Palladium(II)-catalyzed isomerization of olefins with tributyltin hydride

Su Kim In; Ri Dong Guang; Hoon Jung Young

doi:10.1021/jo0705263

Palladium(II)-catalyzed isomerization of olefins with tributyltin hydride

Su Kim In, Ri Dong Guang, Hoon Jung Young

Department of Pharmacy

Sungkyunkwan University

Research output: Contribution to journal › Article › peer-review

15 Scopus citations

Abstract

(Chemical Equation Presented) A new efficient method for the synthesis of geometrically pure (E)-alkenes from (Z)-alkenes is described. The reaction of aryl- or alkyl-substituted (Z)-alkenes with tributyltin hydride and triethylamine in the presence of a catalytic amount of palladium acetate afforded the corresponding (E)-alkenes in good yields.

Original language	English
Pages (from-to)	5424-5426
Number of pages	3
Journal	Journal of Organic Chemistry
Volume	72
Issue number	14
DOIs	https://doi.org/10.1021/jo0705263
State	Published - 6 Jul 2007

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title = "Palladium(II)-catalyzed isomerization of olefins with tributyltin hydride",

abstract = "(Chemical Equation Presented) A new efficient method for the synthesis of geometrically pure (E)-alkenes from (Z)-alkenes is described. The reaction of aryl- or alkyl-substituted (Z)-alkenes with tributyltin hydride and triethylamine in the presence of a catalytic amount of palladium acetate afforded the corresponding (E)-alkenes in good yields.",

author = "In, \{Su Kim\} and Guang, \{Ri Dong\} and Young, \{Hoon Jung\}",

year = "2007",

month = jul,

day = "6",

doi = "10.1021/jo0705263",

language = "English",

volume = "72",

pages = "5424--5426",

journal = "Journal of Organic Chemistry",

issn = "0022-3263",

publisher = "American Chemical Society",

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T1 - Palladium(II)-catalyzed isomerization of olefins with tributyltin hydride

AU - In, Su Kim

AU - Guang, Ri Dong

AU - Young, Hoon Jung

PY - 2007/7/6

Y1 - 2007/7/6

N2 - (Chemical Equation Presented) A new efficient method for the synthesis of geometrically pure (E)-alkenes from (Z)-alkenes is described. The reaction of aryl- or alkyl-substituted (Z)-alkenes with tributyltin hydride and triethylamine in the presence of a catalytic amount of palladium acetate afforded the corresponding (E)-alkenes in good yields.

AB - (Chemical Equation Presented) A new efficient method for the synthesis of geometrically pure (E)-alkenes from (Z)-alkenes is described. The reaction of aryl- or alkyl-substituted (Z)-alkenes with tributyltin hydride and triethylamine in the presence of a catalytic amount of palladium acetate afforded the corresponding (E)-alkenes in good yields.

UR - https://www.scopus.com/pages/publications/34447313119

U2 - 10.1021/jo0705263

DO - 10.1021/jo0705263

M3 - Article

C2 - 17552567

AN - SCOPUS:34447313119

SN - 0022-3263

VL - 72

SP - 5424

EP - 5426

JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

IS - 14

ER -

Palladium(II)-catalyzed isomerization of olefins with tributyltin hydride

Abstract

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