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Experimental insights into the adsorption of newly synthesized Gemini ethoxylated surfactant on C-steel in different acidic media accompanied by DFT and MCs studies

  • Nasser M. El Basiony
  • , Elsayed A. Elsharaky
  • , Dong Hwan Kim
  • , Aziza S. El-Tabei
  • Egyptian Petroleum Research Institute
  • Sungkyunkwan University

Research output: Contribution to journal › Article › peer-review

Abstract

Bis ethoxylated cationic surfactant (BOECS) is synthesized. The prepared surfactant's structure configuration was verified through a variety of spectral and physicochemical techniques, including FT-IR, MS,1HNMR, and surface activity evaluations. BOECS applications as a C-steel corrosion inhibitor in 1.0 N HCl and 1.0 N H2SO4 and sulfate reducing bacteria (SRB) mitigations have been investigated thoroughly. Physical properties of the BOECS indicate its potential adsorption affinity at the air/water interface. The electrical conductivity determines the CMC value in accordance with the surface tension value. Electrochemical kinetic parameters indicate the BOECS is sorted as a mixed-type inhibitor and has an inhibition efficacy of 91.22% and 81.26% for HCl and H2SO4, respectively. Active centers of BOECS structure enhance its adsorption at the electrolyte/C-steel. Calculated adsorption energy change (ΔGads) and theoretical adsorption energy (Eads) values suggest strong and spontaneous BOECS adsorption. The cytotoxic performance of the synthesized BOECS exhibited a potent inhibitory potential against the SRB. The outcomes of this research exhibit that the BOECS can lower SRB growth from 106 to 102cell/mL.

Original languageEnglish
Pages (from-to)777-807
Number of pages31
JournalZeitschrift fur Physikalische Chemie
Volume237
Issue number6
DOIs
StatePublished - 1 Jun 2023

Keywords

  • C-steel corrosion
  • HCl
  • SRB
  • adsorption energy
  • electrochemical techniques
  • surfactants

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