Abstract
We present a comparative study of the low-dimensional compounds α- and β-TeVO 4. Our data clearly show that the change in the local coordination geometry of V 4+ ions comparing α- and β-TeVO 4 leads to a drastic differences in the magnetic properties. Despite sharing the same crystal structure, the two compounds realize different magnetic exchange topologies. Both compounds exhibit a transition from ferro- to antiferromagnetic correlations with decreasing temperature. This effect however is driven by different mechanisms for both compounds. Additionally, a dimensional crossover is found in β-TeVO 4.
| Original language | English |
|---|---|
| Pages (from-to) | 715-727 |
| Number of pages | 13 |
| Journal | Fizika Nizkikh Temperatur |
| Volume | 38 |
| Issue number | 7 |
| State | Published - Jul 2012 |
| Externally published | Yes |
Keywords
- Low-dimensional magnetic systems
- Phononic and magnetic excitations
- Raman scattering
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