Enhanced photocatalytic hydrogen production of microporous organic polymers by incorporation of afterglow phosphorescent materials

Sang Hyun Ryu; Gye Hong Kim; Tae Kyu Ahn; Kyoung Chul Ko; Seung Uk Son

doi:10.1039/d3ta02348f

Enhanced photocatalytic hydrogen production of microporous organic polymers by incorporation of afterglow phosphorescent materials

Sang Hyun Ryu
, Gye Hong Kim
, Tae Kyu Ahn
, Kyoung Chul Ko
, Seung Uk Son

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

This work shows that photocatalytic hydrogen evolution from water by microporous organic polymer (MOP)-based photocatalysts can be enhanced by the incorporation of afterglow phosphorescent materials (AG). The photocatalytic MOPs were introduced on the surface of AG through the Stille coupling of tris(4-trimethylstannylphenyl)amine with 3,7-dibromodibenzothiophene sulfone. The resultant AG-MOP-TADS-Pds showed enhanced photocatalytic activities by 2.4 times, compared with MOP-TADS-Pd, due to the Förster resonance energy transfer or charge transfer between AG and MOP-TADS-Pds.

Original language	English
Pages (from-to)	12719-12725
Number of pages	7
Journal	Journal of Materials Chemistry A
Volume	11
Issue number	24
DOIs	https://doi.org/10.1039/d3ta02348f
State	Published - 12 May 2023

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abstract = "This work shows that photocatalytic hydrogen evolution from water by microporous organic polymer (MOP)-based photocatalysts can be enhanced by the incorporation of afterglow phosphorescent materials (AG). The photocatalytic MOPs were introduced on the surface of AG through the Stille coupling of tris(4-trimethylstannylphenyl)amine with 3,7-dibromodibenzothiophene sulfone. The resultant AG-MOP-TADS-Pds showed enhanced photocatalytic activities by 2.4 times, compared with MOP-TADS-Pd, due to the F{\"o}rster resonance energy transfer or charge transfer between AG and MOP-TADS-Pds.",

author = "Ryu, \{Sang Hyun\} and Kim, \{Gye Hong\} and Ahn, \{Tae Kyu\} and Ko, \{Kyoung Chul\} and Son, \{Seung Uk\}",

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doi = "10.1039/d3ta02348f",

language = "English",

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T1 - Enhanced photocatalytic hydrogen production of microporous organic polymers by incorporation of afterglow phosphorescent materials

AU - Ryu, Sang Hyun

AU - Kim, Gye Hong

AU - Ahn, Tae Kyu

AU - Ko, Kyoung Chul

AU - Son, Seung Uk

PY - 2023/5/12

Y1 - 2023/5/12

N2 - This work shows that photocatalytic hydrogen evolution from water by microporous organic polymer (MOP)-based photocatalysts can be enhanced by the incorporation of afterglow phosphorescent materials (AG). The photocatalytic MOPs were introduced on the surface of AG through the Stille coupling of tris(4-trimethylstannylphenyl)amine with 3,7-dibromodibenzothiophene sulfone. The resultant AG-MOP-TADS-Pds showed enhanced photocatalytic activities by 2.4 times, compared with MOP-TADS-Pd, due to the Förster resonance energy transfer or charge transfer between AG and MOP-TADS-Pds.

AB - This work shows that photocatalytic hydrogen evolution from water by microporous organic polymer (MOP)-based photocatalysts can be enhanced by the incorporation of afterglow phosphorescent materials (AG). The photocatalytic MOPs were introduced on the surface of AG through the Stille coupling of tris(4-trimethylstannylphenyl)amine with 3,7-dibromodibenzothiophene sulfone. The resultant AG-MOP-TADS-Pds showed enhanced photocatalytic activities by 2.4 times, compared with MOP-TADS-Pd, due to the Förster resonance energy transfer or charge transfer between AG and MOP-TADS-Pds.

UR - https://www.scopus.com/pages/publications/85160555285

U2 - 10.1039/d3ta02348f

DO - 10.1039/d3ta02348f

M3 - Article

AN - SCOPUS:85160555285

SN - 2050-7488

VL - 11

SP - 12719

EP - 12725

JO - Journal of Materials Chemistry A

JF - Journal of Materials Chemistry A

IS - 24

ER -

Enhanced photocatalytic hydrogen production of microporous organic polymers by incorporation of afterglow phosphorescent materials

Abstract

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