyuan Pei; In Hyeok Park; Zhun Liu; Hyung Joong Yun; Min Ho Park; Su Hun Jeong; Young Hoon Kim; Jin Woo Park; Emad Oveisi; Satyawan Nagane; Aditya Sadhanala; Lijun Zhang; Jin Jung Kweon; Sung Keun Lee; Hoichang Yang; Hyun Myung Jang; Richard H. Friend; Kian Ping Loh; Mohammad Khaja Nazeeruddin; Nam Gyu Park; Tae Woo Lee

doi:10.1038/s41467-020-17072-0

Proton-transfer-induced 3D/2D hybrid perovskites suppress ion migration and reduce luminance overshoot

Hobeom Kim
, Joo Sung Kim
, Jung Min Heo
, Mingyuan Pei
, In Hyeok Park
, Zhun Liu
, Hyung Joong Yun
, Min Ho Park
, Su Hun Jeong
, Young Hoon Kim
, Jin Woo Park
, Emad Oveisi
, Satyawan Nagane
, Aditya Sadhanala
, Lijun Zhang
, Jin Jung Kweon
, Sung Keun Lee
, Hoichang Yang
, Hyun Myung Jang
, Richard H. Friend

Kian Ping Loh, Mohammad Khaja Nazeeruddin, Nam Gyu Park, Tae Woo Lee

Department of Chemical Engineering

Seoul National University
Inha University
National University of Singapore
Jilin University
Korea Basic Science Institute
Swiss Federal Institute of Technology Lausanne
University of Cambridge
University of Oxford
Indian Institute of Science Bangalore
Pohang University of Science and Technology

Research output: Contribution to journal › Article › peer-review

167 Scopus citations

Abstract

Perovskite light-emitting diodes (PeLEDs) based on three-dimensional (3D) polycrystalline perovskites suffer from ion migration, which causes overshoot of luminance over time during operation and reduces its operational lifetime. Here, we demonstrate 3D/2D hybrid PeLEDs with extremely reduced luminance overshoot and 21 times longer operational lifetime than 3D PeLEDs. The luminance overshoot ratio of 3D/2D hybrid PeLED is only 7.4% which is greatly lower than that of 3D PeLED (150.4%). The 3D/2D hybrid perovskite is obtained by adding a small amount of neutral benzylamine to methylammonium lead bromide, which induces a proton transfer from methylammonium to benzylamine and enables crystallization of 2D perovskite without destroying the 3D phase. Benzylammonium in the perovskite lattice suppresses formation of deep-trap states and ion migration, thereby enhances both operating stability and luminous efficiency based on its retardation effect in reorientation.

Original language	English
Article number	3378
Journal	Nature Communications
Volume	11
Issue number	1
DOIs	https://doi.org/10.1038/s41467-020-17072-0
State	Published - 1 Dec 2020

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Kim, H., Kim, J. S., Heo, J. M., Pei, M., Park, I. H., Liu, Z., Yun, H. J., Park, M. H., Jeong, S. H., Kim, Y. H., Park, J. W., Oveisi, E., Nagane, S., Sadhanala, A., Zhang, L., Kweon, J. J., Lee, S. K., Yang, H., Jang, H. M., ... Lee, T. W. (2020). Proton-transfer-induced 3D/2D hybrid perovskites suppress ion migration and reduce luminance overshoot. Nature Communications, 11(1), Article 3378. https://doi.org/10.1038/s41467-020-17072-0

@article{7a8b5eaa29b04aa8a3fbe12bad1e2139,

title = "Proton-transfer-induced 3D/2D hybrid perovskites suppress ion migration and reduce luminance overshoot",

abstract = "Perovskite light-emitting diodes (PeLEDs) based on three-dimensional (3D) polycrystalline perovskites suffer from ion migration, which causes overshoot of luminance over time during operation and reduces its operational lifetime. Here, we demonstrate 3D/2D hybrid PeLEDs with extremely reduced luminance overshoot and 21 times longer operational lifetime than 3D PeLEDs. The luminance overshoot ratio of 3D/2D hybrid PeLED is only 7.4\% which is greatly lower than that of 3D PeLED (150.4\%). The 3D/2D hybrid perovskite is obtained by adding a small amount of neutral benzylamine to methylammonium lead bromide, which induces a proton transfer from methylammonium to benzylamine and enables crystallization of 2D perovskite without destroying the 3D phase. Benzylammonium in the perovskite lattice suppresses formation of deep-trap states and ion migration, thereby enhances both operating stability and luminous efficiency based on its retardation effect in reorientation.",

author = "Hobeom Kim and Kim, \{Joo Sung\} and Heo, \{Jung Min\} and Mingyuan Pei and Park, \{In Hyeok\} and Zhun Liu and Yun, \{Hyung Joong\} and Park, \{Min Ho\} and Jeong, \{Su Hun\} and Kim, \{Young Hoon\} and Park, \{Jin Woo\} and Emad Oveisi and Satyawan Nagane and Aditya Sadhanala and Lijun Zhang and Kweon, \{Jin Jung\} and Lee, \{Sung Keun\} and Hoichang Yang and Jang, \{Hyun Myung\} and Friend, \{Richard H.\} and Loh, \{Kian Ping\} and Nazeeruddin, \{Mohammad Khaja\} and Park, \{Nam Gyu\} and Lee, \{Tae Woo\}",

note = "Publisher Copyright: {\textcopyright} 2020, The Author(s).",

year = "2020",

month = dec,

day = "1",

doi = "10.1038/s41467-020-17072-0",

language = "English",

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Kim, H, Kim, JS, Heo, JM, Pei, M, Park, IH, Liu, Z, Yun, HJ, Park, MH, Jeong, SH, Kim, YH, Park, JW, Oveisi, E, Nagane, S, Sadhanala, A, Zhang, L, Kweon, JJ, Lee, SK, Yang, H, Jang, HM, Friend, RH, Loh, KP, Nazeeruddin, MK, Park, NG & Lee, TW 2020, 'Proton-transfer-induced 3D/2D hybrid perovskites suppress ion migration and reduce luminance overshoot', Nature Communications, vol. 11, no. 1, 3378. https://doi.org/10.1038/s41467-020-17072-0

TY - JOUR

T1 - Proton-transfer-induced 3D/2D hybrid perovskites suppress ion migration and reduce luminance overshoot

AU - Kim, Hobeom

AU - Kim, Joo Sung

AU - Heo, Jung Min

AU - Pei, Mingyuan

AU - Park, In Hyeok

AU - Liu, Zhun

AU - Yun, Hyung Joong

AU - Park, Min Ho

AU - Jeong, Su Hun

AU - Kim, Young Hoon

AU - Park, Jin Woo

AU - Oveisi, Emad

AU - Nagane, Satyawan

AU - Sadhanala, Aditya

AU - Zhang, Lijun

AU - Kweon, Jin Jung

AU - Lee, Sung Keun

AU - Yang, Hoichang

AU - Jang, Hyun Myung

AU - Friend, Richard H.

AU - Loh, Kian Ping

AU - Nazeeruddin, Mohammad Khaja

AU - Park, Nam Gyu

AU - Lee, Tae Woo

PY - 2020/12/1

Y1 - 2020/12/1

N2 - Perovskite light-emitting diodes (PeLEDs) based on three-dimensional (3D) polycrystalline perovskites suffer from ion migration, which causes overshoot of luminance over time during operation and reduces its operational lifetime. Here, we demonstrate 3D/2D hybrid PeLEDs with extremely reduced luminance overshoot and 21 times longer operational lifetime than 3D PeLEDs. The luminance overshoot ratio of 3D/2D hybrid PeLED is only 7.4% which is greatly lower than that of 3D PeLED (150.4%). The 3D/2D hybrid perovskite is obtained by adding a small amount of neutral benzylamine to methylammonium lead bromide, which induces a proton transfer from methylammonium to benzylamine and enables crystallization of 2D perovskite without destroying the 3D phase. Benzylammonium in the perovskite lattice suppresses formation of deep-trap states and ion migration, thereby enhances both operating stability and luminous efficiency based on its retardation effect in reorientation.

AB - Perovskite light-emitting diodes (PeLEDs) based on three-dimensional (3D) polycrystalline perovskites suffer from ion migration, which causes overshoot of luminance over time during operation and reduces its operational lifetime. Here, we demonstrate 3D/2D hybrid PeLEDs with extremely reduced luminance overshoot and 21 times longer operational lifetime than 3D PeLEDs. The luminance overshoot ratio of 3D/2D hybrid PeLED is only 7.4% which is greatly lower than that of 3D PeLED (150.4%). The 3D/2D hybrid perovskite is obtained by adding a small amount of neutral benzylamine to methylammonium lead bromide, which induces a proton transfer from methylammonium to benzylamine and enables crystallization of 2D perovskite without destroying the 3D phase. Benzylammonium in the perovskite lattice suppresses formation of deep-trap states and ion migration, thereby enhances both operating stability and luminous efficiency based on its retardation effect in reorientation.

UR - https://www.scopus.com/pages/publications/85087504171

U2 - 10.1038/s41467-020-17072-0

DO - 10.1038/s41467-020-17072-0

M3 - Article

C2 - 32632144

AN - SCOPUS:85087504171

SN - 2041-1723

VL - 11

JO - Nature Communications

JF - Nature Communications

IS - 1

M1 - 3378

ER -

Proton-transfer-induced 3D/2D hybrid perovskites suppress ion migration and reduce luminance overshoot

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