Network-controlled unique reactivities of carbonyl groups in hollow and microporous organic polymer

Myung Hyun Kim, Jaewon Choi, Kyoung Chul Ko, Kyoungil Cho, Ji Hoon Park, Sang Moon Lee, Hae Jin Kim, Yoon Joo Ko, Jin Yong Lee, Seung Uk Son

Research output: Contribution to journalArticlepeer-review

20 Scopus citations

Abstract

Hollow and microporous organic network bearing alkynone moieties was prepared via carbonylative Sonogashira coupling. The carbonyl groups in the network showed unusual chemical reactivities, compared with those of a model alkynone compound. The observed differences between the reactivities of alkynones in the molecule and in the network were analyzed based on the "network effect".

Original languageEnglish
Pages (from-to)5134-5137
Number of pages4
JournalChemical Communications
Volume54
Issue number40
DOIs
StatePublished - 2018

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