Fast-Charging High-Energy Battery-Supercapacitor Hybrid: Anodic Reduced Graphene Oxide-Vanadium(IV) Oxide Sheet-on-Sheet Heterostructure

The battery-supercapacitor hybrid (BSH) device has potential applications in energy storage and can be a remedy for low-power batteries and low-energy supercapacitors. Although several studies have investigated electrode materials (particularly for a battery-type anode material) and design for BSHs, the energy density and power density are insufficient (far from the levels required for practical applications). Herein, a hierarchical vanadium(IV) oxide on reduced graphene oxide (rGO@VO₂) heterostructure as an anode and activated carbon on carbon cloth (AC@CC) as a cathode are proposed for fabricating an advanced BSH. The mixed valency of V ions inside the as-prepared VO₂ matrix (V³⁺ and V⁴⁺) facilitates redox reactions at a low potential, giving rise to rGO@VO₂ as a typical anode with a working potential of 0.01-3 V (vs Li/Li⁺). The sheet-on-sheet heterostructured rGO@VO₂ yields a high specific capacity of 1214 mAh g^-1 at 0.1 A g^-1 after 120 cycles, with a high rate capability and stability. The rGO@VO₂//AC@CC BSH device exhibits a maximum gravimetric energy density of 126.7 Wh kg^-1 and a maximum gravimetric power density of â¼10※000 W kg^-1 within a working voltage range of 1-4 V. Moreover, it exhibits fast charging times of 5 and 834 s with energy densities of 15.6 and 82 Wh kg ^-1, respectively.