Iridium(VI) stabilized in a perovskite-type lattice: Ba2CalrO6

Gérard Demazeau; Duk Young Jung; Jean Pierre Sanchez; Eric Colineau; Alain Blaise; Léopold Fournes

doi:10.1016/0038-1098(93)90004-7

Iridium(VI) stabilized in a perovskite-type lattice: Ba₂CalrO₆

Gérard Demazeau
, Duk Young Jung
, Jean Pierre Sanchez
, Eric Colineau
, Alain Blaise
, Léopold Fournes

Université de Bordeaux
Commissariat à l’énergie atomique et aux énergies alternatives

Research output: Contribution to journal › Article › peer-review

35 Scopus citations

Abstract

For the first time iridium(VI) was stabilized in an octahedral site of the perovskite lattice Ba₂CaIrO₆ using optimized structural and chemical bonding factors and oxygen pressure. The stabilization of this unusual oxidation state was inferred from chemical analysis, structural and magnetic measurements and from ¹⁹³Ir Mössbauer study.

Original language	English
Pages (from-to)	479-484
Number of pages	6
Journal	Solid State Communications
Volume	85
Issue number	6
DOIs	https://doi.org/10.1016/0038-1098(93)90004-7
State	Published - Feb 1993
Externally published	Yes

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10.1016/0038-1098(93)90004-7

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title = "Iridium(VI) stabilized in a perovskite-type lattice: Ba2CalrO6",

abstract = "For the first time iridium(VI) was stabilized in an octahedral site of the perovskite lattice Ba2CaIrO6 using optimized structural and chemical bonding factors and oxygen pressure. The stabilization of this unusual oxidation state was inferred from chemical analysis, structural and magnetic measurements and from 193Ir M{\"o}ssbauer study.",

author = "G{\'e}rard Demazeau and Jung, \{Duk Young\} and Sanchez, \{Jean Pierre\} and Eric Colineau and Alain Blaise and L{\'e}opold Fournes",

year = "1993",

month = feb,

doi = "10.1016/0038-1098(93)90004-7",

language = "English",

volume = "85",

pages = "479--484",

journal = "Solid State Communications",

issn = "0038-1098",

publisher = "Elsevier Ltd",

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TY - JOUR

T1 - Iridium(VI) stabilized in a perovskite-type lattice

T2 - Ba2CalrO6

AU - Demazeau, Gérard

AU - Jung, Duk Young

AU - Sanchez, Jean Pierre

AU - Colineau, Eric

AU - Blaise, Alain

AU - Fournes, Léopold

PY - 1993/2

Y1 - 1993/2

N2 - For the first time iridium(VI) was stabilized in an octahedral site of the perovskite lattice Ba2CaIrO6 using optimized structural and chemical bonding factors and oxygen pressure. The stabilization of this unusual oxidation state was inferred from chemical analysis, structural and magnetic measurements and from 193Ir Mössbauer study.

AB - For the first time iridium(VI) was stabilized in an octahedral site of the perovskite lattice Ba2CaIrO6 using optimized structural and chemical bonding factors and oxygen pressure. The stabilization of this unusual oxidation state was inferred from chemical analysis, structural and magnetic measurements and from 193Ir Mössbauer study.

UR - https://www.scopus.com/pages/publications/0027539686

U2 - 10.1016/0038-1098(93)90004-7

DO - 10.1016/0038-1098(93)90004-7

M3 - Article

AN - SCOPUS:0027539686

SN - 0038-1098

VL - 85

SP - 479

EP - 484

JO - Solid State Communications

JF - Solid State Communications

IS - 6

ER -

Iridium(VI) stabilized in a perovskite-type lattice: Ba₂CalrO₆

Abstract

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