Metal-organic decomposition-mediated nanoparticulate vanadium oxide hole transporting buffer layer for polymer bulk-heterojunction solar cells

In this study, a solution-processable compact vanadium oxide (V₂O₅) film with a globular nanoparticulate structure is introduced to the hole transport layer (HTL) of polymer bulk-heterojunction based solar cells comprised of PTB7:PC₇₀BMby using a facilemetal-organic decompositionmethod to replace the conventionallyutilizedpoly(3,4-ethylenedioxythiophene): poly(styrenesulfonate) (PEDOT:PSS). For this, a biocompatible structure-determining agent, polyethylene glycol (PEG, M_n 300), is used as an additive in the precursor to form the nanoparticulate compact V₂O₅ (hereafter referred to as NP-V₂O₅) film, which possesses an outstandingly smooth surface morphology. The introduction of NP-V₂O₅ HTL via the solution process with a neutral pH condition successfully improved the stability by preventing the decomposition of indium tin oxide (ITO) glass and the penetration of heavy-metal components and moisture, which are considered as the crucial drawbacks of using PEDOT:PSS. Over 1440 h (60 days) of the stability test, an organic solar cell (OSC) with NP-V₂O₅ showed a significant durability, maintaining 82% of its initial power conversion efficiency (PCE), whereas an OSC with PEDOT:PSSmaintained 51% of its initial PCE. Furthermore, due to the positive effects of the modified surface properties of NP-V₂O₅, the PCE was slightly enhanced from 7.47% to 7.89% with a significant improvement in the short-circuit current density and fill factor.