Heteroleptic magnesium complexes containing amidinate and aminoalkoxy ligands

Hyo Suk Kim; Sheby Mary George; Eun Ae Jung; Bo Keun Park; Seung Uk Son; Chang Gyoun Kim; Taek Mo Chung

doi:10.1016/j.poly.2015.09.018

Heteroleptic magnesium complexes containing amidinate and aminoalkoxy ligands

Hyo Suk Kim
, Sheby Mary George
, Eun Ae Jung
, Bo Keun Park
, Seung Uk Son
, Chang Gyoun Kim
, Taek Mo Chung

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

New heteroleptic magnesium complexes, [Mg(dmamp)(η²-MeC(NEt)(N^tBu))]₂ (1), [Mg(dmamp)(η²-MeC(NⁱPr)₂]₂ (2), and [Mg(dmamp)(η²-MeC(N^tBu)₂]₂ (3), containing a combination of amidinate and aminoalkoxy ligands were synthesized and characterized by NMR, FT-IR, elemental analysis, and thermogravimetric analysis (TGA). The single-crystal X-ray diffraction study of these complexes (1-3) reveals that all complexes were formed as dimers where the aminoalkoxy ligand acts as the bridge between the two metal centers.

Original language	English
Pages (from-to)	185-190
Number of pages	6
Journal	Polyhedron
Volume	101
DOIs	https://doi.org/10.1016/j.poly.2015.09.018
State	Published - 24 Nov 2015

Keywords

Amidinate
Aminoalkoxy
Heteroleptic
Magnesium
Precursor

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10.1016/j.poly.2015.09.018

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title = "Heteroleptic magnesium complexes containing amidinate and aminoalkoxy ligands",

abstract = "New heteroleptic magnesium complexes, [Mg(dmamp)(η2-MeC(NEt)(NtBu))]2 (1), [Mg(dmamp)(η2-MeC(NiPr)2]2 (2), and [Mg(dmamp)(η2-MeC(NtBu)2]2 (3), containing a combination of amidinate and aminoalkoxy ligands were synthesized and characterized by NMR, FT-IR, elemental analysis, and thermogravimetric analysis (TGA). The single-crystal X-ray diffraction study of these complexes (1-3) reveals that all complexes were formed as dimers where the aminoalkoxy ligand acts as the bridge between the two metal centers.",

keywords = "Amidinate, Aminoalkoxy, Heteroleptic, Magnesium, Precursor",

author = "Kim, \{Hyo Suk\} and George, \{Sheby Mary\} and Jung, \{Eun Ae\} and Park, \{Bo Keun\} and Son, \{Seung Uk\} and Kim, \{Chang Gyoun\} and Chung, \{Taek Mo\}",

year = "2015",

month = nov,

day = "24",

doi = "10.1016/j.poly.2015.09.018",

language = "English",

volume = "101",

pages = "185--190",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier Ltd",

}

TY - JOUR

T1 - Heteroleptic magnesium complexes containing amidinate and aminoalkoxy ligands

AU - Kim, Hyo Suk

AU - George, Sheby Mary

AU - Jung, Eun Ae

AU - Park, Bo Keun

AU - Son, Seung Uk

AU - Kim, Chang Gyoun

AU - Chung, Taek Mo

PY - 2015/11/24

Y1 - 2015/11/24

N2 - New heteroleptic magnesium complexes, [Mg(dmamp)(η2-MeC(NEt)(NtBu))]2 (1), [Mg(dmamp)(η2-MeC(NiPr)2]2 (2), and [Mg(dmamp)(η2-MeC(NtBu)2]2 (3), containing a combination of amidinate and aminoalkoxy ligands were synthesized and characterized by NMR, FT-IR, elemental analysis, and thermogravimetric analysis (TGA). The single-crystal X-ray diffraction study of these complexes (1-3) reveals that all complexes were formed as dimers where the aminoalkoxy ligand acts as the bridge between the two metal centers.

AB - New heteroleptic magnesium complexes, [Mg(dmamp)(η2-MeC(NEt)(NtBu))]2 (1), [Mg(dmamp)(η2-MeC(NiPr)2]2 (2), and [Mg(dmamp)(η2-MeC(NtBu)2]2 (3), containing a combination of amidinate and aminoalkoxy ligands were synthesized and characterized by NMR, FT-IR, elemental analysis, and thermogravimetric analysis (TGA). The single-crystal X-ray diffraction study of these complexes (1-3) reveals that all complexes were formed as dimers where the aminoalkoxy ligand acts as the bridge between the two metal centers.

KW - Amidinate

KW - Aminoalkoxy

KW - Heteroleptic

KW - Magnesium

KW - Precursor

UR - https://www.scopus.com/pages/publications/84942324015

U2 - 10.1016/j.poly.2015.09.018

DO - 10.1016/j.poly.2015.09.018

M3 - Article

AN - SCOPUS:84942324015

SN - 0277-5387

VL - 101

SP - 185

EP - 190

JO - Polyhedron

JF - Polyhedron

ER -

Heteroleptic magnesium complexes containing amidinate and aminoalkoxy ligands

Abstract

Keywords

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