Organometallic coordination networks based on π-bonded transition metal quinonoid complexes

Jeffrey A. Reingold; Seung Uk Son; Gene B. Carpenter; Dwight A. Sweigart

doi:10.1007/s10904-006-9024-0

Organometallic coordination networks based on π-bonded transition metal quinonoid complexes

Jeffrey A. Reingold, Seung Uk Son, Gene B. Carpenter, Dwight A. Sweigart

Department of Chemistry

Brown University

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

Hydroquinones π-bonded to the transition metal fragments Mn(CO) ₃⁺, Rh(COD)⁺, and Rh[P(OPh)₃] ₂⁺ are readily deprotonated to afford anionic η⁴-quinone complexes that function as organometalloligands by binding to metal ions through the quinone oxygen atoms. The resulting supramolecular assemblies display a variety of interesting and potentially useful network topologies.

Original language	English
Pages (from-to)	1-13
Number of pages	13
Journal	Journal of Inorganic and Organometallic Polymers and Materials
Volume	16
Issue number	1
DOIs	https://doi.org/10.1007/s10904-006-9024-0
State	Published - Mar 2006

Keywords

Coordination networks
Hydrogen-bonding
Organometalloligand
Polymers
Quinone complexes
Self-assembly

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10.1007/s10904-006-9024-0

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title = "Organometallic coordination networks based on π-bonded transition metal quinonoid complexes",

abstract = "Hydroquinones π-bonded to the transition metal fragments Mn(CO) 3+, Rh(COD)+, and Rh[P(OPh)3] 2+ are readily deprotonated to afford anionic η4-quinone complexes that function as organometalloligands by binding to metal ions through the quinone oxygen atoms. The resulting supramolecular assemblies display a variety of interesting and potentially useful network topologies.",

keywords = "Coordination networks, Hydrogen-bonding, Organometalloligand, Polymers, Quinone complexes, Self-assembly",

author = "Reingold, \{Jeffrey A.\} and Son, \{Seung Uk\} and Carpenter, \{Gene B.\} and Sweigart, \{Dwight A.\}",

year = "2006",

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doi = "10.1007/s10904-006-9024-0",

language = "English",

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T1 - Organometallic coordination networks based on π-bonded transition metal quinonoid complexes

AU - Reingold, Jeffrey A.

AU - Son, Seung Uk

AU - Carpenter, Gene B.

AU - Sweigart, Dwight A.

PY - 2006/3

Y1 - 2006/3

N2 - Hydroquinones π-bonded to the transition metal fragments Mn(CO) 3+, Rh(COD)+, and Rh[P(OPh)3] 2+ are readily deprotonated to afford anionic η4-quinone complexes that function as organometalloligands by binding to metal ions through the quinone oxygen atoms. The resulting supramolecular assemblies display a variety of interesting and potentially useful network topologies.

AB - Hydroquinones π-bonded to the transition metal fragments Mn(CO) 3+, Rh(COD)+, and Rh[P(OPh)3] 2+ are readily deprotonated to afford anionic η4-quinone complexes that function as organometalloligands by binding to metal ions through the quinone oxygen atoms. The resulting supramolecular assemblies display a variety of interesting and potentially useful network topologies.

KW - Coordination networks

KW - Hydrogen-bonding

KW - Organometalloligand

KW - Polymers

KW - Quinone complexes

KW - Self-assembly

UR - https://www.scopus.com/pages/publications/33747131818

U2 - 10.1007/s10904-006-9024-0

DO - 10.1007/s10904-006-9024-0

M3 - Article

AN - SCOPUS:33747131818

SN - 1574-1443

VL - 16

SP - 1

EP - 13

JO - Journal of Inorganic and Organometallic Polymers and Materials

JF - Journal of Inorganic and Organometallic Polymers and Materials

IS - 1

ER -

Organometallic coordination networks based on π-bonded transition metal quinonoid complexes

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Keywords

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