TY - JOUR
T1 - Molecular sheets in the crystal structure of a Ba(II) complex with imidazole-4,5-dicarboxylate and water ligands
AU - Starosta, Wojciech
AU - Leciejewicz, Janusz
AU - Premkumar, Thathan
AU - Govindarajan, Subbian
PY - 2007
Y1 - 2007
N2 - The structure of poly-tetraaquabis(μ-Himidazole-4,5-dicarboxylato-N,O;- O′)barium(II) dihydrate, Ba(C5H3N2O4)2(H2O)4·2H2O is built of molecular sheets in which singly-deprotonated imidazole-4,5-dicarboxylate [H(4,5-IDA)] bridges metal ions using its N, O bonding moiety and one oxygen atom of its second carboxylate group. Each barium(II) is coordinated by N, O bonding moieties of two ligands, two carboxylate oxygen atoms of two other ligands and four waters. The coordination number of Ba(II) is ten, and the coordination polyhedron contains fourteen faces. A network of hydrogen bonds is responsible for the stability of the crystal.
AB - The structure of poly-tetraaquabis(μ-Himidazole-4,5-dicarboxylato-N,O;- O′)barium(II) dihydrate, Ba(C5H3N2O4)2(H2O)4·2H2O is built of molecular sheets in which singly-deprotonated imidazole-4,5-dicarboxylate [H(4,5-IDA)] bridges metal ions using its N, O bonding moiety and one oxygen atom of its second carboxylate group. Each barium(II) is coordinated by N, O bonding moieties of two ligands, two carboxylate oxygen atoms of two other ligands and four waters. The coordination number of Ba(II) is ten, and the coordination polyhedron contains fourteen faces. A network of hydrogen bonds is responsible for the stability of the crystal.
KW - Barium(II) compounds
KW - Crystal structure
KW - Imidazole-4,5-dicarboxylate ligand
UR - https://www.scopus.com/pages/publications/33947324679
U2 - 10.1080/00958970600784025
DO - 10.1080/00958970600784025
M3 - Article
AN - SCOPUS:33947324679
SN - 0095-8972
VL - 60
SP - 313
EP - 318
JO - Journal of Coordination Chemistry
JF - Journal of Coordination Chemistry
IS - 3
ER -