Low dimensionality magnetism in new layered oxides: The phyllosiloxides

K. P. Hong; G. Goglio; G. Demazeau; D. Y. Jung

doi:10.4028/www.scientific.net/ddf.208-209.251

Low dimensionality magnetism in new layered oxides: The phyllosiloxides

K. P. Hong, G. Goglio, G. Demazeau, D. Y. Jung

ENSCPB Ecole National Supérieure de Chimie et Physique de Bordeaux

Research output: Contribution to journal › Conference article › peer-review

3 Scopus citations

Abstract

Three new compounds (KFeMg₂Si₄O₁₂, KAlFe₂Si₄O₁₂, KFe₄Si₃O₁₂) have been prepared by a solvothermal synthesis using a gel precursor and 2-methoxyethanol as solvent at 750°C and 160 MPa during 3 days. The powder X-ray diffraction characterizations indicate that these new materials are isostructural with 1M polytype of phlogopite mica and exhibit a layered structure. Moreover the infrared spectra confirm the absence of hydroxyls groups in the structure, which improves the thermal stability of the materials. Finally the observed magnetic behaviors are consistent with low dimensionality magnetism.

Original language	English
Pages (from-to)	251-254
Number of pages	4
Journal	Defect and Diffusion Forum
Volume	208-209
DOIs	https://doi.org/10.4028/www.scientific.net/ddf.208-209.251
State	Published - 2002
Externally published	Yes
Event	4th High Pressure School on Chemistry, Biology, Materials Science and Techniques - Warswaw, Poland Duration: 22 Jun 2001 → 25 Jun 2001

Keywords

Layered Oxide
Magnetism
Phyllosiloxide
Solvothermal Synthesis
Supercritical Conditions

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10.4028/www.scientific.net/ddf.208-209.251

Cite this

@article{b52d2b72632f42058a2dcc45b23ec71f,

title = "Low dimensionality magnetism in new layered oxides: The phyllosiloxides",

abstract = "Three new compounds (KFeMg2Si4O12, KAlFe2Si4O12, KFe4Si3O12) have been prepared by a solvothermal synthesis using a gel precursor and 2-methoxyethanol as solvent at 750°C and 160 MPa during 3 days. The powder X-ray diffraction characterizations indicate that these new materials are isostructural with 1M polytype of phlogopite mica and exhibit a layered structure. Moreover the infrared spectra confirm the absence of hydroxyls groups in the structure, which improves the thermal stability of the materials. Finally the observed magnetic behaviors are consistent with low dimensionality magnetism.",

keywords = "Layered Oxide, Magnetism, Phyllosiloxide, Solvothermal Synthesis, Supercritical Conditions",

author = "Hong, \{K. P.\} and G. Goglio and G. Demazeau and Jung, \{D. Y.\}",

year = "2002",

doi = "10.4028/www.scientific.net/ddf.208-209.251",

language = "English",

volume = "208-209",

pages = "251--254",

journal = "Defect and Diffusion Forum",

issn = "1012-0386",

publisher = "Trans Tech Publications Ltd",

note = "4th High Pressure School on Chemistry, Biology, Materials Science and Techniques ; Conference date: 22-06-2001 Through 25-06-2001",

}

TY - JOUR

T1 - Low dimensionality magnetism in new layered oxides

T2 - 4th High Pressure School on Chemistry, Biology, Materials Science and Techniques

AU - Hong, K. P.

AU - Goglio, G.

AU - Demazeau, G.

AU - Jung, D. Y.

PY - 2002

Y1 - 2002

N2 - Three new compounds (KFeMg2Si4O12, KAlFe2Si4O12, KFe4Si3O12) have been prepared by a solvothermal synthesis using a gel precursor and 2-methoxyethanol as solvent at 750°C and 160 MPa during 3 days. The powder X-ray diffraction characterizations indicate that these new materials are isostructural with 1M polytype of phlogopite mica and exhibit a layered structure. Moreover the infrared spectra confirm the absence of hydroxyls groups in the structure, which improves the thermal stability of the materials. Finally the observed magnetic behaviors are consistent with low dimensionality magnetism.

AB - Three new compounds (KFeMg2Si4O12, KAlFe2Si4O12, KFe4Si3O12) have been prepared by a solvothermal synthesis using a gel precursor and 2-methoxyethanol as solvent at 750°C and 160 MPa during 3 days. The powder X-ray diffraction characterizations indicate that these new materials are isostructural with 1M polytype of phlogopite mica and exhibit a layered structure. Moreover the infrared spectra confirm the absence of hydroxyls groups in the structure, which improves the thermal stability of the materials. Finally the observed magnetic behaviors are consistent with low dimensionality magnetism.

KW - Layered Oxide

KW - Magnetism

KW - Phyllosiloxide

KW - Solvothermal Synthesis

KW - Supercritical Conditions

UR - https://www.scopus.com/pages/publications/0036430895

U2 - 10.4028/www.scientific.net/ddf.208-209.251

DO - 10.4028/www.scientific.net/ddf.208-209.251

M3 - Conference article

AN - SCOPUS:0036430895

SN - 1012-0386

VL - 208-209

SP - 251

EP - 254

JO - Defect and Diffusion Forum

JF - Defect and Diffusion Forum

Y2 - 22 June 2001 through 25 June 2001

ER -

Low dimensionality magnetism in new layered oxides: The phyllosiloxides

Abstract

Keywords

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