TY - JOUR
T1 - Ionothermal synthesis of 3D zinc coordination polymer
T2 - [Zn2(BTC)(OH)(I)](BMIM) containing novel tetra nuclear building unit
AU - Xu, Ling
AU - Choi, Eun Young
AU - Kwon, Young Uk
PY - 2008/2
Y1 - 2008/2
N2 - A novel coordination polymer, [Zn2(BTC)(OH)(I)](BMIM) (H3BTC = 1,3,5-benzenetricarboxylic acid and BMIM = 1-butyl-3-methylimidazolium), is synthesized from the ionothermal reaction (160 °C, 5 days) of Zn(NO3)2 and H3BTC in 1-butyl-3-methylimidazolium iodide ([BMIM]I) ionic liquid and is structurally characterized. The structure exhibits a three-dimensional framework constructed from tetra nuclear building unit [Zn4(OH)2(I)2(CO2)6], which is the first appearance in zinc coordination polymers. The imidazolium cation [BMIM]+ of the ionic liquid acting as charge compensating agent has strong interactions with the framework. This compound is thermally stable up to ca. 300 °C based on TGA.
AB - A novel coordination polymer, [Zn2(BTC)(OH)(I)](BMIM) (H3BTC = 1,3,5-benzenetricarboxylic acid and BMIM = 1-butyl-3-methylimidazolium), is synthesized from the ionothermal reaction (160 °C, 5 days) of Zn(NO3)2 and H3BTC in 1-butyl-3-methylimidazolium iodide ([BMIM]I) ionic liquid and is structurally characterized. The structure exhibits a three-dimensional framework constructed from tetra nuclear building unit [Zn4(OH)2(I)2(CO2)6], which is the first appearance in zinc coordination polymers. The imidazolium cation [BMIM]+ of the ionic liquid acting as charge compensating agent has strong interactions with the framework. This compound is thermally stable up to ca. 300 °C based on TGA.
KW - Coordination polymer
KW - Imidazolium iodide
KW - Ionothermal reaction
KW - Tetra nuclear building unit
UR - https://www.scopus.com/pages/publications/38549113937
U2 - 10.1016/j.inoche.2007.11.008
DO - 10.1016/j.inoche.2007.11.008
M3 - Article
AN - SCOPUS:38549113937
SN - 1387-7003
VL - 11
SP - 150
EP - 154
JO - Inorganic Chemistry Communications
JF - Inorganic Chemistry Communications
IS - 2
ER -