Nd2K2IrO7 and Sm2K 2IrO7: Iridium(VI) oxides prepared under ambient pressure

Samuel J. Mugavero; Mark D. Smith; Won Sub Yoon; Hans Conrad Zur Loye

doi:10.1002/anie.200804045

Nd₂K₂IrO₇ and Sm₂K ₂IrO₇: Iridium(VI) oxides prepared under ambient pressure

Samuel J. Mugavero, Mark D. Smith, Won Sub Yoon, Hans Conrad Zur Loye

Research output: Contribution to journal › Article › peer-review

35 Scopus citations

Abstract

No pressure: The most-oxidized iridium oxides known to date are prepared in a hydroxide flux under normal pressure. They contain iridium centers exclusively in the +VI oxidation state and are characterized crystallographically. The picture shows the structure of the Ln ₂K₂IrO₇ (Ln = Nd, Sm) and its structural components: IrO₆ octahedra (black), KO₁₀ polyhedra (beige), LnO₁₀ polyhedra (blue). (Figure Presented).

Original language	English
Pages (from-to)	215-218
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	48
Issue number	1
DOIs	https://doi.org/10.1002/anie.200804045
State	Published - 2009
Externally published	Yes

Keywords

High oxidation state
Iridium
Oxides
Structure elucidation
X-ray absorption spectroscopy

Access to Document

10.1002/anie.200804045

Cite this

@article{8d08528093a64b56848f8218eb242756,

title = "Nd2K2IrO7 and Sm2K 2IrO7: Iridium(VI) oxides prepared under ambient pressure",

abstract = "No pressure: The most-oxidized iridium oxides known to date are prepared in a hydroxide flux under normal pressure. They contain iridium centers exclusively in the +VI oxidation state and are characterized crystallographically. The picture shows the structure of the Ln 2K2IrO7 (Ln = Nd, Sm) and its structural components: IrO6 octahedra (black), KO10 polyhedra (beige), LnO10 polyhedra (blue). (Figure Presented).",

keywords = "High oxidation state, Iridium, Oxides, Structure elucidation, X-ray absorption spectroscopy",

author = "Mugavero, \{Samuel J.\} and Smith, \{Mark D.\} and Yoon, \{Won Sub\} and \{Zur Loye\}, \{Hans Conrad\}",

year = "2009",

doi = "10.1002/anie.200804045",

language = "English",

volume = "48",

pages = "215--218",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Ltd",

number = "1",

}

TY - JOUR

T1 - Nd2K2IrO7 and Sm2K 2IrO7

T2 - Iridium(VI) oxides prepared under ambient pressure

AU - Mugavero, Samuel J.

AU - Smith, Mark D.

AU - Yoon, Won Sub

AU - Zur Loye, Hans Conrad

PY - 2009

Y1 - 2009

N2 - No pressure: The most-oxidized iridium oxides known to date are prepared in a hydroxide flux under normal pressure. They contain iridium centers exclusively in the +VI oxidation state and are characterized crystallographically. The picture shows the structure of the Ln 2K2IrO7 (Ln = Nd, Sm) and its structural components: IrO6 octahedra (black), KO10 polyhedra (beige), LnO10 polyhedra (blue). (Figure Presented).

AB - No pressure: The most-oxidized iridium oxides known to date are prepared in a hydroxide flux under normal pressure. They contain iridium centers exclusively in the +VI oxidation state and are characterized crystallographically. The picture shows the structure of the Ln 2K2IrO7 (Ln = Nd, Sm) and its structural components: IrO6 octahedra (black), KO10 polyhedra (beige), LnO10 polyhedra (blue). (Figure Presented).

KW - High oxidation state

KW - Iridium

KW - Oxides

KW - Structure elucidation

KW - X-ray absorption spectroscopy

UR - https://www.scopus.com/pages/publications/58249135062

U2 - 10.1002/anie.200804045

DO - 10.1002/anie.200804045

M3 - Article

AN - SCOPUS:58249135062

SN - 1433-7851

VL - 48

SP - 215

EP - 218

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 1

ER -

Nd₂K₂IrO₇ and Sm₂K ₂IrO₇: Iridium(VI) oxides prepared under ambient pressure

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this