In-situ blends of polypyrrole/poly(3,4-ethylenedioxythiopene) using vapor phase polymerization technique

Dong Ouk Kim; Pyoung Chan Lee; Soo Jung Kang; Keonsoo Jang; Jun Ho Lee; Min Ho Cho; Jae Do Nam

doi:10.1016/j.tsf.2009.02.028

In-situ blends of polypyrrole/poly(3,4-ethylenedioxythiopene) using vapor phase polymerization technique

Dong Ouk Kim, Pyoung Chan Lee, Soo Jung Kang, Keonsoo Jang, Jun Ho Lee, Min Ho Cho, Jae Do Nam

Department of Chemical Engineering

Research output: Contribution to journal › Article › peer-review

21 Scopus citations

Abstract

We report the In-situ blends of polypyrrole/poly(3,4-ethylenedioxythiophene) synthesized as thin-films on glass substrates using the vapor-phase polymerization (VPP) technique. The blend ratios of PPy to 3,4-ethylenedioxythiopene were controlled by adjusting the amount of liquid-phase monomers placed in the VPP chamber. ATR-FTIR spectroscopy was used to examine the composition of blends. The electrical conductivity of the PPy/PEDOT coating increased from 4 S/cm for the pristine PPy to 58 S/cm in the case of an EDOT ratio of 1.0. Color and light transmittance changes were observed. The surface roughness values increased from 2.94 nm to 16.67 nm.

Original language	English
Pages (from-to)	4156-4160
Number of pages	5
Journal	Thin Solid Films
Volume	517
Issue number	14
DOIs	https://doi.org/10.1016/j.tsf.2009.02.028
State	Published - 29 May 2009

Keywords

Conducting polymer
Electrical conductivity
In-situ blend
PEDOT
Polypyrrole
Vapor-phase polymerization

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10.1016/j.tsf.2009.02.028

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title = "In-situ blends of polypyrrole/poly(3,4-ethylenedioxythiopene) using vapor phase polymerization technique",

abstract = "We report the In-situ blends of polypyrrole/poly(3,4-ethylenedioxythiophene) synthesized as thin-films on glass substrates using the vapor-phase polymerization (VPP) technique. The blend ratios of PPy to 3,4-ethylenedioxythiopene were controlled by adjusting the amount of liquid-phase monomers placed in the VPP chamber. ATR-FTIR spectroscopy was used to examine the composition of blends. The electrical conductivity of the PPy/PEDOT coating increased from 4 S/cm for the pristine PPy to 58 S/cm in the case of an EDOT ratio of 1.0. Color and light transmittance changes were observed. The surface roughness values increased from 2.94 nm to 16.67 nm.",

keywords = "Conducting polymer, Electrical conductivity, In-situ blend, PEDOT, Polypyrrole, Vapor-phase polymerization",

author = "Kim, \{Dong Ouk\} and Lee, \{Pyoung Chan\} and Kang, \{Soo Jung\} and Keonsoo Jang and Lee, \{Jun Ho\} and Cho, \{Min Ho\} and Nam, \{Jae Do\}",

year = "2009",

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doi = "10.1016/j.tsf.2009.02.028",

language = "English",

volume = "517",

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T1 - In-situ blends of polypyrrole/poly(3,4-ethylenedioxythiopene) using vapor phase polymerization technique

AU - Kim, Dong Ouk

AU - Lee, Pyoung Chan

AU - Kang, Soo Jung

AU - Jang, Keonsoo

AU - Lee, Jun Ho

AU - Cho, Min Ho

AU - Nam, Jae Do

PY - 2009/5/29

Y1 - 2009/5/29

N2 - We report the In-situ blends of polypyrrole/poly(3,4-ethylenedioxythiophene) synthesized as thin-films on glass substrates using the vapor-phase polymerization (VPP) technique. The blend ratios of PPy to 3,4-ethylenedioxythiopene were controlled by adjusting the amount of liquid-phase monomers placed in the VPP chamber. ATR-FTIR spectroscopy was used to examine the composition of blends. The electrical conductivity of the PPy/PEDOT coating increased from 4 S/cm for the pristine PPy to 58 S/cm in the case of an EDOT ratio of 1.0. Color and light transmittance changes were observed. The surface roughness values increased from 2.94 nm to 16.67 nm.

AB - We report the In-situ blends of polypyrrole/poly(3,4-ethylenedioxythiophene) synthesized as thin-films on glass substrates using the vapor-phase polymerization (VPP) technique. The blend ratios of PPy to 3,4-ethylenedioxythiopene were controlled by adjusting the amount of liquid-phase monomers placed in the VPP chamber. ATR-FTIR spectroscopy was used to examine the composition of blends. The electrical conductivity of the PPy/PEDOT coating increased from 4 S/cm for the pristine PPy to 58 S/cm in the case of an EDOT ratio of 1.0. Color and light transmittance changes were observed. The surface roughness values increased from 2.94 nm to 16.67 nm.

KW - Conducting polymer

KW - Electrical conductivity

KW - In-situ blend

KW - PEDOT

KW - Polypyrrole

KW - Vapor-phase polymerization

UR - https://www.scopus.com/pages/publications/65449134021

U2 - 10.1016/j.tsf.2009.02.028

DO - 10.1016/j.tsf.2009.02.028

M3 - Article

AN - SCOPUS:65449134021

SN - 0040-6090

VL - 517

SP - 4156

EP - 4160

JO - Thin Solid Films

JF - Thin Solid Films

IS - 14

ER -

In-situ blends of polypyrrole/poly(3,4-ethylenedioxythiopene) using vapor phase polymerization technique

Abstract

Keywords

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