Highly active and stable catalytic performance on phosphorous-promoted Ru/Co/Zr/SiO2 Fischer-Tropsch catalyst

Jong Wook Bae; Seung Moon Kim; Seon Ju Park; Yun Jo Lee; Kyoung Su Ha; Ki Won Jun

doi:10.1016/j.catcom.2010.03.003

Highly active and stable catalytic performance on phosphorous-promoted Ru/Co/Zr/SiO₂ Fischer-Tropsch catalyst

Jong Wook Bae, Seung Moon Kim, Seon Ju Park, Yun Jo Lee, Kyoung Su Ha, Ki Won Jun

Korea Research Institute of Chemical Technology

Research output: Contribution to journal › Article › peer-review

21 Scopus citations

Abstract

A novel doubly promoted Ru/Co/ZrP/SiO₂ catalyst with zirconium-phosphorous species (ZrP) reveals high activity and stability on Fischer-Tropsch synthesis (FTS). The surface modification of SiO₂ with ZrP species containing appropriate amount of phosphorous component, has an effect on the suppression of cobalt particle aggregation during FTS reaction. The spatial confinement of cobalt particles in ZrP matrix could be significantly enhanced when P/(Zr + P) molar ratio is around 0.13 (CoZrP(0.5)).

Original language	English
Pages (from-to)	834-838
Number of pages	5
Journal	Catalysis Communications
Volume	11
Issue number	9
DOIs	https://doi.org/10.1016/j.catcom.2010.03.003
State	Published - 30 Apr 2010
Externally published	Yes

Keywords

Aggregation
Cobalt
Fischer-Tropsch synthesis
Spatial confinement
Zirconium-phosphorous species

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10.1016/j.catcom.2010.03.003

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title = "Highly active and stable catalytic performance on phosphorous-promoted Ru/Co/Zr/SiO2 Fischer-Tropsch catalyst",

abstract = "A novel doubly promoted Ru/Co/ZrP/SiO2 catalyst with zirconium-phosphorous species (ZrP) reveals high activity and stability on Fischer-Tropsch synthesis (FTS). The surface modification of SiO2 with ZrP species containing appropriate amount of phosphorous component, has an effect on the suppression of cobalt particle aggregation during FTS reaction. The spatial confinement of cobalt particles in ZrP matrix could be significantly enhanced when P/(Zr + P) molar ratio is around 0.13 (CoZrP(0.5)).",

keywords = "Aggregation, Cobalt, Fischer-Tropsch synthesis, Spatial confinement, Zirconium-phosphorous species",

author = "Bae, \{Jong Wook\} and Kim, \{Seung Moon\} and Park, \{Seon Ju\} and Lee, \{Yun Jo\} and Ha, \{Kyoung Su\} and Jun, \{Ki Won\}",

year = "2010",

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day = "30",

doi = "10.1016/j.catcom.2010.03.003",

language = "English",

volume = "11",

pages = "834--838",

journal = "Catalysis Communications",

issn = "1566-7367",

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TY - JOUR

T1 - Highly active and stable catalytic performance on phosphorous-promoted Ru/Co/Zr/SiO2 Fischer-Tropsch catalyst

AU - Bae, Jong Wook

AU - Kim, Seung Moon

AU - Park, Seon Ju

AU - Lee, Yun Jo

AU - Ha, Kyoung Su

AU - Jun, Ki Won

PY - 2010/4/30

Y1 - 2010/4/30

N2 - A novel doubly promoted Ru/Co/ZrP/SiO2 catalyst with zirconium-phosphorous species (ZrP) reveals high activity and stability on Fischer-Tropsch synthesis (FTS). The surface modification of SiO2 with ZrP species containing appropriate amount of phosphorous component, has an effect on the suppression of cobalt particle aggregation during FTS reaction. The spatial confinement of cobalt particles in ZrP matrix could be significantly enhanced when P/(Zr + P) molar ratio is around 0.13 (CoZrP(0.5)).

AB - A novel doubly promoted Ru/Co/ZrP/SiO2 catalyst with zirconium-phosphorous species (ZrP) reveals high activity and stability on Fischer-Tropsch synthesis (FTS). The surface modification of SiO2 with ZrP species containing appropriate amount of phosphorous component, has an effect on the suppression of cobalt particle aggregation during FTS reaction. The spatial confinement of cobalt particles in ZrP matrix could be significantly enhanced when P/(Zr + P) molar ratio is around 0.13 (CoZrP(0.5)).

KW - Aggregation

KW - Cobalt

KW - Fischer-Tropsch synthesis

KW - Spatial confinement

KW - Zirconium-phosphorous species

UR - https://www.scopus.com/pages/publications/77951025771

U2 - 10.1016/j.catcom.2010.03.003

DO - 10.1016/j.catcom.2010.03.003

M3 - Article

AN - SCOPUS:77951025771

SN - 1566-7367

VL - 11

SP - 834

EP - 838

JO - Catalysis Communications

JF - Catalysis Communications

IS - 9

ER -

Highly active and stable catalytic performance on phosphorous-promoted Ru/Co/Zr/SiO₂ Fischer-Tropsch catalyst

Abstract

Keywords

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