Oxidative Strong Metal-Support Interaction Induced by an Amorphous TiO_xSeed Layer Boosts the Electrochemical Performance and High-Temperature Durability of Pt Nanocatalysts

Nano-sized metal particles are widely used in various chemical/electrochemical fields due to their excellent catalytic activity, but they still suffer from deactivation by sintering, and this leads to serious issues regarding the price and lifespan of catalysts. In this study, we demonstrate that the introduction of nanoscale amorphous TiO_xvia atomic layer deposition can significantly improve the dispersion and durability of supported Pt nanocatalysts. An ultrathin TiO_xlayer (≪1 nm) deposited on a conductive Pr_0.5Ba_0.5MnO₃electrode, with a deposition time of less than 1 min, provides nucleation sites for the Pt nanocrystals impregnated thereon and promotes the migration of TiO_xto the Pt surface, creating a metal-oxide interface. As a result, when applied to ceramic fuel cells, the TiO_xundercoat achieves remarkable power density increases of over 100% and 400%, respectively, for wet (3% H₂O) H₂and CH₄fuels without degradation at 700 °C for 120 h. These observations provide an innovative direction for the design of supported metal catalysts for high-temperature applications.