New heteroleptic magnesium complexes for MgO thin film application

Hyo Suk Kim; Sheby Mary George; Bo Keun Park; Seung Uk Son; Chang Gyoun Kim; Taek Mo Chung

doi:10.1039/c4dt03497j

New heteroleptic magnesium complexes for MgO thin film application

Hyo Suk Kim, Sheby Mary George, Bo Keun Park, Seung Uk Son, Chang Gyoun Kim, Taek Mo Chung

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

20 Scopus citations

Abstract

Novel heteroleptic magnesium complexes, [Mg(dmamp)(acac)]₂ (1), [Mg(dmamp)(tmhd)]₂ (2), [Mg(dmamp)(tfac)]₂ (3), and [Mg(dmamp)(hfac)]₂ (4), were successfully synthesized using dmamp and β-diketonate as ligands. The thermogravimetric analyses and volatile studies of the complexes showed that the complexes 2 and 4 display high volatility and thermal stability. The single crystal X-ray study of the complexes reveals that both the complexes 1 and 2 were crystalized in the triclinic space group and as dimers, where magnesium atoms are in the pentacoordinate state with distorted trigonal bipyramidal geometry.

Original language	English
Pages (from-to)	2103-2109
Number of pages	7
Journal	Dalton Transactions
Volume	44
Issue number	5
DOIs	https://doi.org/10.1039/c4dt03497j
State	Published - 7 Feb 2015

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title = "New heteroleptic magnesium complexes for MgO thin film application",

abstract = "Novel heteroleptic magnesium complexes, [Mg(dmamp)(acac)]2 (1), [Mg(dmamp)(tmhd)]2 (2), [Mg(dmamp)(tfac)]2 (3), and [Mg(dmamp)(hfac)]2 (4), were successfully synthesized using dmamp and β-diketonate as ligands. The thermogravimetric analyses and volatile studies of the complexes showed that the complexes 2 and 4 display high volatility and thermal stability. The single crystal X-ray study of the complexes reveals that both the complexes 1 and 2 were crystalized in the triclinic space group and as dimers, where magnesium atoms are in the pentacoordinate state with distorted trigonal bipyramidal geometry.",

author = "Kim, \{Hyo Suk\} and George, \{Sheby Mary\} and Park, \{Bo Keun\} and Son, \{Seung Uk\} and Kim, \{Chang Gyoun\} and Chung, \{Taek Mo\}",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2015.",

year = "2015",

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doi = "10.1039/c4dt03497j",

language = "English",

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journal = "Dalton Transactions",

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TY - JOUR

T1 - New heteroleptic magnesium complexes for MgO thin film application

AU - Kim, Hyo Suk

AU - George, Sheby Mary

AU - Park, Bo Keun

AU - Son, Seung Uk

AU - Kim, Chang Gyoun

AU - Chung, Taek Mo

PY - 2015/2/7

Y1 - 2015/2/7

N2 - Novel heteroleptic magnesium complexes, [Mg(dmamp)(acac)]2 (1), [Mg(dmamp)(tmhd)]2 (2), [Mg(dmamp)(tfac)]2 (3), and [Mg(dmamp)(hfac)]2 (4), were successfully synthesized using dmamp and β-diketonate as ligands. The thermogravimetric analyses and volatile studies of the complexes showed that the complexes 2 and 4 display high volatility and thermal stability. The single crystal X-ray study of the complexes reveals that both the complexes 1 and 2 were crystalized in the triclinic space group and as dimers, where magnesium atoms are in the pentacoordinate state with distorted trigonal bipyramidal geometry.

AB - Novel heteroleptic magnesium complexes, [Mg(dmamp)(acac)]2 (1), [Mg(dmamp)(tmhd)]2 (2), [Mg(dmamp)(tfac)]2 (3), and [Mg(dmamp)(hfac)]2 (4), were successfully synthesized using dmamp and β-diketonate as ligands. The thermogravimetric analyses and volatile studies of the complexes showed that the complexes 2 and 4 display high volatility and thermal stability. The single crystal X-ray study of the complexes reveals that both the complexes 1 and 2 were crystalized in the triclinic space group and as dimers, where magnesium atoms are in the pentacoordinate state with distorted trigonal bipyramidal geometry.

UR - https://www.scopus.com/pages/publications/84921676532

U2 - 10.1039/c4dt03497j

DO - 10.1039/c4dt03497j

M3 - Article

AN - SCOPUS:84921676532

SN - 1477-9226

VL - 44

SP - 2103

EP - 2109

JO - Dalton Transactions

JF - Dalton Transactions

IS - 5

ER -

New heteroleptic magnesium complexes for MgO thin film application

Abstract

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