Low ligand field strength ion (I−) mediated 1D inorganic material MoI3: Synthesis and application to photo-detectors

Kyung Hwan Choi; Seungbae Oh; Sudong Chae; Byung Joo Jeong; Bum Jun Kim; Jiho Jeon; Sang Hoon Lee; Sang Ok Yoon; Chaeheon Woo; Xue Dong; Asghar Ghulam; Changmo Lim; Zhixiang Liu; Cong Wang; Ali Junaid; Jae Hyun Lee; Hak Ki Yu; Jae Young Choi

doi:10.1016/j.jallcom.2020.157375

Low ligand field strength ion (I⁻) mediated 1D inorganic material MoI₃: Synthesis and application to photo-detectors

Kyung Hwan Choi, Seungbae Oh, Sudong Chae, Byung Joo Jeong, Bum Jun Kim, Jiho Jeon, Sang Hoon Lee, Sang Ok Yoon, Chaeheon Woo, Xue Dong, Asghar Ghulam, Changmo Lim, Zhixiang Liu, Cong Wang, Ali Junaid, Jae Hyun Lee, Hak Ki Yu, Jae Young Choi

Department of Advanced Materials Science and Engineering

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

A new type of 1D inorganic material, MoI₃, which can be separated into individual 1D chains, was synthesized through a vapor transport reaction between molybdenum and iodine. High-purity and centimeter-scale large MoI₃ crystals were obtained by controlling the growth temperature and the stoichiometric ratio between molybdenum and iodine. Their semiconductor characteristics were confirmed by measuring the electrical conductivity as a function of temperature (conductivity increased with increased temperature across the range −70 to 30 °C). Furthermore, it was confirmed that MoI₃ with a 1.27 eV band gap can be separated to a few nanometer scale through mechanical and chemical exfoliation methods and can be used as a photodetector in the near IR (less than 1000 nm)-to-visible light region. This novel 1D material is expected to play an important role in the development of additional low-dimensional materials and in advanced nano-optoelectronic devices.

Original language	English
Article number	157375
Journal	Journal of Alloys and Compounds
Volume	853
DOIs	https://doi.org/10.1016/j.jallcom.2020.157375
State	Published - 5 Feb 2021

Keywords

1D inorganic materials
Mechanical exfoliation
MoI
Photodetectors

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10.1016/j.jallcom.2020.157375

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Choi, K. H., Oh, S., Chae, S., Jeong, B. J., Kim, B. J., Jeon, J., Lee, S. H., Yoon, S. O., Woo, C., Dong, X., Ghulam, A., Lim, C., Liu, Z., Wang, C., Junaid, A., Lee, J. H., Yu, H. K., & Choi, J. Y. (2021). Low ligand field strength ion (I⁻) mediated 1D inorganic material MoI₃: Synthesis and application to photo-detectors. Journal of Alloys and Compounds, 853, Article 157375. https://doi.org/10.1016/j.jallcom.2020.157375

@article{cb391e192d2c484283b675e4bd81a8d0,

title = "Low ligand field strength ion (I−) mediated 1D inorganic material MoI3: Synthesis and application to photo-detectors",

abstract = "A new type of 1D inorganic material, MoI3, which can be separated into individual 1D chains, was synthesized through a vapor transport reaction between molybdenum and iodine. High-purity and centimeter-scale large MoI3 crystals were obtained by controlling the growth temperature and the stoichiometric ratio between molybdenum and iodine. Their semiconductor characteristics were confirmed by measuring the electrical conductivity as a function of temperature (conductivity increased with increased temperature across the range −70 to 30 °C). Furthermore, it was confirmed that MoI3 with a 1.27 eV band gap can be separated to a few nanometer scale through mechanical and chemical exfoliation methods and can be used as a photodetector in the near IR (less than 1000 nm)-to-visible light region. This novel 1D material is expected to play an important role in the development of additional low-dimensional materials and in advanced nano-optoelectronic devices.",

keywords = "1D inorganic materials, Mechanical exfoliation, MoI, Photodetectors",

author = "Choi, \{Kyung Hwan\} and Seungbae Oh and Sudong Chae and Jeong, \{Byung Joo\} and Kim, \{Bum Jun\} and Jiho Jeon and Lee, \{Sang Hoon\} and Yoon, \{Sang Ok\} and Chaeheon Woo and Xue Dong and Asghar Ghulam and Changmo Lim and Zhixiang Liu and Cong Wang and Ali Junaid and Lee, \{Jae Hyun\} and Yu, \{Hak Ki\} and Choi, \{Jae Young\}",

note = "Publisher Copyright: {\textcopyright} 2020 Elsevier B.V.",

year = "2021",

month = feb,

day = "5",

doi = "10.1016/j.jallcom.2020.157375",

language = "English",

volume = "853",

journal = "Journal of Alloys and Compounds",

issn = "0925-8388",

publisher = "Elsevier B.V.",

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Choi, KH, Oh, S, Chae, S, Jeong, BJ, Kim, BJ, Jeon, J, Lee, SH, Yoon, SO, Woo, C, Dong, X, Ghulam, A, Lim, C, Liu, Z, Wang, C, Junaid, A, Lee, JH, Yu, HK & Choi, JY 2021, 'Low ligand field strength ion (I⁻) mediated 1D inorganic material MoI₃: Synthesis and application to photo-detectors', Journal of Alloys and Compounds, vol. 853, 157375. https://doi.org/10.1016/j.jallcom.2020.157375

TY - JOUR

T1 - Low ligand field strength ion (I−) mediated 1D inorganic material MoI3

T2 - Synthesis and application to photo-detectors

AU - Choi, Kyung Hwan

AU - Oh, Seungbae

AU - Chae, Sudong

AU - Jeong, Byung Joo

AU - Kim, Bum Jun

AU - Jeon, Jiho

AU - Lee, Sang Hoon

AU - Yoon, Sang Ok

AU - Woo, Chaeheon

AU - Dong, Xue

AU - Ghulam, Asghar

AU - Lim, Changmo

AU - Liu, Zhixiang

AU - Wang, Cong

AU - Junaid, Ali

AU - Lee, Jae Hyun

AU - Yu, Hak Ki

AU - Choi, Jae Young

PY - 2021/2/5

Y1 - 2021/2/5

N2 - A new type of 1D inorganic material, MoI3, which can be separated into individual 1D chains, was synthesized through a vapor transport reaction between molybdenum and iodine. High-purity and centimeter-scale large MoI3 crystals were obtained by controlling the growth temperature and the stoichiometric ratio between molybdenum and iodine. Their semiconductor characteristics were confirmed by measuring the electrical conductivity as a function of temperature (conductivity increased with increased temperature across the range −70 to 30 °C). Furthermore, it was confirmed that MoI3 with a 1.27 eV band gap can be separated to a few nanometer scale through mechanical and chemical exfoliation methods and can be used as a photodetector in the near IR (less than 1000 nm)-to-visible light region. This novel 1D material is expected to play an important role in the development of additional low-dimensional materials and in advanced nano-optoelectronic devices.

AB - A new type of 1D inorganic material, MoI3, which can be separated into individual 1D chains, was synthesized through a vapor transport reaction between molybdenum and iodine. High-purity and centimeter-scale large MoI3 crystals were obtained by controlling the growth temperature and the stoichiometric ratio between molybdenum and iodine. Their semiconductor characteristics were confirmed by measuring the electrical conductivity as a function of temperature (conductivity increased with increased temperature across the range −70 to 30 °C). Furthermore, it was confirmed that MoI3 with a 1.27 eV band gap can be separated to a few nanometer scale through mechanical and chemical exfoliation methods and can be used as a photodetector in the near IR (less than 1000 nm)-to-visible light region. This novel 1D material is expected to play an important role in the development of additional low-dimensional materials and in advanced nano-optoelectronic devices.

KW - 1D inorganic materials

KW - Mechanical exfoliation

KW - MoI

KW - Photodetectors

UR - https://www.scopus.com/pages/publications/85091978778

U2 - 10.1016/j.jallcom.2020.157375

DO - 10.1016/j.jallcom.2020.157375

M3 - Article

AN - SCOPUS:85091978778

SN - 0925-8388

VL - 853

JO - Journal of Alloys and Compounds

JF - Journal of Alloys and Compounds

M1 - 157375

ER -

Low ligand field strength ion (I⁻) mediated 1D inorganic material MoI₃: Synthesis and application to photo-detectors

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Keywords

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