Manganese oxide-based heterogeneous electrocatalysts for water oxidation

Sunghak Park; Yoon Ho Lee; Seungwoo Choi; Hongmin Seo; Moo Young Lee; Mani Balamurugan; Ki Tae Nam

doi:10.1039/d0ee00815j

Manganese oxide-based heterogeneous electrocatalysts for water oxidation

Sunghak Park, Yoon Ho Lee, Seungwoo Choi, Hongmin Seo, Moo Young Lee, Mani Balamurugan, Ki Tae Nam

Seoul National University

Research output: Contribution to journal › Review article › peer-review

106 Scopus citations

Abstract

Water oxidation is considered an important reaction to attain sustainable energy systems. Inspired by the biological Mn4CaO5 cluster, considerable effort has been devoted to developing efficient manganese-based heterogeneous catalysts for the water oxidation reaction. This review first describes the structural characteristics of the Mn4CaO5 cluster and synthetic manganese oxides. Important features related to the electrocatalytic activity of manganese-based heterogeneous catalysts as well as recent in situ spectroscopic results for intermediate characterization are then summarized. Current understanding of the reaction mechanism at the atomic level and the rate-determining step is highlighted. Finally, future perspectives for the development of highly active and stable manganese-based water-oxidizing catalysts are proposed.

Original language	English
Pages (from-to)	2310-2340
Number of pages	31
Journal	Energy and Environmental Science
Volume	13
Issue number	8
DOIs	https://doi.org/10.1039/d0ee00815j
State	Published - Aug 2020
Externally published	Yes

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1039/d0ee00815j

Cite this

@article{922cff8738644d4487394cf8ca20c6df,

title = "Manganese oxide-based heterogeneous electrocatalysts for water oxidation",

abstract = "Water oxidation is considered an important reaction to attain sustainable energy systems. Inspired by the biological Mn4CaO5 cluster, considerable effort has been devoted to developing efficient manganese-based heterogeneous catalysts for the water oxidation reaction. This review first describes the structural characteristics of the Mn4CaO5 cluster and synthetic manganese oxides. Important features related to the electrocatalytic activity of manganese-based heterogeneous catalysts as well as recent in situ spectroscopic results for intermediate characterization are then summarized. Current understanding of the reaction mechanism at the atomic level and the rate-determining step is highlighted. Finally, future perspectives for the development of highly active and stable manganese-based water-oxidizing catalysts are proposed.",

author = "Sunghak Park and Lee, \{Yoon Ho\} and Seungwoo Choi and Hongmin Seo and Lee, \{Moo Young\} and Mani Balamurugan and Nam, \{Ki Tae\}",

note = "Publisher Copyright: {\textcopyright} 2020 The Royal Society of Chemistry.",

year = "2020",

month = aug,

doi = "10.1039/d0ee00815j",

language = "English",

volume = "13",

pages = "2310--2340",

journal = "Energy and Environmental Science",

issn = "1754-5692",

publisher = "Royal Society of Chemistry",

number = "8",

}

TY - JOUR

T1 - Manganese oxide-based heterogeneous electrocatalysts for water oxidation

AU - Park, Sunghak

AU - Lee, Yoon Ho

AU - Choi, Seungwoo

AU - Seo, Hongmin

AU - Lee, Moo Young

AU - Balamurugan, Mani

AU - Nam, Ki Tae

PY - 2020/8

Y1 - 2020/8

N2 - Water oxidation is considered an important reaction to attain sustainable energy systems. Inspired by the biological Mn4CaO5 cluster, considerable effort has been devoted to developing efficient manganese-based heterogeneous catalysts for the water oxidation reaction. This review first describes the structural characteristics of the Mn4CaO5 cluster and synthetic manganese oxides. Important features related to the electrocatalytic activity of manganese-based heterogeneous catalysts as well as recent in situ spectroscopic results for intermediate characterization are then summarized. Current understanding of the reaction mechanism at the atomic level and the rate-determining step is highlighted. Finally, future perspectives for the development of highly active and stable manganese-based water-oxidizing catalysts are proposed.

AB - Water oxidation is considered an important reaction to attain sustainable energy systems. Inspired by the biological Mn4CaO5 cluster, considerable effort has been devoted to developing efficient manganese-based heterogeneous catalysts for the water oxidation reaction. This review first describes the structural characteristics of the Mn4CaO5 cluster and synthetic manganese oxides. Important features related to the electrocatalytic activity of manganese-based heterogeneous catalysts as well as recent in situ spectroscopic results for intermediate characterization are then summarized. Current understanding of the reaction mechanism at the atomic level and the rate-determining step is highlighted. Finally, future perspectives for the development of highly active and stable manganese-based water-oxidizing catalysts are proposed.

UR - https://www.scopus.com/pages/publications/85089185244

U2 - 10.1039/d0ee00815j

DO - 10.1039/d0ee00815j

M3 - Review article

AN - SCOPUS:85089185244

SN - 1754-5692

VL - 13

SP - 2310

EP - 2340

JO - Energy and Environmental Science

JF - Energy and Environmental Science

IS - 8

ER -

Manganese oxide-based heterogeneous electrocatalysts for water oxidation

Abstract

UN SDGs

Access to Document

Other files and links

Fingerprint

Cite this