Intramolecular charge transfer of π-conjugated push-pull systems in terms of polarizability and electronegativity

Jin Yong Lee; Kwang S. Kim; Byung Jin Mhin

doi:10.1063/1.1413986

Intramolecular charge transfer of π-conjugated push-pull systems in terms of polarizability and electronegativity

Jin Yong Lee, Kwang S. Kim, Byung Jin Mhin

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76 Scopus citations

Abstract

The origin of ICT was elucidated in push-pull systems. A simple model was established to estimate the amount of ICT for various systems as a function of the properties of monosubstituted systems. The model was verified from the studies for various push-pull bridge systems of butadiene, benzene, and stilbene, with various donor and acceptors. It was found that the amount of ICT for a push-pull system can be estimated by the electronegativities and polarizabilities of push and pull systems.

Original language	English
Pages (from-to)	9484-9489
Number of pages	6
Journal	Journal of Chemical Physics
Volume	115
Issue number	20
DOIs	https://doi.org/10.1063/1.1413986
State	Published - 22 Nov 2001
Externally published	Yes

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title = "Intramolecular charge transfer of π-conjugated push-pull systems in terms of polarizability and electronegativity",

abstract = "The origin of ICT was elucidated in push-pull systems. A simple model was established to estimate the amount of ICT for various systems as a function of the properties of monosubstituted systems. The model was verified from the studies for various push-pull bridge systems of butadiene, benzene, and stilbene, with various donor and acceptors. It was found that the amount of ICT for a push-pull system can be estimated by the electronegativities and polarizabilities of push and pull systems.",

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year = "2001",

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AU - Lee, Jin Yong

AU - Kim, Kwang S.

AU - Mhin, Byung Jin

PY - 2001/11/22

Y1 - 2001/11/22

N2 - The origin of ICT was elucidated in push-pull systems. A simple model was established to estimate the amount of ICT for various systems as a function of the properties of monosubstituted systems. The model was verified from the studies for various push-pull bridge systems of butadiene, benzene, and stilbene, with various donor and acceptors. It was found that the amount of ICT for a push-pull system can be estimated by the electronegativities and polarizabilities of push and pull systems.

AB - The origin of ICT was elucidated in push-pull systems. A simple model was established to estimate the amount of ICT for various systems as a function of the properties of monosubstituted systems. The model was verified from the studies for various push-pull bridge systems of butadiene, benzene, and stilbene, with various donor and acceptors. It was found that the amount of ICT for a push-pull system can be estimated by the electronegativities and polarizabilities of push and pull systems.

UR - https://www.scopus.com/pages/publications/0035935877

U2 - 10.1063/1.1413986

DO - 10.1063/1.1413986

M3 - Article

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SN - 0021-9606

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EP - 9489

JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

IS - 20

ER -

Intramolecular charge transfer of π-conjugated push-pull systems in terms of polarizability and electronegativity

Abstract

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