Formation of 1,1,12,12-tetramethyl[1.1]silaferrocenophane and poly(ferrocenylsilane) in the reaction of ferrous chloride with the dilithium salt of dicyclopentadienyldimethylsilanes

Jaiwook Park; Youngsoo Seo; Sungseo Cho; Dongmok Whang; Kimoon Kim; Taihyun Chang

doi:10.1016/0022-328X(94)05027-9

Formation of 1,1,12,12-tetramethyl[1.1]silaferrocenophane and poly(ferrocenylsilane) in the reaction of ferrous chloride with the dilithium salt of dicyclopentadienyldimethylsilanes

Jaiwook Park
, Youngsoo Seo
, Sungseo Cho
, Dongmok Whang
, Kimoon Kim
, Taihyun Chang

Research Institute of Industrial Science & Technology, Pohang
Pohang University of Science and Technology

Research output: Contribution to journal › Article › peer-review

52 Scopus citations

Abstract

1,1,12,12-Tetramethyl[1.1]silaferrocenophane (1) and poly(ferrocenylsilane) (2) were formed as the major products in the reaction of FeCl₂ with the dilithium salt of (C₅H₅)₂SiMe₂, and the X-ray crystallography for 1 revealed its molecular structure of an anti conformation.

Original language	English
Pages (from-to)	23-25
Number of pages	3
Journal	Journal of Organometallic Chemistry
Volume	489
Issue number	1-2
DOIs	https://doi.org/10.1016/0022-328X(94)05027-9
State	Published - 8 Mar 1995
Externally published	Yes

Keywords

Cyclopentadieny
Ferrocene
Polymer
Polysilane
Silicon
X-ray diffraction

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10.1016/0022-328X(94)05027-9

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title = "Formation of 1,1,12,12-tetramethyl[1.1]silaferrocenophane and poly(ferrocenylsilane) in the reaction of ferrous chloride with the dilithium salt of dicyclopentadienyldimethylsilanes",

abstract = "1,1,12,12-Tetramethyl[1.1]silaferrocenophane (1) and poly(ferrocenylsilane) (2) were formed as the major products in the reaction of FeCl2 with the dilithium salt of (C5H5)2SiMe2, and the X-ray crystallography for 1 revealed its molecular structure of an anti conformation.",

keywords = "Cyclopentadieny, Ferrocene, Polymer, Polysilane, Silicon, X-ray diffraction",

author = "Jaiwook Park and Youngsoo Seo and Sungseo Cho and Dongmok Whang and Kimoon Kim and Taihyun Chang",

year = "1995",

month = mar,

day = "8",

doi = "10.1016/0022-328X(94)05027-9",

language = "English",

volume = "489",

pages = "23--25",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier B.V.",

number = "1-2",

}

Formation of 1,1,12,12-tetramethyl[1.1]silaferrocenophane and poly(ferrocenylsilane) in the reaction of ferrous chloride with the dilithium salt of dicyclopentadienyldimethylsilanes. / Park, Jaiwook; Seo, Youngsoo; Cho, Sungseo et al.
In: Journal of Organometallic Chemistry, Vol. 489, No. 1-2, 08.03.1995, p. 23-25.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Formation of 1,1,12,12-tetramethyl[1.1]silaferrocenophane and poly(ferrocenylsilane) in the reaction of ferrous chloride with the dilithium salt of dicyclopentadienyldimethylsilanes

AU - Park, Jaiwook

AU - Seo, Youngsoo

AU - Cho, Sungseo

AU - Whang, Dongmok

AU - Kim, Kimoon

AU - Chang, Taihyun

PY - 1995/3/8

Y1 - 1995/3/8

N2 - 1,1,12,12-Tetramethyl[1.1]silaferrocenophane (1) and poly(ferrocenylsilane) (2) were formed as the major products in the reaction of FeCl2 with the dilithium salt of (C5H5)2SiMe2, and the X-ray crystallography for 1 revealed its molecular structure of an anti conformation.

AB - 1,1,12,12-Tetramethyl[1.1]silaferrocenophane (1) and poly(ferrocenylsilane) (2) were formed as the major products in the reaction of FeCl2 with the dilithium salt of (C5H5)2SiMe2, and the X-ray crystallography for 1 revealed its molecular structure of an anti conformation.

KW - Cyclopentadieny

KW - Ferrocene

KW - Polymer

KW - Polysilane

KW - Silicon

KW - X-ray diffraction

UR - https://www.scopus.com/pages/publications/0002666073

U2 - 10.1016/0022-328X(94)05027-9

DO - 10.1016/0022-328X(94)05027-9

M3 - Article

AN - SCOPUS:0002666073

SN - 0022-328X

VL - 489

SP - 23

EP - 25

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1-2

ER -

Formation of 1,1,12,12-tetramethyl[1.1]silaferrocenophane and poly(ferrocenylsilane) in the reaction of ferrous chloride with the dilithium salt of dicyclopentadienyldimethylsilanes

Abstract

Keywords

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