Hollow and Microporous Organic Polymers Bearing Sulfonic Acids: Antifouling Seed Materials for Polyketone Synthesis

Nojin Park; Yu Na Lim; Shin Young Kang; Sang Moon Lee; Hae Jin Kim; Yoon Joo Ko; Bun Yeoul Lee; Hye Young Jang; Seung Uk Son

doi:10.1021/acsmacrolett.6b00846

Hollow and Microporous Organic Polymers Bearing Sulfonic Acids: Antifouling Seed Materials for Polyketone Synthesis

Nojin Park, Yu Na Lim, Shin Young Kang, Sang Moon Lee, Hae Jin Kim, Yoon Joo Ko, Bun Yeoul Lee, Hye Young Jang, Seung Uk Son

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

38 Scopus citations

Abstract

The reactor fouling is a notorious obstacle in managing continuous synthetic processes of polyketones. The fouling raises synthetic costs and reduces the bulk density of polymers. Thus, efficient seed materials are required for antifouling performance. Hollow microporous organic polymers (HMOPs) were prepared using ZIF-8 nanoparticles as templating materials. Sulfonic groups were incorporated into HMOP via a post synthetic approach. The resultant HMOP-SO₃H (20-90 μg/mL in methanol) showed successful catalyst activation and antifouling performance in polyketone synthesis.

Original language	English
Pages (from-to)	1322-1326
Number of pages	5
Journal	ACS Macro Letters
Volume	5
Issue number	12
DOIs	https://doi.org/10.1021/acsmacrolett.6b00846
State	Published - 20 Dec 2016

Access to Document

10.1021/acsmacrolett.6b00846

Cite this

@article{032aa4ff4a174f489f2b29f8679ed59b,

title = "Hollow and Microporous Organic Polymers Bearing Sulfonic Acids: Antifouling Seed Materials for Polyketone Synthesis",

abstract = "The reactor fouling is a notorious obstacle in managing continuous synthetic processes of polyketones. The fouling raises synthetic costs and reduces the bulk density of polymers. Thus, efficient seed materials are required for antifouling performance. Hollow microporous organic polymers (HMOPs) were prepared using ZIF-8 nanoparticles as templating materials. Sulfonic groups were incorporated into HMOP via a post synthetic approach. The resultant HMOP-SO3H (20-90 μg/mL in methanol) showed successful catalyst activation and antifouling performance in polyketone synthesis.",

author = "Nojin Park and Lim, \{Yu Na\} and Kang, \{Shin Young\} and Lee, \{Sang Moon\} and Kim, \{Hae Jin\} and Ko, \{Yoon Joo\} and Lee, \{Bun Yeoul\} and Jang, \{Hye Young\} and Son, \{Seung Uk\}",

note = "Publisher Copyright: {\textcopyright} 2016 American Chemical Society.",

year = "2016",

month = dec,

day = "20",

doi = "10.1021/acsmacrolett.6b00846",

language = "English",

volume = "5",

pages = "1322--1326",

journal = "ACS Macro Letters",

issn = "2161-1653",

publisher = "American Chemical Society",

number = "12",

}

TY - JOUR

T1 - Hollow and Microporous Organic Polymers Bearing Sulfonic Acids

T2 - Antifouling Seed Materials for Polyketone Synthesis

AU - Park, Nojin

AU - Lim, Yu Na

AU - Kang, Shin Young

AU - Lee, Sang Moon

AU - Kim, Hae Jin

AU - Ko, Yoon Joo

AU - Lee, Bun Yeoul

AU - Jang, Hye Young

AU - Son, Seung Uk

PY - 2016/12/20

Y1 - 2016/12/20

N2 - The reactor fouling is a notorious obstacle in managing continuous synthetic processes of polyketones. The fouling raises synthetic costs and reduces the bulk density of polymers. Thus, efficient seed materials are required for antifouling performance. Hollow microporous organic polymers (HMOPs) were prepared using ZIF-8 nanoparticles as templating materials. Sulfonic groups were incorporated into HMOP via a post synthetic approach. The resultant HMOP-SO3H (20-90 μg/mL in methanol) showed successful catalyst activation and antifouling performance in polyketone synthesis.

AB - The reactor fouling is a notorious obstacle in managing continuous synthetic processes of polyketones. The fouling raises synthetic costs and reduces the bulk density of polymers. Thus, efficient seed materials are required for antifouling performance. Hollow microporous organic polymers (HMOPs) were prepared using ZIF-8 nanoparticles as templating materials. Sulfonic groups were incorporated into HMOP via a post synthetic approach. The resultant HMOP-SO3H (20-90 μg/mL in methanol) showed successful catalyst activation and antifouling performance in polyketone synthesis.

UR - https://www.scopus.com/pages/publications/85007015577

U2 - 10.1021/acsmacrolett.6b00846

DO - 10.1021/acsmacrolett.6b00846

M3 - Article

AN - SCOPUS:85007015577

SN - 2161-1653

VL - 5

SP - 1322

EP - 1326

JO - ACS Macro Letters

JF - ACS Macro Letters

IS - 12

ER -

Hollow and Microporous Organic Polymers Bearing Sulfonic Acids: Antifouling Seed Materials for Polyketone Synthesis

Abstract

Access to Document

Other files and links

Fingerprint

Cite this