Monodisperse micron-sized crosslinked polystyrene particles. VII. Importance of monomer-diffusible surface characteristics of growing particles

Jin Woong Kim; Chung Hyuk Lee; Jung Bae Jun; Kyung Do Suh

doi:10.1016/S0927-7757(01)00805-6

Monodisperse micron-sized crosslinked polystyrene particles. VII. Importance of monomer-diffusible surface characteristics of growing particles

Jin Woong Kim
, Chung Hyuk Lee
, Jung Bae Jun
, Kyung Do Suh

Amorepacific Corporation
Hanyang University

Research output: Contribution to journal › Article › peer-review

19 Scopus citations

Abstract

The monodisperse micron-sized polystyrene particles crosslinked with polyether diol diacrylates were produced by a simple dispersion polymerization in an ethanol solution. Unlike conventional divinylmonomers, the polyether diol diacrylates used as a crosslinker showed an excellent effect on maintaining the particle monodispersity even in a moderate crosslinker concentration. It is believed that the monomer-diffusible surface of primary particles played a decisive role in achieving the monodispersity of final particles by suppressing the second nucleation. The importance of monomer-diffusivity was tried to understand systematically in producing the crosslinked micron-sized polymer particles by the dispersion polymerization.

Original language	English
Pages (from-to)	57-64
Number of pages	8
Journal	Colloids and Surfaces A: Physicochemical and Engineering Aspects
Volume	194
Issue number	1-3
DOIs	https://doi.org/10.1016/S0927-7757(01)00805-6
State	Published - 20 Dec 2001
Externally published	Yes

Keywords

Monomer-diffusible surface
Polyether diol diacrylate
Second nucleation

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10.1016/S0927-7757(01)00805-6

Cite this

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title = "Monodisperse micron-sized crosslinked polystyrene particles. VII. Importance of monomer-diffusible surface characteristics of growing particles",

abstract = "The monodisperse micron-sized polystyrene particles crosslinked with polyether diol diacrylates were produced by a simple dispersion polymerization in an ethanol solution. Unlike conventional divinylmonomers, the polyether diol diacrylates used as a crosslinker showed an excellent effect on maintaining the particle monodispersity even in a moderate crosslinker concentration. It is believed that the monomer-diffusible surface of primary particles played a decisive role in achieving the monodispersity of final particles by suppressing the second nucleation. The importance of monomer-diffusivity was tried to understand systematically in producing the crosslinked micron-sized polymer particles by the dispersion polymerization.",

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}

Monodisperse micron-sized crosslinked polystyrene particles. VII. Importance of monomer-diffusible surface characteristics of growing particles. / Kim, Jin Woong; Lee, Chung Hyuk; Jun, Jung Bae et al.
In: Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 194, No. 1-3, 20.12.2001, p. 57-64.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Monodisperse micron-sized crosslinked polystyrene particles. VII. Importance of monomer-diffusible surface characteristics of growing particles

AU - Kim, Jin Woong

AU - Lee, Chung Hyuk

AU - Jun, Jung Bae

AU - Suh, Kyung Do

PY - 2001/12/20

Y1 - 2001/12/20

N2 - The monodisperse micron-sized polystyrene particles crosslinked with polyether diol diacrylates were produced by a simple dispersion polymerization in an ethanol solution. Unlike conventional divinylmonomers, the polyether diol diacrylates used as a crosslinker showed an excellent effect on maintaining the particle monodispersity even in a moderate crosslinker concentration. It is believed that the monomer-diffusible surface of primary particles played a decisive role in achieving the monodispersity of final particles by suppressing the second nucleation. The importance of monomer-diffusivity was tried to understand systematically in producing the crosslinked micron-sized polymer particles by the dispersion polymerization.

AB - The monodisperse micron-sized polystyrene particles crosslinked with polyether diol diacrylates were produced by a simple dispersion polymerization in an ethanol solution. Unlike conventional divinylmonomers, the polyether diol diacrylates used as a crosslinker showed an excellent effect on maintaining the particle monodispersity even in a moderate crosslinker concentration. It is believed that the monomer-diffusible surface of primary particles played a decisive role in achieving the monodispersity of final particles by suppressing the second nucleation. The importance of monomer-diffusivity was tried to understand systematically in producing the crosslinked micron-sized polymer particles by the dispersion polymerization.

KW - Monomer-diffusible surface

KW - Polyether diol diacrylate

KW - Second nucleation

UR - https://www.scopus.com/pages/publications/0035924033

U2 - 10.1016/S0927-7757(01)00805-6

DO - 10.1016/S0927-7757(01)00805-6

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AN - SCOPUS:0035924033

SN - 0927-7757

VL - 194

SP - 57

EP - 64

JO - Colloids and Surfaces A: Physicochemical and Engineering Aspects

JF - Colloids and Surfaces A: Physicochemical and Engineering Aspects

IS - 1-3

ER -

Monodisperse micron-sized crosslinked polystyrene particles. VII. Importance of monomer-diffusible surface characteristics of growing particles

Abstract

Keywords

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