New heteroleptic magnesium complexes for MgO thin film application

Hyo Suk Kim; Sheby Mary George; Bo Keun Park; Seung Uk Son; Chang Gyoun Kim; Taek Mo Chung

doi:10.1039/c4dt03497j

New heteroleptic magnesium complexes for MgO thin film application

Hyo Suk Kim
, Sheby Mary George
, Bo Keun Park
, Seung Uk Son
, Chang Gyoun Kim
, Taek Mo Chung

Department of Chemistry

Korea Research Institute of Chemical Technology
Sungkyunkwan University

Research output: Contribution to journal › Article › peer-review

20 Scopus citations

Abstract

Novel heteroleptic magnesium complexes, [Mg(dmamp)(acac)]₂ (1), [Mg(dmamp)(tmhd)]₂ (2), [Mg(dmamp)(tfac)]₂ (3), and [Mg(dmamp)(hfac)]₂ (4), were successfully synthesized using dmamp and β-diketonate as ligands. The thermogravimetric analyses and volatile studies of the complexes showed that the complexes 2 and 4 display high volatility and thermal stability. The single crystal X-ray study of the complexes reveals that both the complexes 1 and 2 were crystalized in the triclinic space group and as dimers, where magnesium atoms are in the pentacoordinate state with distorted trigonal bipyramidal geometry.

Original language	English
Pages (from-to)	2103-2109
Number of pages	7
Journal	Dalton Transactions
Volume	44
Issue number	5
DOIs	https://doi.org/10.1039/c4dt03497j
State	Published - 7 Feb 2015

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title = "New heteroleptic magnesium complexes for MgO thin film application",

abstract = "Novel heteroleptic magnesium complexes, [Mg(dmamp)(acac)]2 (1), [Mg(dmamp)(tmhd)]2 (2), [Mg(dmamp)(tfac)]2 (3), and [Mg(dmamp)(hfac)]2 (4), were successfully synthesized using dmamp and β-diketonate as ligands. The thermogravimetric analyses and volatile studies of the complexes showed that the complexes 2 and 4 display high volatility and thermal stability. The single crystal X-ray study of the complexes reveals that both the complexes 1 and 2 were crystalized in the triclinic space group and as dimers, where magnesium atoms are in the pentacoordinate state with distorted trigonal bipyramidal geometry.",

author = "Kim, \{Hyo Suk\} and George, \{Sheby Mary\} and Park, \{Bo Keun\} and Son, \{Seung Uk\} and Kim, \{Chang Gyoun\} and Chung, \{Taek Mo\}",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2015.",

year = "2015",

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doi = "10.1039/c4dt03497j",

language = "English",

volume = "44",

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journal = "Dalton Transactions",

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TY - JOUR

T1 - New heteroleptic magnesium complexes for MgO thin film application

AU - Kim, Hyo Suk

AU - George, Sheby Mary

AU - Park, Bo Keun

AU - Son, Seung Uk

AU - Kim, Chang Gyoun

AU - Chung, Taek Mo

PY - 2015/2/7

Y1 - 2015/2/7

N2 - Novel heteroleptic magnesium complexes, [Mg(dmamp)(acac)]2 (1), [Mg(dmamp)(tmhd)]2 (2), [Mg(dmamp)(tfac)]2 (3), and [Mg(dmamp)(hfac)]2 (4), were successfully synthesized using dmamp and β-diketonate as ligands. The thermogravimetric analyses and volatile studies of the complexes showed that the complexes 2 and 4 display high volatility and thermal stability. The single crystal X-ray study of the complexes reveals that both the complexes 1 and 2 were crystalized in the triclinic space group and as dimers, where magnesium atoms are in the pentacoordinate state with distorted trigonal bipyramidal geometry.

AB - Novel heteroleptic magnesium complexes, [Mg(dmamp)(acac)]2 (1), [Mg(dmamp)(tmhd)]2 (2), [Mg(dmamp)(tfac)]2 (3), and [Mg(dmamp)(hfac)]2 (4), were successfully synthesized using dmamp and β-diketonate as ligands. The thermogravimetric analyses and volatile studies of the complexes showed that the complexes 2 and 4 display high volatility and thermal stability. The single crystal X-ray study of the complexes reveals that both the complexes 1 and 2 were crystalized in the triclinic space group and as dimers, where magnesium atoms are in the pentacoordinate state with distorted trigonal bipyramidal geometry.

UR - https://www.scopus.com/pages/publications/84921676532

U2 - 10.1039/c4dt03497j

DO - 10.1039/c4dt03497j

M3 - Article

AN - SCOPUS:84921676532

SN - 1477-9226

VL - 44

SP - 2103

EP - 2109

JO - Dalton Transactions

JF - Dalton Transactions

IS - 5

ER -

New heteroleptic magnesium complexes for MgO thin film application

Abstract

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